File name: Pandora135s1_ManhattanNY-CCNY_20220505_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241023T140845.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20220505_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20220505 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220505T132001.9Z 8160.555577 181 1 18.75 2 51.70 102.02 86.11 58.08 0.00 1 0.00 1 0 17 8.700e-03 5.506e-03 4.342e-04 2.101e-04 2.393448e-01 1.067276e-04 2.855747e-03 -6.000000e+00 5.000921e-03 230.26 -2.00 3.51 -2.00 316.28 0.00e+00 3.604017e-04 1.198581e-05 5.487791e-05 -6.000000e+00 2.199669e-04 282.45 -2.00 20.00 -2.00 315.58 0.00e+00 1.610 0.000 302.00 328.00 3 5.9599e-01 2.7926e-04 2.0364e-02 -6.0000e+00 1.2500e-02 1.0120e-02 3.1223e-04 1.2323e-02 -6.0000e+00 1.3566e-02 -5.1719e-03 1.7962e-04 6.0029e-03 -6.0000e+00 8.0637e-03 1.3110e-03 8.2943e-05 1.6617e-03 -6.0000e+00 3.3893e-03 4.3846e-02 -2.4755e-04 5.9496e-06 1.9276e-05 -6.0000e+00 2.3666e-04 1.8819e-02 0.0000e+00 12 1 1 12 1 1 32.10 20.68 0.25 0.01882 0.01696 1109 803 1 5 0 16.160 25.47 19.99 20.68 20.49 18.1 980.74 -931 -1266 -2380 -3665 -3204 -2210 -398 338 -346 -2213 -1990 -1345 -401 331 328 -299 220 652 852 1120 587 692 804 905 604 266 -421 -573 50 745 1465 1933 640 -1319 -1564 -1205 -718 97 67 -514 -830 -621 -790 -372 -251 -355 -760 -694 -435 344 628 812 982 613 686 755 457 372 693 1001 1186 1505 1381 763 -222 -231 -352 493 847 494 253 16 39 -115 -52 -164 -399 -207 -232 -644 -994 -1621 -1805 -1430 -934 -701 -488 -264 -36 307 380 207 720 906 428 377 419 107 -92 -381 -555 -500 171 -180 -704 -643 -628 -423 19 206 48 165 16 90 105 555 401 444 289 11 -24 227 245 587 557 184 689 737 330 197 -50 213 -1 -205 -121 -25 255 43 -288 -116 -380 -357 -598 -179 -262 -499 -717 -559 -369 -70 66 -75 -506 -448 -311 -94 88 99 -98 74 227 307 416 222 259 308 337 238 108 -169 -215 19 277 572 750 270 -569 -634 -482 -315 50 38 -316 -554 -431 -562 -265 -178 -251 -525 -466 -285 226 433 598 715 469 538 604 372 300 547 787 965 1315 1231 721 -207 -198 -297 405 751 467 246 16 39 -111 -49 -147 -325 -162 -191 -566 -981 -1667 -1973 -1548 -1078 -821 -602 -334 -45 368 442 230 731 898 453 418 490 138 -120 -482 -687 -599 195 -216 -875 -844 -819 -575 28 297 72 249 23 126 142 704 511 593 396 15 -34 319 349 798 755 237 842 910 438 267 -71 308 -2 -301 -188 -40 406 71 -473 -185 -586 -554 -916 SS 20220505T133008.5Z 8160.562598 184 1 26.71 2 49.84 104.02 84.53 59.58 0.00 1 0.00 1 0 17 8.547e-03 5.525e-03 2.843e-04 1.428e-04 2.309513e-01 7.263658e-05 2.758349e-03 -6.000000e+00 4.912532e-03 230.26 -2.00 3.51 -2.00 316.19 0.00e+00 3.935861e-04 7.962961e-06 5.748634e-05 -6.000000e+00 2.160967e-04 282.45 -2.00 20.00 -2.00 315.49 0.00e+00 1.547 0.000 302.00 328.00 3 2.3046e-01 1.8954e-04 1.9601e-02 -6.0000e+00 1.2279e-02 1.1976e-02 2.1182e-04 1.1884e-02 -6.0000e+00 1.3327e-02 -6.1739e-03 1.2177e-04 5.7877e-03 -6.0000e+00 7.9215e-03 1.5672e-03 5.5944e-05 1.6030e-03 -6.0000e+00 3.3291e-03 6.8143e-02 -3.1440e-04 4.0445e-06 1.8665e-05 -6.0000e+00 2.3251e-04 1.9596e-02 0.0000e+00 10 0 0 10 0 0 35.29 20.69 0.27 0.01960 0.01723 2669 753 1 5 0 9.570 25.47 20.00 20.69 21.89 18.2 993.61 -795 -1209 -2163 -3620 -3054 -2192 -352 415 -182 -2018 -1960 -1071 -365 527 300 -189 122 630 828 1130 615 761 831 880 