File name: Pandora135s1_ManhattanNY-CCNY_20210830_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20241023T095202.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20210830_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20210830 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210830T130856.8Z 7912.547880 316 1 0.61 2 59.41 106.01 34.47 247.36 0.00 1 0.00 1 0 17 1.816e-02 9.313e-03 1.737e-02 7.221e-03 2.462534e-01 3.729167e-03 2.997895e-03 -6.000000e+00 1.059637e-02 230.57 -2.00 3.51 -2.00 316.66 0.00e+00 5.160128e-05 4.641933e-04 1.965719e-04 -6.000000e+00 4.751050e-04 289.09 -2.00 20.00 -2.00 315.85 0.00e+00 1.957 0.000 302.00 328.00 3 2.7898e+00 9.7846e-03 2.3423e-02 -6.0000e+00 2.6456e-02 -1.1317e-02 1.0910e-02 1.2914e-02 -6.0000e+00 2.8545e-02 9.8440e-03 6.3960e-03 6.2676e-03 -6.0000e+00 1.7023e-02 -3.9118e-03 3.0904e-03 1.7463e-03 -6.0000e+00 7.3585e-03 3.4894e-03 -1.5187e-04 2.0554e-04 2.0453e-05 -6.0000e+00 4.9622e-04 4.1277e-03 8.7539e-05 12 9 1 12 1 1 999.00 21.88 0.06 0.00413 0.00299 1 63 1 5 0 206.060 26.41 20.00 21.88 30.52 16.3 1028.59 -6088 2647 -2182 -2133 -643 -10184 1284 2526 1199 -5408 -2363 -632 -560 -2225 -706 -876 1401 396 -3159 4094 -1761 3672 -1865 4433 2312 -541 1301 -3321 2309 2928 3807 824 3143 -4313 -1078 -1102 -378 -1272 151 -339 -515 -344 -362 277 -1568 934 -1823 202 -2165 2118 955 -271 1984 -1499 -159 1010 957 -755 217 1147 995 1058 1434 1648 -473 -808 415 1158 -430 1135 74 1562 299 -337 597 -731 -1535 -739 -791 -1243 -581 -2003 -613 -1658 -298 -1007 550 -817 287 -121 300 495 1146 702 -42 582 812 1857 -1028 238 -932 -524 878 -2023 -1468 -2018 -790 -203 1481 20 758 159 -276 -430 55 723 -160 -530 283 325 143 920 731 475 1139 350 84 521 700 -752 781 -649 -12 164 58 79 111 -760 -226 168 -674 -288 -993 418 -355 -315 -88 -1533 190 404 211 -1034 -435 -122 -118 -549 -186 -248 400 119 -988 1269 -564 1149 -620 1472 826 -203 463 -1154 741 943 1305 306 1214 -1759 -401 -419 -157 -618 82 -203 -322 -222 -239 182 -1047 603 -1180 128 -1386 1332 631 -189 1427 -1136 -122 783 750 -594 166 878 783 881 1255 1494 -420 -673 337 941 -375 1048 73 1541 293 -324 533 -620 -1231 -579 -659 -1124 -569 -2073 -646 -1828 -341 -1218 673 -1012 354 -145 341 530 1158 717 -46 671 997 2371 -1365 305 -1160 -626 1017 -2475 -1891 -2691 -1068 -280 2089 30 1148 239 -402 -597 73 930 -212 -719 404 478 208 1329 1042 660 1525 456 108 675 956 -1070 1137 -957 -19 254 93 129 185 -1278 -376 274 -1087 -454 SS 20210830T131752.9Z 7912.554084 322 1 4.99 2 57.80 107.77 36.00 249.66 0.00 1 0.00 1 0 17 1.447e-02 7.338e-03 1.453e-02 5.620e-03 2.464153e-01 2.897064e-03 2.981352e-03 -6.000000e+00 8.443269e-03 230.57 -2.00 3.51 -2.00 316.83 0.00e+00 -1.968284e-04 3.769972e-04 1.883277e-04 -6.000000e+00 3.785757e-04 289.09 -2.00 20.00 -2.00 316.02 0.00e+00 1.870 0.000 302.00 328.00 3 4.9456e+00 7.6189e-03 2.2718e-02 -6.0000e+00 2.1080e-02 2.8582e-02 8.5068e-03 1.2914e-02 -6.0000e+00 2.2745e-02 4.8472e-03 5.0215e-03 6.2598e-03 -6.0000e+00 1.3564e-02 -3.7389e-03 2.4503e-03 1.7690e-03 -6.0000e+00 5.8631e-03 4.3203e-04 -1.4572e-04 1.6029e-04 2.0322e-05 -6.0000e+00 3.9541e-04 4.5925e-03 9.4561e-05 12 9 1 12 1 1 999.00 21.90 0.20 0.00459 0.00350 2 8 1 5 