File name: Pandora135s1_ManhattanNY-CCNY_20211110_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241023T110051.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20211110_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20211110 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211110T124001.4Z 7984.527794 70 1 46.36 2 80.34 123.04 145.32 71.85 0.00 1 0.00 1 0 17 4.860e-01 1.007e-02 2.055e-01 4.098e-03 6.533061e-01 2.225823e-03 7.264978e-03 -6.000000e+00 2.786475e-01 223.68 -2.00 3.51 -2.00 321.38 0.00e+00 6.419918e-03 1.137655e-03 6.792108e-04 -6.000000e+00 1.376291e-02 281.04 -2.00 20.00 -2.00 320.84 0.00e+00 5.688 0.003 302.00 328.00 3 2.2592e+00 7.7579e-03 6.6365e-02 -6.0000e+00 6.8976e-01 5.0225e-02 1.1098e-02 3.7051e-02 -6.0000e+00 7.5610e-01 -7.7528e-02 1.1831e-02 1.9626e-02 -6.0000e+00 4.4678e-01 2.3273e-02 5.5646e-03 1.0451e-02 -6.0000e+00 1.9109e-01 1.0497e-04 -7.2523e-04 1.1778e-04 9.9338e-05 -6.0000e+00 1.3719e-02 2.5600e-02 0.0000e+00 12 8 8 10 0 0 90.62 20.66 0.36 0.02560 0.02015 97 27 1 5 0 477.790 25.39 19.98 20.66 19.69 16.7 955.40 900000 -142902 900000 -200995 900000 -268420 900000 -155668 900000 -163159 900000 -113677 -29238 900000 -125803 900000 -29407 900000 -40591 176765 -42923 69827 -11365 -18964 25848 -21501 67293 -9077 154604 -49206 76911 -24540 62319 -16550 15986 10585 1207 31503 -2006 16096 -2169 12434 -11460 2030 1661 10378 4049 5416 8528 6949 7576 -215 13896 260 13115 1610 2048 -2187 -380 1072 5196 9351 -4070 5621 -532 5714 -315 6424 -120 1735 419 134 -535 -1473 1795 -2376 1808 -5080 1240 -3120 -799 -1824 -1442 -1434 -1538 278 1065 1417 -245 2723 -835 1425 -767 738 -292 23 -85 -83 125 -989 426 -1088 763 -1758 -427 -1279 -563 -305 -150 504 -167 436 -703 53 -221 709 -234 230 262 -369 41 392 902 -22 488 -912 1002 32 737 -132 25 131 199 150 -532 271 120 137 -529 491 -471 53 -354 900000 -923 900000 -2405 900000 -5864 900000 -1360 900000 -1829 900000 -993 -152 900000 -2772 900000 -341 900000 -640 705 -750 418 -161 -314 294 -412 537 -154 617 -1443 782 -797 1032 -604 427 302 42 987 -103 810 -147 784 -971 155 131 779 335 464 750 675 820 -28 1745 41 1898 272 352 -389 -65 180 884 1716 -937 1319 -138 1369 -80 1590 -36 583 156 52 -203 -529 567 -706 513 -1536 404 -1270 -372 -975 -837 -845 -970 184 734 996 -174 1795 -533 871 -466 466 -203 19 -80 -85 138 -1088 446 -1035 661 -1605 -415 -1325 -613 -356 -186 698 -247 671 -1089 82 -322 989 -335 345 418 -588 64 609 1346 -32 683 -1245 1308 45 1172 -230 47 262 403 325 -1241 632 286 332 -1279 1170 -1064 112 -738 SS 20211110T124811.5Z 7984.533466 75 1 47.96 2 79.06 124.54 143.91 73.72 0.00 1 0.00 1 0 17 5.468e-01 2.764e-02 3.077e-01 1.223e-02 5.626311e-01 6.449878e-03 6.944938e-03 -6.000000e+00 3.116614e-01 223.68 -2.00 3.51 -2.00 320.89 0.00e+00 1.690797e-02 2.714571e-03 1.673078e-03 -6.000000e+00 1.523042e-02 281.04 -2.00 20.00 -2.00 320.30 0.00e+00 5.079 0.002 302.00 328.00 3 4.4518e+00 2.0601e-02 5.8220e-02 -6.0000e+00 7.7056e-01 4.0400e-01 2.5667e-02 3.1807e-02 -6.0000e+00 8.4297e-01 -4.0526e-01 2.2313e-02 2.0808e-02 -6.0000e+00 4.9797e-01 1.6790e-01 1.1075e-02 1.7552e-02 -6.0000e+00 2.1093e-01 1.9329e-05 -1.3717e-03 3.5635e-04 1.9435e-04 -6.0000e+00 1.5364e-02 2.4452e-02 0.0000e+00 12 8 8 10 0 0 99.58 20.65 0.23 0.02445 