File name: Pandora135s1_ManhattanNY-CCNY_20210916_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20241023T101421.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20210916_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20210916 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210916T131305.7Z 7929.550760 149 1 46.40 2 62.09 113.22 163.80 354.33 0.00 1 0.00 1 0 17 4.326e-02 1.245e-02 3.372e-02 7.033e-03 2.917059e-01 3.591765e-03 3.457063e-03 -6.000000e+00 2.513873e-02 229.13 -2.00 3.51 -2.00 318.26 0.00e+00 3.418848e-04 6.752107e-04 2.209404e-04 -6.000000e+00 1.125843e-03 287.75 -2.00 20.00 -2.00 317.45 0.00e+00 2.125 0.000 302.00 328.00 3 6.5178e+00 9.6986e-03 2.6097e-02 -6.0000e+00 6.2576e-02 6.6281e-02 1.1028e-02 1.5148e-02 -6.0000e+00 6.7571e-02 1.6354e-02 7.0947e-03 7.4260e-03 -6.0000e+00 4.0308e-02 -1.1591e-02 3.6653e-03 2.0954e-03 -6.0000e+00 1.7482e-02 6.3159e-05 2.0486e-04 2.0558e-04 2.2322e-05 -6.0000e+00 1.1805e-03 -2.5403e-03 2.4250e-04 12 9 8 11 8 0 99.98 21.56 0.00 -0.00254 -0.00100 52 15 1 5 0 892.140 26.21 20.00 21.56 28.12 16.6 1010.28 10390 -6552 -2676 -6822 8337 -21814 -12262 12535 -14736 -3401 -7635 -5373 7940 13924 -13843 -5565 8729 3276 2638 -7491 2914 1980 4372 -3593 1005 530 330 8666 -3267 -1865 -1963 4041 547 -2360 -4902 3974 -1231 4912 -1426 -1022 90 -4390 587 -3662 3872 990 3379 -4259 17 3071 1350 3145 -770 964 1112 5163 -2263 4105 -3463 2025 773 3962 195 560 -2539 -1177 422 -2974 1504 -2230 2121 592 2476 -702 1141 -370 -2021 -1563 -1426 -239 -3568 462 -2611 864 -1514 465 994 861 801 241 673 -1279 -16 -1899 54 -642 655 124 641 139 -377 -1238 -1060 -839 -1800 737 -841 582 -638 1434 554 624 -75 -912 524 -733 498 -1104 1260 -1048 1816 264 687 535 -710 -812 -260 679 -586 1385 -59 791 -665 -1204 -410 553 898 233 2 155 56 -1480 636 -509 -199 -485 464 -1629 -912 828 -1400 -296 -694 -512 760 1461 -2102 -844 1199 497 420 -1367 483 331 741 -703 199 108 65 1538 -622 -356 -407 865 126 -553 -1152 867 -318 1377 -510 -415 39 -2064 268 -1754 1720 450 1471 -1963 7 1340 641 1576 -425 547 647 2957 -1411 2371 -2114 1175 476 2566 143 427 -1938 -815 271 -1988 1064 -1842 1802 523 2109 -586 857 -252 -1284 -1010 -967 -182 -3145 427 -2632 886 -1648 529 1179 1040 956 274 724 -1276 -15 -1785 54 -720 807 163 865 181 -473 -1437 -1197 -1001 -2340 980 -1188 848 -965 2269 923 1034 -119 -1395 729 -987 674 -1602 1919 -1654 2800 418 1048 779 -997 -1081 -331 886 -837 2076 -94 1269 -1110 -2050 -735 1022 1690 448 5 288 103 -2658 SS 20210916T134026.0Z 7929.569746 167 1 15.65 2 57.45 119.03 163.35 15.20 0.00 1 0.00 1 0 17 1.890e-02 7.429e-03 1.368e-02 4.698e-03 2.469329e-01 2.401442e-03 2.984849e-03 -6.000000e+00 1.097865e-02 229.13 -2.00 3.51 -2.00 317.20 0.00e+00 6.230929e-04 3.420174e-04 1.480127e-04 -6.000000e+00 4.917686e-04 287.75 -2.00 20.00 -2.00 316.40 0.00e+00 1.852 0.000 302.00 328.00 3 4.4602e+00 6.3360e-03 2.2523e-02 -6.0000e+00 2.7328e-02 2.5476e-02 7.1061e-03 1.2834e-02 -6.0000e+00 2.9512e-02 -5.2998e-04 4.2521e-03 6.2822e-03 -6.0000e+00 1.7605e-02 -1.6575e-03 2.1096e-03 1.7872e-03 -6.0000e+00 7.6342e-03 7.1382e-04 2.9412e-05 1.3491e-04 1.9591e-05 -6.0000e+00 5.1572e-04 -2.2572e-03 1.9319e-04 12 9 1 12 1 1 99.96 