0 1605.230 26.51 20.00 21.90 31.03 16.3 1030.76 -846 -2237 3819 -3847 -1815 -7029 -3638 1042 -153 1730 -2606 -3161 1360 4456 -2444 20 -1820 -248 3484 1685 1743 1076 214 -847 940 -639 762 1745 -1602 -588 1558 -575 549 -2841 -3798 -1683 -2362 -167 422 -2533 -239 690 -1216 -1605 443 890 391 -743 -1 -173 1100 -542 1359 1002 495 1304 66 351 -367 2198 1611 2170 2157 910 51 -359 231 -424 920 -409 509 -580 20 -114 387 -840 -504 -970 -557 -2010 -1857 -1886 -1274 420 -717 -329 915 448 -73 -93 92 -306 224 500 189 482 -219 550 103 -627 -612 -92 -234 -759 -726 -1034 -68 -553 182 449 485 696 152 -490 680 232 402 -148 792 -482 516 -627 608 708 474 -359 -78 799 85 233 120 16 -528 -405 87 133 438 525 -635 320 -612 -725 -121 -343 540 -533 -232 -912 -502 156 -25 283 -442 -573 267 970 -616 5 -503 -70 981 499 518 322 67 -284 316 -222 261 550 -494 -181 503 -206 206 -1045 -1373 -608 -939 -78 218 -1477 -145 431 -788 -1045 282 558 240 -463 -1 -108 701 -375 972 728 370 989 51 268 -277 1627 1259 1775 1850 820 44 -295 182 -339 782 -384 494 -583 19 -106 348 -703 -385 -754 -455 -1830 -1780 -1967 -1354 463 -837 -399 1118 560 -90 -111 104 -330 230 514 205 549 -272 720 136 -819 -756 -108 -276 -934 -940 -1373 -93 -778 262 671 736 1063 227 -689 893 301 532 -203 1132 -716 765 -921 873 991 633 -468 -100 1026 115 329 175 24 -791 -622 138 219 738 878 -1068 528 -1004 -1147 SS 20210830T132219.3Z 7912.557168 325 1 3.69 2 57.00 108.67 36.77 250.75 0.00 1 0.00 1 0 17 8.301e-03 5.587e-03 2.319e-03 1.060e-03 2.375246e-01 5.488000e-04 2.873025e-03 -6.000000e+00 4.843540e-03 230.57 -2.00 3.51 -2.00 316.42 0.00e+00 3.462932e-04 6.408734e-05 9.295601e-05 -6.000000e+00 2.171628e-04 289.09 -2.00 20.00 -2.00 315.62 0.00e+00 1.830 0.000 302.00 328.00 3 1.9144e+00 1.4347e-03 2.2099e-02 -6.0000e+00 1.2093e-02 2.4136e-03 1.5974e-03 1.2385e-02 -6.0000e+00 1.3048e-02 2.5095e-03 9.2863e-04 6.0250e-03 -6.0000e+00 7.7807e-03 -8.7534e-04 4.4198e-04 1.6763e-03 -6.0000e+00 3.3636e-03 9.5569e-03 6.9355e-05 3.0139e-05 1.9680e-05 -6.0000e+00 2.2679e-04 5.0787e-03 1.4766e-04 12 1 1 12 1 1 99.82 21.91 0.23 0.00508 0.00560 48 177 1 5 0 71.800 26.51 20.00 21.91 31.07 16.3 1030.38 -941 -916 -2219 -2697 -2703 -1768 -665 745 -828 -1739 -1563 -833 -111 581 524 -577 558 681 1100 349 443 763 648 848 702 516 -158 -80 181 740 1256 1991 -25 -1778 -1899 -1848 -1050 -283 -151 -777 -1086 -624 -822 -442 -244 -529 -552 -677 -249 322 364 884 827 702 691 772 490 356 412 821 866 1780 1542 659 168 -417 -153 767 844 489 473 29 297 -73 -66 -437 -745 -712 -792 -1035 -1332 -1650 -1579 -1105 -667 -228 -83 9 413 378 334 -33 472 522 288 580 693 73 -43 -357 -809 -701 -188 -623 -772 -841 -623 -287 157 340 392 416 200 36 63 242 239 13 180 -72 133 258 362 567 480 105 586 378 334 289 5 205 -37 -314 -202 53 344 52 -216 -265 -495 -539 -169 -174 -418 -463 -421 -272 -111 138 -169 -364 -323 -181 -27 148 150 -178 176 222 369 122 155 266 234 323 282 211 -63 -30 63 259 469 799 -10 -770 -774 -769 -452 -144 -85 -496 -694 -411 -553 -297 -163 -352 -357 -457 -164 216 243 627 618 547 551 589 378 290 329 660 685 1512 1416 595 156 -354 -121 607 740 454 471 29 298 -70 -62 -365 -610 -573 -650 -963 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