File name: Pandora135s1_ManhattanNY-CCNY_20211012_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20241023T102427.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20211012_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20211012 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211012T152052.8Z 7955.639500 197 1 1.95 2 51.94 154.06 119.84 100.76 0.00 1 0.00 1 0 17 1.242e-02 8.537e-03 1.036e-02 6.214e-03 1.875066e-01 3.186316e-03 2.274931e-03 -6.000000e+00 7.149000e-03 226.28 -2.00 3.51 -2.00 315.49 0.00e+00 3.260999e-04 3.057155e-04 4.516681e-05 -6.000000e+00 3.190393e-04 284.58 -2.00 20.00 -2.00 314.84 0.00e+00 1.618 0.000 302.00 328.00 3 4.3694e+00 8.1765e-03 1.8690e-02 -6.0000e+00 1.7696e-02 4.3213e-02 9.0833e-03 9.5582e-03 -6.0000e+00 1.9152e-02 -1.0090e-03 5.2327e-03 4.6915e-03 -6.0000e+00 1.1429e-02 -7.9683e-04 2.4201e-03 1.3574e-03 -6.0000e+00 4.9793e-03 1.0989e-03 -3.0995e-04 1.7542e-04 1.6628e-05 -6.0000e+00 3.3865e-04 -1.4313e-02 9.9394e-05 12 9 1 12 1 1 999.00 21.17 0.23 -0.01431 -0.01664 1 15 1 5 0 887.250 25.90 20.00 21.17 27.35 16.8 1005.34 586 -1805 -3246 -613 -81 -3269 94 1343 513 -4146 391 539 4556 -116 -1703 -790 757 2418 1299 2565 -463 1110 822 613 -1122 1394 -445 1365 -1663 870 10 3284 1257 -2287 -2324 -3518 1425 -959 1728 -1488 -919 -396 -1312 -1663 -379 1416 -583 -1291 -1004 1015 -29 1753 -872 572 -889 307 684 866 1077 -667 798 1283 1816 170 -754 126 -633 559 1538 253 798 442 540 632 970 -886 -1081 182 -9 -676 -2908 -2148 -1486 -1199 -353 -831 753 335 465 880 425 111 747 728 -37 584 141 648 -110 1005 -625 -520 92 -630 -864 -393 -65 -771 -51 -739 -638 10 -32 -457 -20 23 1049 577 -125 658 -663 511 394 932 -66 -51 42 1102 65 -124 68 987 180 -860 -3 660 759 263 -996 -1034 -94 -200 157 -521 -935 -161 -19 -768 23 365 148 -1270 116 159 1429 -42 -669 -327 315 1015 568 1138 -213 497 377 287 -560 692 -218 628 -737 381 5 1526 631 -1137 -1111 -1704 730 -561 1105 -1085 -694 -308 -1021 -1298 -298 1083 -441 -972 -732 730 -22 1362 -711 478 -767 260 582 746 909 -575 690 1188 1752 169 -729 114 -549 472 1369 244 807 462 557 639 923 -805 -914 150 -7 -620 -2893 -2252 -1594 -1347 -414 -1002 940 420 578 1057 492 121 759 745 -40 656 167 821 -142 1271 -760 -609 104 -747 -1089 -508 -86 -1041 -71 -1064 -932 15 -45 -619 -26 28 1308 747 -169 917 -934 714 545 1250 -85 -63 51 1339 83 -165 91 1337 250 -1235 -4 994 1149 408 -1564 -1584 -141 -295 SS 20211012T154647.5Z 7955.657494 212 1 10.60 2 50.11 161.98 115.28 104.31 0.00 1 0.00 1 0 17 7.863e-03 5.797e-03 2.896e-03 1.791e-03 1.814962e-01 9.182003e-04 2.240164e-03 -6.000000e+00 4.526826e-03 226.28 -2.00 3.51 -2.00 315.38 0.00e+00 4.129354e-04 8.626475e-05 3.257976e-05 -6.000000e+00 2.019401e-04 284.58 -2.00 20.00 -2.00 314.75 0.00e+00 1.556 0.000 302.00 328.00 3 4.3413e+00 2.3535e-03 1.8046e-02 -6.0000e+00 1.1206e-02 3.9843e-02 2.6129e-03 9.3371e-03 -6.0000e+00 1.2126e-02 -2.8921e-03 1.5045e-03 4.5904e-03 -6.0000e+00 7.2365e-03 -1.3062e-04 6.9226e-04 1.3228e-03 -6.0000e+00 3.1533e-03 1.2173e-03 6.8487e-05 5.0577e-05 1.6692e-05 -6.0000e+00 2.1435e-04 -1.4220e-02 1.7227e-04 12 1 1 12 1 1 99.69 21.22 0.33 -0.01422 -0.01371 13 18 1 5 0 744.930 25.90 20.01 21.22 28.41 16.9 1013.46 -190 -1766 -1510 -1778 -2709 -1402 -391 1669 -617 -994 -2077 -97 -149 1608 -439 -124 608 37 1520 1206 619 392 1066 600 758 413 132 -356 260 626 1076 1490 -10 -1089 -1521 -674 -1252 108 -514 -673 -936 -743 -1085 -405 -115 -379 -457 -1237 -128 522 798 774 609 485 1008 951 143 316 520 1139 842 1527 1334 704 -235 -445 -450 377 1026 93 363 129 69 -145 306 -341 -230 -296 -664 -552 -1560 -1419 -1545 -1386 -872 -294 -29 -146 -78 310 128 -196 719 708 295 338 568 323 -208 -360 -566 -525 115 -496 -864 -607 -709 -292 44 365 268 270 315 -36 427 352 369 94 209 -188 342 -120 476 746 609 -34 548 700 436 130 -151 370 -74 -70 -207 -25 8 164 -402 -401 -358 -535 -55 -541 -453 -485 -693 -343 -102 461 -189 -310 -639 -30 -50 592 -177 -53 261 16 683 559 290 182 502 288 380 212 66 -171 116 282 488 719 -5 -560 -734 -323 -646 63 -346 -485 -722 -574 -856 -317 -89 -301 -352 -923 -94 385 598 616 494 408 861 827 123 276 445 972 731 1416 1294 694 -231 -408 -391 320 917 91 373 133 71 -146 292 -309 -193 -240 -573 -504 -1555 -1494 -1671 -1532 -1005 -351 -36 -183 -97 374 149 -212 741 718 312 382 672 408 -268 -458 -686 -602 131 -589 -1089 -782 -933 -398 62 522 388 396 445 -47 542 436 462 121 278 -261 480 -166 651 994 790 -42 658 852 554 171 -207 509 -102 -98 -301 -38 13 254 -627 -609 -537 -793 SS 20211012T155949.3Z 7955.666542 219 1 14.94 2 49.44 166.12 113.01 106.08 0.00 1 0.00 1 0 17 7.796e-03 5.766e-03 2.500e-03 1.528e-03 1.794299e-01 7.832833e-04 2.214511e-03 -6.000000e+00 4.487531e-03 226.28 -2.00 3.51 -2.00 315.42 0.00e+00 3.293161e-04 7.406048e-05 3.853932e-05 -6.000000e+00 2.002214e-04 284.58 -2.00 20.00 -2.00 314.78 0.00e+00 1.535 0.000 302.00 328.00 3 4.3943e+00 2.0087e-03 1.7810e-02 -6.0000e+00 1.1108e-02 4.0503e-02 2.2307e-03 9.2279e-03 -6.0000e+00 1.2022e-02 -3.0930e-03 1.2843e-03 4.5402e-03 -6.0000e+00 7.1739e-03 4.3994e-04 5.9221e-04 1.2988e-03 -6.0000e+00 3.1256e-03 1.1837e-03 1.0184e-04 4.3207e-05 1.6458e-05 -6.0000e+00 2.1253e-04 -1.3496e-02 1.6306e-04 12 1 1 12 1 1 99.92 21.26 0.20 -0.01350 -0.01273 22 21 1 5 0 641.830 25.90 20.00 21.26 29.11 17.0 1018.98 -89 -418 -1983 -3054 -1497 -1543 623 1441 -183 -936 -622 -906 -355 602 -116 14 657 323 459 923 702 654 735 1121 584 110 -613 350 283 479 1798 1890 258 -1591 -1452 -2035 -627 220 -367 -835 -465 -930 -707 -662 -399 -664 -638 -788 -471 570 384 758 1163 691 859 538 109 640 293 1059 1213 1401 1420 599 -27 -190 -527 508 811 509 375 4 283 -231 -7 -93 -511 -592 -389 -1240 -1324 -1798 -1609 -1233 -555 -414 -201 -96 1 475 312 -132 580 593 265 441 646 255 60 -284 -683 -450 162 -467 -687 -766 -669 -363 297 430 327 549 66 59 131 319 193 138 188 -114 64 -102 400 691 428 179 436 569 166 34 -7 244 61 -223 -204 -7 206 109 -367 -70 -570 -438 -25 -123 -581 -851 -367 -368 156 403 -54 -284 -190 -276 -119 225 -47 6 283 143 208 414 317 292 335 534 293 56 -306 166 126 208 807 904 128 -790 -695 -982 -320 127 -245 -614 -353 -732 -565 -529 -316 -522 -485 -595 -344 414 294 595 951 572 723 462 95 547 247 889 1061 1278 1350 595 -26 -175 -449 435 733 490 378 4 290 -234 -7 -82 -423 -486 -328 -1149 -1325 -1908 -1744 -1362 -637 -496 -252 -120 2 584 363 -143 600 604 280 498 763 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