21.55 0.34 -0.00226 -0.00204 4 4 2 5 0 3095.310 26.21 19.99 21.55 28.11 16.5 1010.21 -3195 -2383 -5826 -1427 -4251 -10183 -918 -4482 -2531 -575 846 -7576 4687 2694 -4389 -1270 3298 2279 3224 2023 516 579 -1245 118 -1882 3178 239 2373 -77 -1386 897 497 1428 -6007 -3023 -186 -1461 1193 412 -403 166 -182 -2137 -691 350 421 -105 -1004 296 2190 -10 1689 137 292 1463 2288 -759 331 -162 881 2057 1485 1849 981 65 -415 -1322 -295 482 375 631 -73 -255 -374 372 63 -1674 -710 -978 -1977 -1133 -1103 -1846 -191 264 -1006 293 -137 444 -111 578 -799 261 -158 -134 -453 1056 297 -10 95 -415 -561 -16 -1135 -872 -554 -540 33 63 909 791 541 172 -511 848 -84 -264 -148 -69 -144 45 768 494 879 -202 -449 716 828 -199 111 -92 401 -431 -381 243 -168 855 -23 -60 -534 -327 -598 -399 -314 -784 -167 -482 -1207 -108 -617 -372 -81 121 -1203 747 503 -990 -298 765 554 805 528 137 153 -346 34 -586 960 72 655 -20 -378 256 155 469 -2095 -961 -58 -520 492 197 -212 93 -106 -1301 -416 208 249 -61 -570 169 1254 -6 1066 92 206 1042 1595 -551 235 -117 635 1483 1167 1565 844 55 -330 -990 -227 392 332 599 -69 -247 -345 323 49 -1253 -515 -770 -1719 -1055 -1119 -1928 -207 297 -1222 358 -171 545 -133 656 -859 257 -156 -143 -521 1287 388 -14 124 -517 -664 -19 -1364 -1129 -729 -742 47 93 1365 1237 841 261 -741 1149 -110 -353 -202 -102 -217 68 1134 729 1233 -281 -592 925 1066 -278 160 -139 610 -658 -610 399 -288 1447 -40 -104 -926 -544 -991 SS 20210916T134842.2Z 7929.575489 170 1 43.49 2 56.10 120.90 162.87 21.11 0.00 1 0.00 1 0 17 8.215e-03 5.331e-03 6.255e-04 2.591e-04 2.346908e-01 1.329909e-04 2.847081e-03 -6.000000e+00 4.771659e-03 229.13 -2.00 3.51 -2.00 316.68 0.00e+00 2.592640e-04 1.668522e-05 1.094040e-04 -6.000000e+00 2.137730e-04 287.75 -2.00 20.00 -2.00 315.90 0.00e+00 1.787 0.000 302.00 328.00 3 1.5520e+00 3.4829e-04 2.1614e-02 -6.0000e+00 1.1878e-02 -2.0665e-03 3.8857e-04 1.2184e-02 -6.0000e+00 1.2828e-02 1.3226e-03 2.2782e-04 5.9591e-03 -6.0000e+00 7.6521e-03 -1.0925e-03 1.1043e-04 1.6683e-03 -6.0000e+00 3.3177e-03 1.4441e-02 1.6106e-04 7.4097e-06 1.9173e-05 -6.0000e+00 2.2421e-04 -1.7688e-03 1.5257e-04 10 0 0 10 0 0 99.98 21.53 0.24 -0.00177 -0.00056 1555 439 1 5 0 27.520 26.21 20.00 21.53 28.30 16.6 1012.31 -921 -1057 -2400 -3257 -2660 -1593 -385 745 -611 -1874 -1575 -768 -231 588 212 -396 257 413 726 775 336 484 583 863 593 261 -190 -215 177 855 1261 1864 46 -1732 -1806 -1467 -880 -217 -323 -832 -854 -773 -711 -362 -274 -460 -654 -740 -441 501 572 829 983 653 782 845 378 426 563 1032 1172 1600 1439 696 -179 -94 -129 744 940 389 400 126 194 -55 -97 -273 -612 -415 -572 -917 -1174 -1716 -1632 -1105 -715 -410 -233 -1 145 339 279 23 591 623 353 469 528 131 -111 -422 -698 -572 56 -558 -827 -690 -625 -299 174 405 264 382 172 85 131 313 268 200 105 -186 35 214 282 611 430 62 594 549 279 190 -29 201 12 -318 -172 63 316 24 -277 -230 -454 -454 -146 -177 -401 -498 -366 -215 -56 121 -109 -346 -286 -146 -49 143 58 -116 77 128 233 235 103 161 183 287 207 94 -66 -76 59 284 445 649 17 -652 -698 -573 -353 -103 -169 -494 -543 -509 -477 -242 -183 -305 -423 -466 -272 312 379 584 729 470 575 635 288 320 415 763 908 1336 1299 613 -164 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