File name: Pandora135s1_ManhattanNY-CCNY_20220131_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241023T120338.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20220131_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20220131 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220131T124943.9Z 8066.534535 54 1 46.71 2 83.55 119.54 84.21 130.25 0.00 1 0.00 1 0 17 6.076e-01 2.182e-02 3.916e-01 1.024e-02 1.012343e+00 6.262582e-03 1.078916e-02 -6.000000e+00 3.535688e-01 224.33 -2.00 3.51 -2.00 322.40 0.00e+00 1.617901e-02 3.733204e-03 8.522985e-03 -6.000000e+00 2.243472e-02 275.17 -2.00 20.00 -2.00 322.00 0.00e+00 8.062 0.010 302.00 328.00 3 7.8343e-01 2.4645e-02 1.1708e-01 -6.0000e+00 8.7683e-01 1.1478e+00 3.7040e-02 1.0790e-01 -6.0000e+00 9.6164e-01 -1.3858e+00 3.9865e-02 3.5223e-02 -6.0000e+00 5.6612e-01 5.4163e-01 1.7973e-02 1.8289e-02 -6.0000e+00 2.4567e-01 2.6978e-05 -1.7735e-03 2.8210e-04 1.7056e-04 -6.0000e+00 1.8142e-02 -1.4656e-02 0.0000e+00 12 8 8 10 0 0 -19.21 18.78 0.45 -0.01466 -0.02798 65 18 1 5 0 718.140 23.72 20.01 18.78 2.22 15.9 845.07 24793 900000 900000 900000 900000 -280574 900000 89975 900000 -133453 900000 900000 900000 900000 -95402 -4335 21682 900000 -55138 900000 199 191450 -69859 116240 900000 27779 900000 900000 900000 -84214 428 -39946 900000 10915 112416 28880 42567 215122 252865 900000 110145 49116 -7061 101106 23558 190546 60675 104173 900000 93817 59599 63557 80999 27878 86469 60892 32778 15880 23491 -6853 69811 25738 6665 28829 14495 26776 16150 23640 6747 25562 12895 24708 15376 413 11527 15079 7706 -9393 2198 -9933 10943 3983 1439 6072 -1 7031 2478 2662 -1891 4406 -335 4117 -3249 -4186 -4950 -1670 -3206 -657 -2104 -2494 933 -3495 1887 -5647 -1079 -3366 -1650 -2639 -1855 -1574 -2129 33 -2412 -1318 -510 165 -553 734 770 70 2038 2207 2148 1348 692 26 1370 1461 1474 390 914 1103 626 603 -716 -112 319 121 -1206 429 -153 -36 -1593 247 900000 900000 900000 900000 -13073 900000 895 900000 -1327 900000 900000 900000 900000 -1898 -43 216 900000 -1219 900000 2 1904 -1506 1156 900000 276 900000 900000 900000 -2187 6 -1104 900000 229 1118 473 623 2140 2515 900000 1353 1178 -310 1538 786 1895 1491 1768 900000 2086 2092 2417 2844 1794 3238 2993 2129 1180 1526 -577 2778 1762 647 2631 1594 2820 1918 2753 977 3517 2209 3878 2566 73 1618 1906 987 -1427 372 -2223 2413 1103 457 1963 0 2495 960 1055 -779 1638 -122 1360 -1144 -1601 -2240 -890 -2094 -470 -1720 -2110 720 -2622 1176 -3648 -703 -2383 -1216 -2141 -1607 -1600 -2534 42 -3345 -1809 -674 211 -721 991 1097 104 2855 2892 2667 1641 825 30 1542 1751 2086 666 1777 2241 1378 1435 -1859 -305 879 337 -3366 1122 -371 -79 -3535 SS 20220131T130025.4Z 8066.541961 57 1 46.44 2 81.80 121.42 82.73 132.08 0.00 1 0.00 1 0 25 6.946e-01 9.177e-03 3.345e-01 3.969e-03 8.837920e-01 2.224424e-03 9.546706e-03 -6.000000e+00 3.952368e-01 224.34 -2.00 3.51 -2.00 321.95 0.00e+00 9.132891e-03 1.232095e-03 2.836878e-03 -6.000000e+00 1.766350e-02 275.17 -2.00 20.00 -2.00 321.53 0.00e+00 6.581 0.005 302.00 328.00 3 9.3550e-01 8.2927e-03 8.4260e-02 -6.0000e+00 9.7765e-01 2.9062e-01 1.3590e-02 6.0708e-02 -6.0000e+00 1.0661e+00 -3.3966e-01 1.5942e-02 2.9047e-02 -6.0000e+00 6.3105e-01 1.3033e-01 7.2179e-03 1.3683e-02 -6.0000e+00 2.6862e-01 