File name: Pandora135s1_ManhattanNY-CCNY_20220511_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241023T141826.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20220511_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20220511 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220511T132656.4Z 8166.560375 283 1 8.04 2 49.34 101.80 131.72 5.15 0.00 1 0.00 1 0 17 1.720e-02 8.802e-03 1.439e-02 5.705e-03 2.474511e-01 2.888773e-03 2.931874e-03 -6.000000e+00 9.900390e-03 230.76 -2.00 3.51 -2.00 316.78 0.00e+00 2.557078e-04 3.649966e-04 8.633247e-05 -6.000000e+00 4.359884e-04 283.11 -2.00 20.00 -2.00 316.04 0.00e+00 1.532 0.000 302.00 328.00 3 5.7428e+00 7.6132e-03 2.0074e-02 -6.0000e+00 2.4770e-02 5.2224e-02 8.5364e-03 1.2754e-02 -6.0000e+00 2.6875e-02 -6.1223e-03 4.9925e-03 6.2108e-03 -6.0000e+00 1.5974e-02 1.0402e-03 2.3719e-03 1.7056e-03 -6.0000e+00 6.7074e-03 2.6515e-04 -2.1901e-04 1.6252e-04 1.9394e-05 -6.0000e+00 4.6797e-04 2.1916e-02 0.0000e+00 12 9 1 12 1 1 999.00 20.76 0.26 0.02192 0.02027 2 5 1 5 0 2623.650 25.47 20.03 20.76 23.00 18.0 998.47 2866 -1770 2311 -6920 4288 -7053 6583 -2923 3143 -2848 -2016 -797 -3585 3346 -3349 -194 -873 1255 -2457 2194 -1033 3554 63 1521 1219 -1158 2199 -2782 1519 -2232 1038 662 1632 -2377 -2409 -1747 -82 939 -1998 503 -1059 -149 -389 -173 -1442 -244 -982 -723 535 355 1551 507 550 -19 1931 200 816 -527 89 1153 1858 3435 504 1636 -294 -826 -1908 1093 664 706 160 -324 1847 -878 312 129 305 -893 193 -1758 -1260 -895 -2057 -980 -1417 13 -650 1462 -446 1236 23 257 -205 164 -376 -268 912 665 344 -634 188 -1395 172 -1592 -1030 -808 -869 -664 -628 495 730 692 154 -16 -201 -277 -378 -145 731 -229 362 463 609 917 535 -466 900 1176 283 599 -930 730 646 -668 340 -31 253 586 -510 391 -1254 -892 -310 407 -283 354 -1071 549 -980 856 -457 508 -503 -349 -142 -733 732 -856 -52 -244 355 -748 658 -323 1055 20 498 422 -422 758 -942 477 -719 343 231 604 -917 -871 -622 -32 411 -1047 286 -661 -96 -257 -115 -961 -160 -632 -451 332 223 988 349 388 -14 1441 155 636 -413 68 868 1441 2748 437 1476 -265 -705 -1563 856 551 644 155 -326 1799 -841 280 107 234 -686 151 -1539 -1197 -904 -2171 -1073 -1629 15 -816 1840 -555 1481 26 280 -211 165 -395 -302 1100 863 458 -832 232 -1646 197 -1895 -1321 -1063 -1166 -927 -902 731 1125 1069 228 -23 -270 -362 -496 -194 1021 -335 535 673 876 1257 716 -612 1135 1498 380 837 -1347 1059 955 -1019 533 -51 416 979 -844 638 -2046 -1393 -484 SS 20220511T133540.9Z 8166.566445 286 1 4.11 2 47.73 103.55 131.57 7.92 0.00 1 0.00 1 0 17 9.753e-03 5.928e-03 3.236e-03 1.641e-03 2.341356e-01 8.363399e-04 2.787940e-03 -6.000000e+00 5.615200e-03 230.76 -2.00 3.51 -2.00 316.11 0.00e+00 3.134069e-04 9.043552e-05 6.704630e-05 -6.000000e+00 2.472721e-04 283.11 -2.00 20.00 -2.00 315.41 0.00e+00 1.484 0.000 302.00 328.00 3 3.2352e+00 2.1835e-03 1.9242e-02 -6.0000e+00 1.4049e-02 2.9635e-02 2.4396e-03 1.2049e-02 -6.0000e+00 1.5242e-02 -5.2229e-03 1.4017e-03 5.8634e-03 -6.0000e+00 9.0596e-03 5.6700e-04 6.4185e-04 1.6105e-03 -6.0000e+00 3.8044e-03 3.5332e-03 -2.2132e-04 4.6314e-05 1.8930e-05 -6.0000e+00 2.6540e-04 2.1530e-02 0.0000e+00 12 1 1 12 1 1 99.64 20.79 0.21 0.02153 0.01987 16 57 1 5 0 231.550 25.58 19.98 20.79 23.96 18.0 1005.24 1066 -2685 -705 -5039 -2391 -3007 72 -102 -149 -1306 -3022 597 -1256 1425 -1091 739 -68 1157 916 389 1098 834 1136 202 940 -199 -103 -1691 252 102 1412 1781 -108 -905 -2329 -751 -1478 708 -226 -178 -1073 -563 -846 -149 -377 -587 -230 -703 -179 304 717 737 1397 846 644 821 543 440 494 1433 1166 1600 1204 1000 -664 -155 -557 317 772 550 383 -192 230 -381 136 -440 -328 -269 -425 -919 -1328 -1444 -1732 -1202 -830 -748 -363 13 -413 360 175 133 499 820 470 210 579 138 207 -353 -773 -794 222 -255 -697 -500 -643 -458 18 295 -136 570 136 418 -30 468 266 240 337 -87 129 261 594 542 550 52 615 615 337 242 -185 417 -291 -228 -306 12 -2 266 -274 -94 -137 -442 -643 216 -575 -155 -1066 -441 -540 13 -22 -35 -299 -729 144 -327 413 -347 249 -24 415 341 150 426 321 446 81 392 -86 -44 -679 98 39 562 763 -48 -407 -995 -328 -684 363 -134 -116 -731 -397 -611 -107 -271 -421 -160 -496 -123 209 498 547 1086 664 519 675 453 365 401 1150 973 1380 1089 951 -629 -138 -478 265 671 522 382 -192 235 -376 128 -385 -270 -219 -355 -836 -1310 -1508 -1860 -1305 -962 -899 -445 16 -516 440 204 145 511 848 502 240 687 175 267 -461 -969 -943 260 -304 -877 -642 -839 -621 25 420 -203 847 193 579 -40 594 340 313 458 -122 186 368 834 727 721 67 772 757 445 332 -258 590 -409 -334 -463 19 -3 428 -432 -148 -214 -664 -980 SS 20220511T134433.9Z 8166.572614 293 1 43.57 2 46.10 105.39 131.35 10.72 0.00 1 0.00 1 0 17 7.851e-03 5.347e-03 1.271e-03 5.789e-04 2.269216e-01 2.939877e-04 2.707930e-03 -6.000000e+00 4.519991e-03 230.76 -2.00 3.51 -2.00 316.42 0.00e+00 3.408243e-04 3.433293e-05 7.101409e-05 -6.000000e+00 1.990496e-04 283.11 -2.00 20.00 -2.00 315.71 0.00e+00 1.440 0.000 302.00 328.00 3 3.5007e+00 7.7099e-04 1.8690e-02 -6.0000e+00 1.1309e-02 2.7172e-02 8.6268e-04 1.1727e-02 -6.0000e+00 1.2270e-02 -2.0857e-03 4.9801e-04 5.7173e-03 -6.0000e+00 7.2927e-03 -6.4163e-04 2.3188e-04 1.5808e-03 -6.0000e+00 3.0622e-03 2.8666e-03 -1.1897e-04 1.6458e-05 1.8150e-05 -6.0000e+00 2.1365e-04 2.1923e-02 0.0000e+00 12 1 1 12 1 1 99.99 20.83 0.22 0.02192 0.02103 319 97 1 5 0 135.610 25.58 20.00 20.83 24.92 18.1 1011.86 -967 -767 -2128 -3202 -2139 -1413 360 944 494 -1953 -885 -747 219 237 225 -484 251 408 643 884 461 604 526 728 268 41 -664 -563 -3 665 1283 1707 681 -1729 -1624 -1281 -619 -47 68 -630 -922 -849 -890 -434 -517 -329 -814 -791 -674 435 568 937 1012 729 827 951 503 438 650 979 1371 1509 1362 597 -264 -147 -256 687 848 511 247 167 62 -66 -13 -210 -446 -274 -246 -563 -1050 -1706 -1744 -1374 -803 -691 -363 -213 68 293 211 -13 460 854 304 456 413 224 -215 -298 -507 -413 115 -280 -737 -679 -574 -381 104 259 196 218 55 113 140 437 277 325 223 -60 -68 166 231 657 527 29 583 753 339 155 -54 124 -31 -293 -162 -43 281 46 -249 -35 -321 -329 -512 -174 -147 -411 -575 -340 -216 58 170 98 -408 -180 -157 51 63 67 -156 83 139 207 293 155 201 179 260 101 16 -254 -201 -1 236 477 682 269 -699 -670 -523 -254 -23 39 -384 -609 -582 -624 -304 -361 -227 -551 -519 -431 277 381 668 760 573 665 723 389 361 525 788 1141 1254 1224 567 -247 -126 -218 568 704 480 236 165 61 -67 -12 -176 -364 -213 -203 -486 -1019 -1699 -1839 -1514 -944 -814 -449 -270 86 351 248 -14 479 867 330 509 511 286 -288 -389 -617 -492 131 -337 -906 -879 -775 -534 144 380 299 334 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