File name: Pandora135s1_ManhattanNY-CCNY_20211028_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241023T110103.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20211028_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20211028 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211028T120342.1Z 7971.502571 273 1 46.43 2 83.45 113.88 23.45 229.95 0.00 1 0.00 1 0 17 6.150e-01 2.395e-02 3.408e-01 1.021e-02 8.935266e-01 5.964002e-03 1.003308e-02 -6.000000e+00 3.575767e-01 224.82 -2.00 3.51 -2.00 322.23 0.00e+00 1.934795e-02 3.756656e-03 4.933325e-03 -6.000000e+00 1.807700e-02 282.64 -2.00 20.00 -2.00 321.76 0.00e+00 7.956 0.009 302.00 328.00 3 8.1134e-01 2.4282e-02 1.0613e-01 -6.0000e+00 8.8677e-01 1.0112e+00 3.3510e-02 9.2938e-02 -6.0000e+00 9.7387e-01 -1.2179e+00 3.1773e-02 2.6133e-02 -6.0000e+00 5.7453e-01 4.8320e-01 1.4473e-02 2.2371e-02 -6.0000e+00 2.4370e-01 3.2879e-05 -1.6144e-03 2.7895e-04 2.2976e-04 -6.0000e+00 1.8064e-02 2.5048e-02 0.0000e+00 12 8 8 10 0 0 99.95 20.25 0.34 0.02505 0.01292 95 27 1 5 0 488.650 24.96 20.01 20.25 15.94 16.3 928.90 900000 -65207 900000 -162909 900000 -234228 900000 -137416 900000 -80627 197885 -78715 39526 900000 -133061 900000 -47723 900000 93051 900000 6968 197365 -8579 24659 900000 -47968 900000 208598 900000 -55322 900000 -8545 900000 7626 26238 150796 6724 900000 30317 240786 35327 108237 -573 81372 74290 86735 65913 64799 127812 55435 97930 17660 63347 24672 93966 63478 33970 26322 12545 38777 34563 53514 -72 42407 4038 26887 9580 16532 9759 10931 14187 12800 7811 -1633 16244 -1906 9389 -14139 7682 -1777 -729 5398 594 5970 1251 4201 -547 5284 -3246 4022 -3416 4771 -2505 -4543 -3969 -3378 -2715 -2280 579 -3724 736 -3527 1591 -4019 -2586 -176 -3343 -552 -3243 311 -1903 -59 -2609 -737 -1537 -569 -948 113 997 -353 2786 1479 3368 1496 1825 -277 1758 641 1375 538 896 1744 367 663 -592 -70 81 547 -1038 462 -262 -445 -2234 900000 -827 900000 -5033 900000 -11112 900000 -2274 900000 -801 1965 -874 392 900000 -5946 900000 -1237 900000 924 900000 118 1960 -150 302 900000 -1149 900000 2071 900000 -1680 900000 -260 900000 232 613 1497 192 900000 903 2391 1217 2015 -31 2121 1996 2261 2079 2195 2618 2396 3282 1382 3404 2075 4062 3745 2659 2137 1114 2605 2544 3688 -10 4384 653 3455 1477 2511 1778 2117 2864 2662 1633 -342 2676 -336 1426 -2932 1526 -450 -218 1742 220 2216 515 1768 -252 2341 -1547 1704 -1457 1776 -999 -2012 -2058 -2099 -1998 -1948 500 -3356 618 -2720 1053 -2820 -1915 -135 -2815 -495 -3401 346 -2467 -81 -3747 -1018 -2060 -739 -1265 157 1458 -534 3942 2002 4292 1888 2353 -334 2166 825 2071 953 1769 3694 843 1550 -1504 -184 217 1466 -2789 1158 -642 -1007 -4982 SS 20211028T121323.2Z 7971.509296 276 1 27.78 2 81.79 115.56 24.87 233.94 0.00 1 0.00 1 0 17 5.365e-01 1.597e-02 3.186e-01 7.153e-03 7.642359e-01 3.891041e-03 8.730996e-03 -6.000000e+00 3.028498e-01 224.82 -2.00 3.51 -2.00 321.69 0.00e+00 1.268624e-02 2.142284e-03 9.301006e-04 -6.000000e+00 1.425305e-02 282.64 -2.00 20.00 -2.00 321.17 0.00e+00 6.567 0.005 302.00 328.00 3 1.6442e+00 1.4245e-02 7.7489e-02 -6.0000e+00 7.4641e-01 4.1813e-01 2.0345e-02 4.5616e-02 -6.0000e+00 8.1403e-01 -4.6778e-01 2.0831e-02 2.4057e-02 -6.0000e+00 4.8568e-01 1.8347e-01 9.6346e-03 1.6303e-02 -6.0000e+00 2.0907e-01 