File name: Pandora135s1_ManhattanNY-CCNY_20220514_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T030843.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20220514_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20220514 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220514T142204.7Z 8169.598665 359 1 12.53 2 38.90 113.27 146.86 329.12 0.00 1 0.00 1 0 17 7.966e-03 5.700e-03 1.538e-03 9.343e-04 1.899575e-01 4.786048e-04 2.271879e-03 -6.000000e+00 4.585268e-03 231.02 -2.00 3.51 -2.00 315.49 0.00e+00 3.308155e-04 4.559184e-05 4.168684e-05 -6.000000e+00 2.023288e-04 283.45 -2.00 20.00 -2.00 314.83 0.00e+00 1.284 0.000 302.00 328.00 3 3.5500e+00 1.2424e-03 1.6229e-02 -6.0000e+00 1.1477e-02 2.4588e-02 1.3835e-03 9.8015e-03 -6.0000e+00 1.2455e-02 -2.8755e-03 7.9018e-04 4.7610e-03 -6.0000e+00 7.4025e-03 -5.6942e-05 3.5142e-04 1.3108e-03 -6.0000e+00 3.1024e-03 3.4317e-03 -9.7026e-05 2.6375e-05 1.6471e-05 -6.0000e+00 2.1692e-04 3.1757e-02 0.0000e+00 12 1 1 12 1 1 99.93 21.38 0.21 0.03176 0.03103 54 59 1 5 0 224.590 26.11 20.00 21.38 29.90 18.6 1044.76 326 -1011 -1532 -3843 -1062 -1790 1081 1300 110 -1461 -1151 -663 -384 1248 196 23 164 760 576 952 405 776 616 387 847 -228 -79 -704 234 113 1708 1468 527 -1465 -1862 -1287 -1045 179 -337 -485 -959 -596 -933 -342 -358 -546 -850 -895 -332 290 689 735 1068 705 870 719 475 546 568 922 1145 1632 1376 823 -328 -201 -432 407 609 567 488 96 170 47 83 -417 -431 -842 -411 -772 -1136 -1534 -1709 -1266 -920 -590 -388 78 -79 428 201 43 348 614 167 315 476 158 83 -410 -466 -766 304 -352 -638 -654 -667 -333 80 303 124 332 146 212 48 400 255 257 124 -64 34 295 416 537 765 50 647 457 417 146 -35 207 -132 -273 -62 16 259 108 -301 -96 -351 -399 -624 87 -289 -434 -1013 -265 -437 275 371 32 -435 -334 -197 -126 454 80 10 67 318 248 421 181 342 278 184 419 -116 -39 -326 108 52 801 680 261 -731 -871 -647 -536 107 -224 -342 -727 -465 -745 -271 -283 -428 -647 -657 -235 219 510 578 878 605 759 600 401 455 496 805 973 1484 1348 793 -328 -183 -385 354 538 564 493 100 175 47 81 -366 -364 -683 -352 -697 -1145 -1590 -1870 -1368 -1062 -727 -476 98 -98 533 230 47 368 635 173 359 565 195 106 -513 -571 -868 351 -409 -804 -822 -874 -453 107 430 183 484 202 284 62 488 314 333 165 -91 47 418 571 703 1000 62 763 547 532 187 -46 280 -181 -393 -89 23 400 162 -454 -149 -524 -576 -892 SS 20220514T142739.5Z 8169.602541 363 1 47.01 2 37.94 114.72 147.38 331.33 0.00 1 0.00 1 0 17 7.701e-03 5.537e-03 4.453e-04 2.558e-04 1.861758e-01 1.307723e-04 2.224689e-03 -6.000000e+00 4.432285e-03 231.02 -2.00 3.51 -2.00 315.73 0.00e+00 3.102945e-04 1.296811e-05 4.582795e-05 -6.000000e+00 1.955819e-04 283.45 -2.00 20.00 -2.00 315.04 0.00e+00 1.267 0.000 302.00 328.00 3 2.2173e+00 3.4060e-04 1.5974e-02 -6.0000e+00 1.1094e-02 2.1198e-02 3.7955e-04 9.6082e-03 -6.0000e+00 1.2040e-02 -1.1936e-03 2.1706e-04 4.6669e-03 -6.0000e+00 7.1556e-03 -7.7904e-04 9.7282e-05 1.2846e-03 -6.0000e+00 2.9989e-03 1.3344e-02 -1.0551e-04 7.2773e-06 1.5600e-05 -6.0000e+00 2.0969e-04 3.1863e-02 0.0000e+00 10 0 0 10 0 0 99.99 21.40 0.27 0.03186 0.03107 1508 425 1 5 0 30.760 26.11 20.00 21.40 30.08 18.8 1048.04 -122 -1063 -1701 -3144 -1991 -1266 670 1261 136 -1321 -1467 -351 -127 837 136 -142 18 560 696 972 490 592 765 811 702 