0.01414 17 5 1 5 0 2820.440 25.39 20.00 20.65 19.84 16.8 956.35 110971 216054 -67649 18867 900000 -217757 900000 33103 900000 -46841 900000 -100283 900000 900000 -62151 900000 110916 16101 8857 153364 62327 188620 -11055 60165 -11243 75099 17116 220478 158719 -16328 32222 -10898 265731 -8829 85649 35133 72639 24416 20394 29084 24494 12985 -5395 438 20423 43834 21928 31396 33870 37487 12650 17581 15729 12124 22257 22631 4634 6239 -2755 2603 22854 10924 -1692 5711 1714 2657 4970 927 -1634 3128 -4826 2850 -1575 -3569 839 2180 -6119 -7350 1523 -2570 -4622 -912 -2344 -1302 -2781 -1029 2427 -832 327 25 -230 2592 -5181 -3059 -5588 -3144 -2953 -283 -281 -562 610 -932 -442 -2554 -876 91 -191 -232 624 250 709 588 -1225 -1528 45 -220 -751 -61 1767 70 1702 1619 1661 2986 -1033 142 -499 -1 1919 518 1333 430 619 242 -275 -628 710 804 -1324 483 -451 -559 -2160 1322 2573 -1973 233 900000 -20330 900000 394 900000 -897 900000 -3666 900000 900000 -3395 900000 1517 596 373 1827 1622 2246 -541 1486 -545 1590 642 2626 1890 -938 1421 -848 3165 -781 2871 1906 2916 1766 1796 2660 2542 1602 -813 65 2632 4624 2957 3966 4308 4848 2208 3199 3126 2634 4470 4564 1115 1445 -681 614 4831 2809 -561 1947 627 926 1637 324 -645 1337 -2416 1356 -763 -1651 337 776 -2219 -2762 593 -1234 -2624 -560 -1520 -879 -2026 -783 1873 -680 262 20 -171 1733 -3568 -2129 -4477 -2754 -2982 -316 -338 -669 664 -922 -418 -2522 -915 99 -214 -277 811 362 1117 932 -1950 -2395 65 -307 -1068 -90 2748 115 2729 2503 2476 4237 -1465 190 -653 -1 2890 884 2442 807 1208 502 -611 -1460 1661 1903 -3183 1096 -970 -1173 -4496 SS 20211110T125748.8Z 7984.540148 81 1 35.36 2 77.58 126.33 142.23 75.81 0.00 1 0.00 1 0 17 3.629e-01 1.263e-02 2.094e-01 7.266e-03 5.270572e-01 3.709996e-03 6.026075e-03 -6.000000e+00 2.039018e-01 223.68 -2.00 3.51 -2.00 320.57 0.00e+00 6.180622e-03 1.437850e-03 4.112124e-04 -6.000000e+00 9.284607e-03 281.04 -2.00 20.00 -2.00 319.95 0.00e+00 4.517 0.002 302.00 328.00 3 4.1880e+00 1.1435e-02 5.2347e-02 -6.0000e+00 5.0170e-01 1.4091e-01 1.4298e-02 2.8028e-02 -6.0000e+00 5.4748e-01 -1.1319e-01 1.2968e-02 1.5033e-02 -6.0000e+00 3.2646e-01 3.8516e-02 6.5376e-03 8.3882e-03 -6.0000e+00 1.3883e-01 4.9246e-05 -4.0333e-04 2.0870e-04 7.8458e-05 -6.0000e+00 9.9150e-03 2.3901e-02 0.0000e+00 12 9 9 12 1 1 99.87 20.63 0.27 0.02390 0.02087 17 7 1 5 0 1954.640 25.39 20.01 20.63 19.63 16.7 954.28 43214 -10381 -84956 -114360 900000 -188587 -49730 -57249 290154 -59582 -17552 -41210 32189 123210 -42772 -15800 30859 -17237 4614 -2081 -10223 -1372 -1073 -12645 5777 -3685 11025 28952 7730 -24995 14682 -11911 30607 -13790 -7861 -5002 10389 12535 8280 9258 7597 1548 -4276 -1055 5143 8868 4047 3871 12786 13578 1923 4998 5533 3397 4235 4525 -1708 -2127 -4476 -2893 8986 5731 799 71 -201 -1616 -281 499 -2070 2263 1239 1308 220 -317 1137 2048 -2369 -1450 452 -2088 -3342 -2033 -2585 353 -2016 732 630 582 866 802 -741 -869 -503 -567 -2219 451 -636 1080 -175 209 608 -1465 2 -745 -892 -758 -761 -158 234 642 601 500 -937 -775 605 -308 434 -311 155 -292 139 712 401 1384 3 -467 206 700 595 -181 -76 161 383 -200 -385 176 726 -4 -886 530 239 -547 -742 306 -99 -1717 -2941 900000 -8780 -664 -920 2056 -1120 -225 -764 374 873 -1526 -521 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