6.7264e-05 -1.1502e-03 1.9174e-04 1.7992e-04 -6.0000e+00 1.4770e-02 2.4870e-02 0.0000e+00 12 9 9 12 9 1 99.80 20.25 0.28 0.02487 0.01623 39 19 1 5 0 690.120 25.07 19.99 20.25 16.45 16.4 932.49 900000 -210534 900000 -209962 900000 -299266 -31720 -134766 -177253 -121233 -134088 -45953 -100162 56473 -143424 149885 -58276 35886 -23630 -34216 -17648 -2853 8286 -65452 34367 -42869 134515 -15212 80931 -66507 32417 -13050 65877 -6362 -16902 41807 -1807 59655 428 26386 4411 16531 -3285 11747 27771 23247 36774 15439 31433 9803 19171 10433 20723 17979 21418 26472 8294 9113 -1092 12186 5478 15819 -1458 13869 -1117 6669 3181 4138 4503 3571 1999 4528 1897 -3602 5522 -2806 -221 -3620 866 -526 -1563 1279 -2875 1124 -1070 903 -401 612 420 1300 494 -775 -907 -2191 -1828 -1710 -1252 -557 -607 -1124 -58 -175 -21 -1746 -2647 -1118 -2093 102 -1589 1124 -285 970 -1082 -884 441 -395 -711 -156 1002 -139 981 1050 1319 620 1091 -414 819 990 320 812 313 756 -349 500 -434 182 57 143 -465 19 -333 -118 -1030 900000 -3631 900000 -3621 900000 -10871 -221 -1096 -2334 -939 -1246 -320 -1086 394 -4052 1045 -1038 278 -357 -596 -260 -35 93 -1597 338 -880 938 -236 564 -2087 505 -374 1054 -207 -583 840 -58 1297 19 1053 243 864 -221 705 1463 1333 1923 1058 1960 828 1656 1103 2167 2082 2505 3025 1147 1225 -157 1529 777 2285 -276 2555 -252 1380 683 926 1130 1036 640 1452 606 -1126 1418 -704 -52 -929 248 -185 -656 596 -1526 608 -597 524 -247 382 260 803 287 -430 -495 -1294 -1181 -1306 -1118 -569 -673 -1245 -59 -157 -17 -1482 -2434 -1071 -2148 111 -1969 1474 -424 1511 -1730 -1367 641 -562 -1034 -238 1597 -231 1564 1593 1919 880 1490 -553 1111 1374 516 1494 609 1567 -775 1178 -1055 460 147 371 -1205 45 -796 -263 -2258 SS 20211028T122935.1Z 7971.520545 281 1 46.35 2 79.06 118.45 27.41 239.81 0.00 1 0.00 1 0 17 4.393e-01 6.775e-03 2.025e-01 3.730e-03 6.313522e-01 1.959190e-03 7.083412e-03 -6.000000e+00 2.473386e-01 224.82 -2.00 3.51 -2.00 321.11 0.00e+00 3.290523e-03 9.275778e-04 4.949931e-04 -6.000000e+00 1.111620e-02 282.64 -2.00 20.00 -2.00 320.53 0.00e+00 5.078 0.002 302.00 328.00 3 2.4575e+00 6.5613e-03 6.0231e-02 -6.0000e+00 6.1031e-01 6.0197e-02 8.9954e-03 3.3881e-02 -6.0000e+00 6.6522e-01 -1.2816e-02 9.1858e-03 1.7717e-02 -6.0000e+00 3.9717e-01 -3.5211e-03 4.4107e-03 7.0661e-03 -6.0000e+00 1.6873e-01 1.4899e-04 -5.4274e-04 1.0391e-04 7.3614e-05 -6.0000e+00 1.1941e-02 2.4811e-02 0.0000e+00 11 8 0 10 0 0 99.97 20.25 0.32 0.02481 0.02073 167 47 1 5 0 277.500 25.07 19.99 20.25 16.62 16.4 933.26 217619 -103897 -136900 -110603 -113920 -170426 -144451 255118 -119774 -54564 -89287 -59855 -47519 3688 -52779 61 18836 -7410 16759 -50922 18551 -39225 -13499 -45317 -1896 -19238 -24488 21635 -20453 -89 -20992 -6529 397 -2956 -27059 7559 -7721 3567 14091 -4403 3797 -10074 -2050 -8668 6227 -1677 8036 -1430 8398 3891 479 5869 3407 3369 1867 7003 -2924 2488 502 1756 2324 3963 870 1592 1924 -441 3071 -968 1964 -689 1160 339 112 123 254 666 -1511 -1005 249 -484 -2344 -179 -2501 72 -2049 202 117 -237 415 618 1538 -55 857 16 599 -108 380 302 18 -277 -731 -86 -488 -9 -1561 -353 -1082 -232 -64 550 60 130 -33 -160 829 4 476 -119 221 -913 273 246 136 734 -313 -298 237 822 96 166 -126 523 -246 24 -423 -136 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