1.2628e-04 -1.2223e-03 1.0666e-04 1.4370e-04 -6.0000e+00 1.9357e-02 -1.4384e-02 0.0000e+00 11 8 0 10 0 0 98.53 18.79 0.34 -0.01438 -0.02357 181 51 1 5 0 256.520 23.72 20.00 18.79 3.48 16.1 854.57 -225924 -248715 900000 -222311 900000 -367463 -140867 900000 -179233 -251650 -13759 -36052 -165258 -67620 -150609 -121827 -99616 89328 -98312 -44447 7226 -119987 -14477 -112078 263990 -83697 22734 -33048 18570 -96037 -77295 -34288 -10082 -22560 -42415 6856 -29608 2736 6148 11436 -4330 -11089 -10024 -10169 10194 5404 14676 7087 33576 9994 4373 9411 9766 5955 9081 12426 -833 4394 -2313 3649 4425 11277 -578 8062 1607 6032 6156 3172 3716 2387 3875 2798 3891 -33 1479 2581 -1373 -3922 -2462 -1775 -1325 1726 -955 1723 -922 1038 309 495 -146 2114 538 308 620 -1085 -497 -761 37 573 97 -551 -751 -1096 -860 -1078 -1753 -1658 -1645 -774 -810 17 -455 574 -191 -159 150 51 404 -70 498 -487 115 766 830 365 407 -122 430 998 208 240 272 669 41 -118 -588 -74 38 195 -123 -159 102 -78 -387 -874 -1225 900000 -938 900000 -5945 -545 900000 -693 -1770 -53 -139 -959 -262 -1457 -1131 -886 346 -1103 -309 31 -1810 -78 -1734 1021 -1101 106 -268 93 -1746 -1495 -557 -156 -436 -985 95 -641 51 136 288 -146 -438 -419 -445 375 217 568 318 1260 526 277 652 756 528 836 1159 -91 454 -247 359 445 1182 -73 1089 255 933 963 541 707 534 949 724 981 -8 321 496 -259 -793 -570 -500 -448 660 -420 788 -460 539 170 280 -82 1129 274 148 292 -551 -289 -531 30 503 95 -559 -718 -932 -708 -868 -1511 -1515 -1589 -734 -862 21 -638 868 -301 -246 223 73 582 -106 791 -806 184 1155 1191 511 551 -160 547 1331 325 439 517 1376 90 -281 -1508 -200 105 539 -339 -422 249 -176 -836 SS 20220131T131717.6Z 8066.553677 62 1 46.10 2 79.12 124.47 80.48 135.05 0.00 1 0.00 1 0 25 4.016e-01 5.895e-03 1.365e-01 1.719e-03 7.115500e-01 9.054616e-04 7.916074e-03 -6.000000e+00 2.267421e-01 224.34 -2.00 3.51 -2.00 321.19 0.00e+00 4.791500e-03 4.209008e-04 7.486896e-04 -6.000000e+00 9.866769e-03 275.17 -2.00 20.00 -2.00 320.72 0.00e+00 5.106 0.002 302.00 328.00 3 1.1973e+00 2.9615e-03 6.3151e-02 -6.0000e+00 5.6039e-01 8.7242e-02 4.2343e-03 3.9164e-02 -6.0000e+00 6.1062e-01 -7.4783e-02 4.7400e-03 2.1326e-02 -6.0000e+00 3.6312e-01 2.1418e-02 2.2751e-03 9.1159e-03 -6.0000e+00 1.5435e-01 4.7027e-04 -8.5678e-04 4.6491e-05 9.1366e-05 -6.0000e+00 1.0892e-02 -1.4481e-02 0.0000e+00 10 0 0 10 0 0 97.48 18.81 0.27 -0.01448 -0.02092 327 92 1 5 0 140.510 23.72 20.00 18.81 5.35 16.3 868.02 -170944 -97658 -138855 -31873 -79019 -192773 -106690 -160656 -63133 -170285 -37146 -112853 -54092 -89496 -54830 -63497 -18169 -32183 -47275 -7858 -42990 -21337 -60645 -19268 -39207 -7291 -24777 -10539 -22181 -26188 -17157 -10612 8159 -13145 -1547 -9455 -4467 -11585 251 -1158 -2867 -3163 -4531 1104 -1810 3866 -1500 3697 1512 5821 1295 4711 4050 2274 4752 2081 1829 -957 398 -782 3558 1301 2692 2690 1698 2508 1119 2044 1224 2225 828 1285 14 557 -511 584 -1073 -1224 -236 -932 44 -1481 -1802 -1660 -928 -724 -250 -117 269 949 544 484 81 420 -159 494 209 586 -27 -291 -343 -613 -42 -533 -1045 -1380 -792 -519 170 211 -48 339 122 209 -11 732 323 285 -72 -400 -292 340 125 340 144 -349 538 743 388 -66 -51 313 38 -298 -386 -236 178 246 -366 136 -258 35 110 -1032 -344 -815 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