168 -309 -714 111 669 1418 1749 429 -1438 -1759 -1176 -819 107 -188 -606 -950 -748 -834 -458 -351 -467 -723 -836 -418 324 708 751 1043 657 814 838 483 500 639 1061 1125 1604 1362 786 -238 -309 -495 425 836 442 382 99 201 13 4 -250 -544 -568 -464 -796 -1102 -1597 -1761 -1253 -822 -521 -375 -94 36 288 242 -60 491 660 295 370 460 173 17 -304 -537 -550 104 -344 -693 -627 -652 -390 87 316 168 312 108 111 90 378 237 261 214 -63 71 234 309 658 618 158 628 626 321 196 -53 222 -81 -312 -213 -21 265 112 -226 -69 -344 -395 -625 -32 -292 -463 -790 -442 -270 150 317 38 -377 -409 -100 -40 292 49 -54 7 222 284 406 207 248 326 362 329 81 -145 -312 49 287 632 761 200 -675 -774 -513 -394 60 -116 -428 -721 -586 -618 -364 -277 -366 -550 -614 -296 229 524 589 855 521 658 689 402 412 517 857 945 1442 1317 742 -235 -276 -408 367 726 433 377 101 204 13 4 -215 -457 -457 -395 -707 -1091 -1613 -1878 -1395 -979 -621 -470 -120 45 347 286 -64 510 670 319 410 563 217 22 -387 -636 -641 117 -411 -845 -803 -872 -540 119 452 250 459 151 151 112 474 300 327 289 -91 98 339 433 875 780 202 761 769 421 257 -72 305 -114 -456 -310 -32 413 178 -361 -107 -518 -574 -901 SS 20220514T143136.5Z 8169.605284 366 1 2.99 2 37.26 115.78 147.73 332.93 0.00 1 0.00 1 0 17 7.446e-03 5.694e-03 1.204e-03 7.886e-04 1.839933e-01 4.048837e-04 2.201583e-03 -6.000000e+00 4.285331e-03 231.02 -2.00 3.51 -2.00 315.19 0.00e+00 3.354345e-04 3.596112e-05 2.826520e-05 -6.000000e+00 1.891214e-04 283.45 -2.00 20.00 -2.00 314.55 0.00e+00 1.255 0.000 302.00 328.00 3 1.8438e+00 1.0474e-03 1.5804e-02 -6.0000e+00 1.0726e-02 1.8919e-02 1.1650e-03 9.4837e-03 -6.0000e+00 1.1641e-02 -1.5057e-03 6.6506e-04 4.6090e-03 -6.0000e+00 6.9185e-03 -1.1269e-05 2.9136e-04 1.2717e-03 -6.0000e+00 2.8992e-03 1.9705e-02 -2.3322e-04 2.2251e-05 1.5831e-05 -6.0000e+00 2.0277e-04 3.2593e-02 0.0000e+00 12 1 1 12 1 1 80.32 21.41 0.24 0.03259 0.03084 55 261 1 5 0 50.230 26.11 20.00 21.41 30.39 18.8 1050.92 -168 -590 -1501 -3044 -1718 -720 420 1205 66 -1561 -1164 -243 25 530 373 -136 203 571 561 1103 452 720 683 911 485 384 -516 -345 97 867 1490 1987 431 -1429 -1449 -1227 -825 -38 16 -556 -1037 -828 -941 -553 -332 -317 -984 -755 -424 390 587 723 841 578 551 818 551 430 740 831 1207 1537 1458 712 -321 -284 -501 475 793 435 243 89 248 15 -11 -207 -399 -640 -377 -808 -976 -1628 -1603 -1264 -907 -581 -366 -185 49 408 303 -38 539 777 246 431 356 197 -108 -276 -534 -484 28 -266 -736 -561 -643 -490 73 193 213 284 259 77 118 366 219 384 265 -96 30 238 276 697 576 239 707 556 337 199 -11 189 -56 -288 -133 24 368 -29 -316 -114 -291 -464 -626 -53 -198 -501 -938 -467 -187 116 371 23 -547 -396 -84 9 210 164 -64 90 259 261 525 218 343 332 463 259 209 -276 -171 48 418 746 980 229 -763 -722 -608 -451 -22 11 -422 -797 -657 -761 -446 -266 -251 -759 -595 -323 295 466 573 698 500 486 731 471 386 650 731 1040 1419 1446 700 -307 -260 -448 414 705 414 250 94 260 15 -11 -194 -338 -551 -322 -735 -988 -1710 -1774 -1390 -1067 -695 -460 -227 59 493 353 -42 542 806 258 471 430 248 -135 -351 -633 -555 31 -313 -899 -721 -822 -650 101 269 308 407 351 100 148 453 273 480 341 -132 42 329 370 929 729 302 845 674 415 260 -15 248 -74 -401 -188 35 555 -42 -470 -172 -425 -656 -916 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