646 258 -394 -706 -57 620 1302 1780 528 -1435 -1695 -1295 -892 86 41 -530 -871 -611 -743 -390 -254 -346 -691 -628 -396 426 655 820 1051 694 782 848 534 443 659 1015 1234 1559 1467 870 -220 -231 -390 427 854 473 288 87 104 -79 -57 -215 -500 -445 -402 -788 -1030 -1604 -1809 -1335 -888 -635 -432 -173 -17 235 247 5 498 715 334 350 424 143 -81 -356 -538 -493 187 -245 -690 -647 -648 -373 62 286 161 260 83 143 115 502 344 381 234 -61 -39 231 309 611 581 215 716 707 350 212 -80 208 -90 -189 -214 -23 243 67 -263 -75 -385 -377 -589 -162 -264 -477 -746 -560 -384 -65 85 -41 -482 -461 -258 -89 146 94 -64 43 226 307 431 239 292 326 363 260 107 -161 -293 -22 234 516 759 225 -626 -752 -566 -394 44 23 -351 -584 -425 -529 -278 -180 -244 -478 -421 -259 298 449 600 810 526 606 671 430 353 514 789 992 1346 1291 809 -202 -207 -323 344 742 438 290 86 108 -79 -53 -190 -426 -363 -345 -718 -991 -1700 -1924 -1483 -996 -762 -518 -213 -21 289 280 5 520 729 363 397 505 178 -106 -457 -678 -570 218 -284 -873 -820 -858 -514 86 416 234 379 121 202 149 644 443 490 325 -86 -55 326 445 838 757 281 884 882 469 288 -114 301 -127 -277 -334 -36 387 109 -431 -120 -593 -587 -905 SS 20220505T133035.4Z 8160.562910 184 2 26.79 2 49.76 104.11 84.46 59.64 0.00 1 0.00 1 0 17 8.546e-03 5.544e-03 2.826e-04 1.424e-04 2.302808e-01 7.242029e-05 2.750471e-03 -6.000000e+00 4.912298e-03 230.26 -2.00 3.51 -2.00 316.18 0.00e+00 4.172816e-04 7.929127e-06 5.630572e-05 -6.000000e+00 2.160857e-04 282.45 -2.00 20.00 -2.00 315.48 0.00e+00 1.545 0.000 302.00 328.00 3 2.2870e-01 1.8896e-04 1.9558e-02 -6.0000e+00 1.2278e-02 1.1284e-02 2.1118e-04 1.1850e-02 -6.0000e+00 1.3326e-02 -5.8294e-03 1.2137e-04 5.7699e-03 -6.0000e+00 7.9211e-03 1.4815e-03 5.5723e-05 1.6002e-03 -6.0000e+00 3.3289e-03 6.8530e-02 -3.0333e-04 4.0293e-06 1.8624e-05 -6.0000e+00 2.3249e-04 1.9562e-02 0.0000e+00 10 0 0 10 0 0 33.75 20.70 0.27 0.01956 0.01728 2669 753 1 5 0 9.570 25.47 20.01 20.70 22.11 18.2 993.61 -804 -1288 -2121 -3592 -3066 -2148 -308 524 -300 -2091 -1903 -1010 -365 465 330 -163 156 730 848 1066 615 728 818 866 650 166 -352 -669 -43 577 1333 1809 498 -1452 -1735 -1280 -873 100 26 -483 -838 -645 -766 -397 -230 -324 -666 -679 -404 430 660 811 1085 698 793 850 543 435 649 1052 1227 1579 1472 825 -203 -205 -392 453 834 454 310 53 88 -110 -65 -202 -521 -435 -392 -780 -1072 -1598 -1792 -1343 -903 -656 -426 -181 -13 261 270 -7 484 717 346 371 436 137 -61 -336 -541 -526 164 -232 -706 -622 -637 -369 87 275 155 258 92 139 131 535 355 365 202 -50 -26 240 295 612 583 162 717 736 348 192 -99 173 -107 -197 -198 -25 270 58 -274 -77 -369 -375 -579 -164 -283 -470 -744 -566 -378 -57 108 -69 -502 -449 -244 -90 129 104 -55 55 263 316 408 239 281 322 359 262 69 -144 -279 -17 219 530 773 213 -635 -772 -561 -387 52 15 -320 -563 -450 -547 -283 -164 -230 -462 -457 -265 281 454 595 837 530 616 674 437 348 508 819 990 1366 1298 769 -188 -185 -325 366 726 422 312 52 87 -110 -61 -178 -445 -355 -338 -712 -1034 -1697 -1908 -1494 -1016 -788 -512 -223 -16 321 306 -7 506 732 377 421 519 171 -80 -431 -681 -608 192 -270 -895 -789 -844 -509 119 401 225 377 134 196 170 686 457 470 280 -71 -37 339 424 841 761 212 886 919 466 261 -142 251 -151 -290 -295 -39 431 94 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