File name: Pandora135s1_ManhattanNY-CCNY_20211123_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241023T113436.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20211123_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20211123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211123T122605.2Z 7997.518116 287 1 47.56 2 85.30 122.29 57.28 277.27 0.00 1 0.00 1 0 25 8.455e-01 5.542e-02 4.575e-01 3.860e-02 1.157994e+00 2.538450e-02 1.250081e-02 -6.000000e+00 5.259881e-01 223.13 -2.00 3.51 -2.00 322.55 0.00e+00 6.475186e-03 1.490038e-02 1.428725e-02 -6.000000e+00 3.757812e-02 279.55 -2.00 20.00 -2.00 322.15 0.00e+00 10.279 0.020 302.00 328.00 3 -6.2231e-02 1.0162e-01 1.5044e-01 -6.0000e+00 1.2846e+00 2.5297e+00 1.1506e-01 1.2433e-01 -6.0000e+00 1.4116e+00 -2.6485e+00 7.0565e-02 3.1704e-02 -6.0000e+00 8.3982e-01 9.5557e-01 3.9046e-02 1.9645e-02 -6.0000e+00 3.6654e-01 4.4703e-06 -1.3452e-03 1.0496e-03 1.7615e-04 -6.0000e+00 2.7873e-02 2.8331e-03 0.0000e+00 12 8 8 10 0 0 -53.51 19.36 1.20 0.00283 -0.00728 28 8 1 5 0 1698.220 24.25 20.00 19.36 6.43 15.9 865.93 292452 900000 145142 401668 900000 -107258 900000 900000 900000 29469 900000 900000 900000 900000 75309 900000 900000 244726 118103 172419 900000 900000 38736 900000 900000 900000 900000 900000 900000 18419 72498 84315 900000 7023 87617 900000 900000 900000 900000 900000 900000 8899 21873 14283 372255 900000 900000 900000 900000 900000 -1874 333196 42831 92397 900000 900000 22548 77099 13410 18187 900000 67027 -45245 51911 34984 22658 24221 -744 7431 80330 3575 112567 13274 5807 6031 900000 30570 10944 15885 -5932 5882 37766 775 53216 -1881 8883 45458 10621 -606 15642 -9052 11001 39021 -24373 -20322 4040 -12043 -1260 -4634 -6731 3178 -209 -2852 -4455 4762 -2548 -838 -4384 -3826 1339 1786 1642 -7557 -377 7353 -3842 -5546 -4117 5921 -4040 1617 4132 11205 7837 -4235 2035 -3322 -3574 5498 962 2710 -575 3168 2510 -3016 -210 1991 986 -2967 580 648 111 -3750 10918 900000 5418 14995 900000 -17757 900000 900000 900000 1100 900000 900000 900000 900000 2939 900000 900000 9136 4409 6437 900000 900000 1653 900000 900000 900000 900000 900000 900000 688 2706 3148 900000 474 3271 900000 900000 900000 900000 900000 900000 680 1439 1013 13897 900000 900000 900000 900000 900000 -182 12439 3118 4312 900000 900000 2104 3886 1151 1358 900000 3253 -7770 3876 3330 2453 2622 -110 1124 6597 674 7144 2131 889 788 900000 2568 1205 1987 -1140 1208 6556 215 9238 -590 2587 9418 3132 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96.53 19.36 0.33 0.00316 -0.01085 67 20 1 5 0 666.490 24.25 19.99 19.36 6.83 15.8 868.18 900000 51228 900000 -125282 900000 -287953 900000 900000 900000 -167223 900000 900000 900000 900000 -78159 900000 70881 30461 323443 900000 316896 45150 -52446 -42819 900000 -50460 24198 900000 900000 -38799 -377 99807 900000 26216 -21145 163713 167461 900000 64381 154572 91062 50488 5074 -5200 44755 30479 118087 34707 348832 55633 33854 42535 81523 37810 52701 74310 12929 28463 12917 17231 62007 33997 4131 19931 22681 19072 32142 12268 10041 20665 16912 19757 11539 2411 6472 13799 3750 -5919 -1230 1334 132 6585 2364 8716 -802 5502 1944 3925 1587 2516 -2293 325 -96 -7367 -4362 -3409 -2487 -1356 -1532 -722 21 -1833 -1390 -4061 -1966 -2230 -3917 -1354 -2171 -819 -1803 -797 -2157 -1551 650 -864 -16 -493 1148 -668 1883 1517 3401 2669 784 656 524 1152 919 791 834 835 148 302 -340 -453 367 613 -429 40 -21 -1045 -1419 900000 494 900000 -1554 900000 -13628 900000 900000 900000 -2228 900000 900000 900000 900000 -1320 900000 684 294 3121 900000 3058 436 -911 -682 900000 -852 233 900000 900000 -636 -5 963 900000 455 -551 1580 1616 900000 981 1491 1341 1179 184 -211 1159 929 1559 1128 3366 1752 1496 1944 2774 2151 2703 3132 954 1821 905 1103 2582 2089 383 1846 2243 1997 3024 1503 1415 3001 2774 3222 1959 407 921 1611 463 -868 -206 271 33 1798 750 2763 -280 1988 721 1453 594 936 -838 110 -33 -2971 -1934 -1827 -1593 -1015 -1285 -612 16 -1284 -852 -2483 -1249 -1504 -2856 -1055 -1957 -863 -2134 -1034 -2963 -2117 844 -1112 -20 -675 1629 -982 2586 1949 4260 3281 957 780 612 1451 1325 1362 1641 1808 334 735 -896 -1254 1021 1709 -1191 106 -50 -2388 -3093 SS 20211123T124805.5Z 7997.533397 293 1 46.08 2 81.86 126.15 61.30 280.36 0.00 1 0.00 1 0 25 8.064e-01 8.001e-03 2.797e-01 3.182e-03 9.382389e-01 1.772454e-03 1.010717e-02 -6.000000e+00 4.530014e-01 223.13 -2.00 3.51 -2.00 322.03 0.00e+00 6.730393e-03 1.063037e-03 3.269852e-03 -6.000000e+00 2.078057e-02 279.55 -2.00 20.00 -2.00 321.58 0.00e+00 6.620 0.005 302.00 328.00 3 4.4402e-01 6.9682e-03 8.7152e-02 -6.0000e+00 1.1140e+00 2.7470e-01 1.1841e-02 6.6369e-02 -6.0000e+00 1.2152e+00 -3.2887e-01 1.3752e-02 3.1543e-02 -6.0000e+00 7.2493e-01 1.2572e-01 6.1004e-03 1.3394e-02 -6.0000e+00 3.1139e-01 1.8978e-04 -9.3964e-04 8.0495e-05 1.4090e-04 -6.0000e+00 2.2060e-02 2.2284e-03 0.0000e+00 11 8 0 10 0 0 12.42 19.36 0.36 0.00223 -0.00483 264 74 1 5 0 174.500 24.25 20.00 19.36 7.21 15.8 871.06 -341471 900000 -315736 -164060 900000 -354439 -233676 -221185 -117945 -320056 -70241 -275758 -169663 -180008 -139816 -124929 -81262 -92772 -113551 -44809 -112046 -29221 -126429 -63951 -30810 -79515 -51668 -42917 -55146 -112118 -52835 -53985 28695 -47204 -30066 -41475 -24700 -14957 21224 6957 4862 -8542 -13838 -3896 -7351 16767 -5404 -2623 7691 10555 -2768 9424 7825 6176 9228 8083 6090 2425 4071 -1181 4541 5446 5069 8105 1128 5016 4509 3620 4674 5851 2548 5225 849 73 -912 1734 -1686 -1687 215 -668 1378 -409 -656 227 -805 326 1030 436 550 1526 680 687 581 -424 -456 56 -422 -25 -228 -287 -355 -1094 -320 -928 -1514 -1299 -1125 -1220 -686 -175 -68 221 -82 -134 -33 473 76 341 -160 -498 15 955 665 637 97 -322 499 801 220 220 295 409 282 -512 -352 -54 344 200 -329 16 -114 27 -377 -2119 900000 -2048 -509 900000 -3099 -725 -686 -366 -2979 -218 -2255 -737 -1229 -868 -853 -429 -633 -1057 -222 -1112 -127 -1530 -456 -172 -765 -385 -293 -445 -1878 -639 -854 240 -923 -485 -746 -414 -274 336 153 125 -276 -502 -133 -267 499 -213 -109 317 475 -164 570 541 481 750 700 554 226 360 -107 404 542 599 1089 162 707 656 571 829 1191 591 1226 203 16 -184 305 -294 -315 47 -180 439 -155 -277 102 -387 164 538 235 293 772 325 313 264 -211 -266 39 -352 -22 -225 -286 -330 -984 -255 -733 -1282 -1162 -1065 -1153 -730 -216 -96 339 -130 -210 -49 687 111 526 -261 -832 24 1426 949 883 131 -424 637 1095 355 416 581 877 648 -1279 -942 -139 904 531 -868 43 -284 61 -828 SS 20211123T125816.4Z 7997.540468 296 1 45.63 2 80.33 128.00 63.14 281.77 0.00 1 0.00 1 0 25 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