File name: Pandora135s1_ManhattanNY-CCNY_20211102_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241023T105910.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20211102_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20211102 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211102T150659.6Z 7976.629856 251 1 45.53 2 59.74 153.97 41.59 187.06 0.00 1 0.00 1 0 17 2.674e-02 7.300e-03 8.413e-03 2.848e-03 2.491541e-01 1.407502e-03 2.983827e-03 -6.000000e+00 1.503216e-02 224.37 -2.00 3.51 -2.00 317.25 0.00e+00 5.570777e-04 2.028037e-04 7.201751e-05 -6.000000e+00 6.747677e-04 282.01 -2.00 20.00 -2.00 316.53 0.00e+00 1.976 0.000 302.00 328.00 3 5.9749e+00 3.6950e-03 2.3287e-02 -6.0000e+00 3.7063e-02 4.5083e-02 4.1756e-03 1.2582e-02 -6.0000e+00 4.0412e-02 -3.2455e-03 2.4992e-03 6.2165e-03 -6.0000e+00 2.4127e-02 -1.2001e-03 1.2286e-03 1.7985e-03 -6.0000e+00 1.0256e-02 1.3956e-04 -1.1364e-04 8.1725e-05 1.9753e-05 -6.0000e+00 7.2660e-04 2.3069e-02 0.0000e+00 11 8 0 10 0 0 99.77 20.36 0.05 0.02307 0.02222 12 3 1 5 0 3793.300 25.17 20.00 20.36 17.97 16.6 943.16 1490 -4344 -778 -11060 9037 -22442 -2150 4419 -524 -2690 -6323 -3074 -248 4729 -4498 2620 675 4192 -179 877 1274 -83 350 -1757 959 -1247 390 257 1679 822 986 966 1878 -1828 -2289 -1292 -1097 1856 -408 864 -732 -428 -1338 -1347 -9 -405 400 -1299 945 1118 634 618 2368 411 1669 1303 56 322 1 807 1982 2582 481 683 -633 -58 -819 -253 176 -337 216 161 265 127 -70 -582 -1109 -781 -993 -1904 -1862 -671 -1860 -1124 -883 304 316 443 268 893 -41 -79 401 -338 237 137 873 226 -22 -542 -379 -841 -206 -650 -1229 -321 -556 -32 90 790 396 762 -125 -327 139 335 140 -502 456 -535 387 272 466 815 420 -376 59 226 571 52 -163 426 118 141 -595 20 339 374 -107 -17 -66 -539 -871 176 -583 -101 -1460 906 -2888 -242 527 -72 -389 -938 -460 -41 849 -1003 589 161 999 -46 231 338 -22 95 -499 280 -382 119 73 445 218 278 296 612 -619 -730 -406 -379 713 -192 445 -414 -251 -787 -821 -6 -243 232 -748 522 624 376 393 1562 280 1153 922 41 231 0 563 1422 1988 398 594 -547 -47 -621 -188 142 -298 200 154 251 116 -60 -468 -837 -566 -768 -1627 -1730 -656 -1950 -1194 -1003 355 389 557 336 1063 -47 -84 401 -335 243 155 1060 296 -30 -709 -473 -992 -239 -773 -1550 -422 -767 -45 132 1196 614 1180 -191 -475 190 444 182 -689 649 -794 579 411 681 1167 574 -492 76 292 767 76 -240 637 181 220 -965 33 585 657 -185 -29 -109 -884 -1412 SS 20211102T170807.2Z 7976.713972 331 1 46.56 2 56.19 188.36 52.24 225.49 0.00 1 0.00 1 0 17 8.877e-03 5.358e-03 1.945e-03 8.681e-04 2.212121e-01 4.307157e-04 2.676306e-03 -6.000000e+00 4.989750e-03 224.37 -2.00 3.51 -2.00 316.56 0.00e+00 4.226107e-04 5.222784e-05 4.519694e-05 -6.000000e+00 2.240018e-04 282.00 -2.00 20.00 -2.00 315.85 0.00e+00 1.791 0.000 302.00 328.00 3 4.1244e+00 1.1165e-03 2.0984e-02 -6.0000e+00 1.2303e-02 7.7521e-03 1.2562e-03 1.1180e-02 -6.0000e+00 1.3414e-02 1.3116e-03 7.3358e-04 5.5271e-03 -6.0000e+00 8.0089e-03 -1.6527e-03 3.4700e-04 1.5874e-03 -6.0000e+00 3.4042e-03 1.1344e-03 -7.3963e-05 2.4798e-05 1.8219e-05 -6.0000e+00 2.4123e-04 2.3699e-02 0.0000e+00 10 0 0 10 0 0 99.88 20.38 0.28 0.02370 0.02314 119 34 1 5 0 391.220 25.17 19.99 20.38 17.17 16.5 937.74 -745 -1285 -2570 -4416 -1360 -2737 228 912 -207 -2156 -2232 -706 129 1092 -440 202 147 1192 1034 886 220 438 627 682 800 -99 -306 -450 365 386 1675 1636 726 -1741 -1834 -1147 -725 185 -95 -591 -1127 -647 -1076 -570 -294 -392 -633 -774 -247 209 837 767 1047 605 949 885 402 465 582 1032 1358 1610 1167 759 -400 -196 -287 597 980 493 151 8 25 -141 -6 -343 -377 -80 -277 -860 -1000 -1686 -1570 -1286 -801 -515 -353 -165 -9 265 171 82 573 867 424 487 415 110 -269 -286 -415 -481 348 -314 -733 -564 -611 -383 93 236 12 254 23 122 187 480 285 334 89 -347 -29 179 191 588 527 98 745 834 389 161 -110 264 131 -139 -260 -25 301 17 -394 -97 -336 -268 -464 -133 -227 -496 -796 -213 -421 37 164 -41 -448 -457 -147 28 264 -121 60 45 371 333 295 74 147 214 245 303 -39 -117 -161 122 127 574 605 290 -711 -702 -433 -301 90 -51 -367 -709 -421 -719 -380 -195 -258 -408 -485 -161 137 536 525 752 456 730 695 321 368 451 797 1087 1298 1021 699 -364 -163 -235 477 846 452 151 8 24 -139 -6 -299 -297 -60 -222 -733 -953 -1666 -1640 -1407 -935 -607 -437 -210 -12 318 200 87 590 873 457 545 486 142 -365 -377 -509 -575 398 -381 -914 -740 -838 -517 132 355 18 377 34 168 249 602 360 444 121 -504 -43 260 269 833 710 126 959 1086 514 228 -154 376 189 -211 -398 -40 492 29 -663 -159 -532 -429 -736 SS 20211102T171250.1Z 7976.717246 334 1 45.37 2 56.33 189.72 52.88 226.69 0.00 1 0.00 1 0 25 8.482e-03 5.676e-03 6.568e-04 3.227e-04 2.208456e-01 1.603812e-04 2.685299e-03 -6.000000e+00 4.767555e-03 224.37 -2.00 3.51 -2.00 316.23 0.00e+00 3.648089e-04 1.804253e-05 5.100755e-05 -6.000000e+00 2.140423e-04 282.00 -2.00 20.00 -2.00 315.54 0.00e+00 1.798 0.000 302.00 328.00 3 2.2442e+00 4.1436e-04 2.1031e-02 -6.0000e+00 1.1755e-02 2.0059e-03 4.6578e-04 1.1168e-02 -6.0000e+00 1.2817e-02 4.1808e-04 2.6945e-04 5.5221e-03 -6.0000e+00 7.6524e-03 -9.1442e-04 1.2554e-04 1.5739e-03 -6.0000e+00 3.2524e-03 7.4183e-03 -1.5951e-04 9.1391e-06 1.8921e-05 -6.0000e+00 2.3050e-04 2.4118e-02 0.0000e+00 10 0 0 10 0 0 99.34 20.38 0.22 0.02412 0.02292 561 158 1 5 0 80.850 25.17 19.99 20.38 17.29 16.5 938.59 -883 -1334 -2391 -3695 -2620 -2058 158 511 4 -2229 -1353 -732 14 560 279 -182 189 692 640 962 343 817 671 853 521 240 -384 -564 192 745 1477 1834 424 -1726 -1443 -1050 -518 95 -117 -681 -1087 -676 -855 -402 -270 -427 -836 -619 -379 676 758 868 1084 652 805 810 458 427 653 988 1232 1565 1346 634 -328 -170 -236 722 986 451 147 21 -15 -181 -168 -151 -307 -187 -235 -775 -997 -1657 -1818 -1286 -853 -648 -440 -293 -110 179 229 45 689 1049 435 451 450 126 -202 -404 -622 -465 272 -276 -762 -694 -653 -408 137 259 95 240 98 165 221 665 390 364 102 -258 -170 143 261 613 605 258 854 842 427 214 -10 265 5 -256 -204 -94 210 -13 -359 -133 -393 -308 -419 -175 -284 -512 -736 -462 -349 28 102 1 -517 -306 -170 4 150 84 -59 63 239 228 353 128 301 253 338 218 103 -163 -224 71 270 561 748 188 -779 -608 -438 -237 47 -70 -432 -747 -481 -582 -273 -196 -308 -590 -423 -252 449 531 649 795 501 633 650 373 345 516 779 1008 1376 1202 598 -305 -144 -197 588 870 423 141 21 -15 -172 -156 -135 -248 -144 -193 -675 -972 -1674 -1948 -1439 -963 -782 -529 -361 -135 220 260 49 725 1080 451 516 540 157 -265 -518 -784 -538 319 -324 -974 -886 -871 -566 189 379 138 349 143 233 286 855 506 471 142 -365 -246 203 359 846 794 340 1065 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