File name: Pandora135s1_ManhattanNY-CCNY_20220606_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T034310.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20220606_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20220606 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220606T133755.5Z 8192.568003 220 1 26.71 2 44.87 98.36 109.65 49.20 0.00 1 0.00 1 0 17 8.041e-03 5.573e-03 2.382e-04 1.306e-04 2.120062e-01 6.689338e-05 2.524030e-03 -6.000000e+00 4.648906e-03 232.39 -2.00 3.51 -2.00 315.91 0.00e+00 4.175971e-04 6.953434e-06 4.715179e-05 -6.000000e+00 2.062476e-04 285.74 -2.00 20.00 -2.00 315.16 0.00e+00 1.409 0.000 302.00 328.00 3 2.2156e-01 1.7492e-04 1.7987e-02 -6.0000e+00 1.1667e-02 2.6550e-03 1.9509e-04 1.1020e-02 -6.0000e+00 1.2645e-02 -2.3295e-03 1.1148e-04 5.3309e-03 -6.0000e+00 7.5168e-03 2.4434e-04 5.0214e-05 1.4609e-03 -6.0000e+00 3.1458e-03 8.1785e-02 -1.6012e-04 3.6968e-06 1.7442e-05 -6.0000e+00 2.1910e-04 3.6371e-02 0.0000e+00 10 0 0 10 0 0 -2.49 21.27 0.26 0.03637 0.03517 2953 833 1 5 0 8.620 26.00 20.00 21.27 27.00 19.0 1026.39 -533 -1033 -2056 -3288 -2534 -1591 260 785 -127 -1848 -1571 -738 -75 675 346 -147 141 732 791 1018 527 657 734 770 576 196 -308 -492 208 807 1499 1721 341 -1594 -1639 -1228 -741 39 -126 -658 -910 -703 -768 -412 -319 -425 -748 -764 -446 407 627 842 1021 682 793 839 483 475 674 1042 1214 1515 1385 728 -233 -217 -317 602 893 476 226 37 68 -117 -84 -189 -422 -347 -400 -790 -1108 -1684 -1736 -1238 -841 -582 -365 -165 7 255 236 70 549 732 344 398 393 68 -114 -386 -573 -530 149 -381 -709 -660 -609 -362 123 295 159 268 107 133 162 464 319 315 174 -130 1 203 282 679 627 247 750 687 391 222 3 230 -15 -247 -169 -13 225 23 -264 -121 -382 -383 -608 -128 -243 -482 -775 -532 -323 56 189 -34 -465 -422 -204 -21 214 123 -56 55 293 302 399 209 259 296 326 257 89 -138 -205 87 333 649 738 158 -743 -715 -534 -357 22 -79 -440 -654 -522 -583 -312 -240 -318 -546 -539 -306 280 454 648 773 540 640 691 403 392 546 843 1023 1372 1273 702 -219 -197 -267 497 803 456 221 37 68 -119 -78 -168 -340 -287 -332 -739 -1092 -1717 -1868 -1395 -960 -708 -444 -205 9 313 266 75 572 751 357 456 472 86 -149 -488 -709 -605 174 -446 -904 -841 -810 -500 169 428 229 385 153 182 204 583 405 401 240 -182 1 282 399 914 803 317 911 850 519 299 4 326 -22 -356 -259 -19 352 36 -423 -187 -575 -582 -917 SS 20220606T133822.5Z 8192.568316 220 2 26.84 2 44.78 98.44 109.59 49.30 0.00 1 0.00 1 0 17 8.023e-03 5.559e-03 2.379e-04 1.305e-04 2.115158e-01 6.681066e-05 2.514850e-03 -6.000000e+00 4.638258e-03 232.39 -2.00 3.51 -2.00 315.90 0.00e+00 4.293427e-04 6.940783e-06 4.671121e-05 -6.000000e+00 2.057752e-04 285.74 -2.00 20.00 -2.00 315.16 0.00e+00 1.407 0.000 302.00 328.00 3 2.2226e-01 1.7472e-04 1.7951e-02 -6.0000e+00 1.1640e-02 1.9080e-03 1.9485e-04 1.0987e-02 -6.0000e+00 1.2616e-02 -2.0379e-03 1.1134e-04 5.3127e-03 -6.0000e+00 7.4995e-03 3.2831e-04 5.0125e-05 1.4568e-03 -6.0000e+00 3.1386e-03 8.1977e-02 -1.5675e-04 3.6877e-06 1.7381e-05 -6.0000e+00 2.1860e-04 3.6374e-02 0.0000e+00 10 0 0 10 0 0 22.72 21.27 0.26 0.03637 0.03520 2953 833 1 5 0 8.620 26.00 20.00 21.27 27.18 19.0 1027.74 -455 -1052 -2028 -3324 -2519 -1525 358 969 -143 -1777 -1586 -737 -96 679 285 -182 134 688 791 1045 544 708 701 739 579 186 -396 -490 198 702 1464 1679 332 -1595 -1665 -1229 -742 49 -84 -640 -897 -697 -801 -418 -299 -417 -713 -774 -440 404 649 829 1050 663 794 846 503 448 654 1073 1200 1533 1367 729 -248 -211 -311 604 904 464 247 34 88 -120 -94 -225 -459 -364 -420 -822 -1143 -1668 -1715 -1255 -837 -569 -356 -130 -1 272 227 58 558 742 302 391 415 61 -120 -381 -568 -493 160 -383 -705 -654 -582 -370 116 295 146 264 108 145 169 456 323 307 178 -121 -5 219 282 668 596 238 768 663 380 202 -28 230 -21 -231 -169 2 222 28 -271 -132 -369 -365 -605 -110 -248 -477 -786 -531 -310 77 234 -38 -448 -427 -188 -27 216 102 -70 53 276 302 411 217 279 283 314 259 85 -177 -204 83 291 635 722 154 -744 -728 -536 -358 28 -53 -429 -646 -519 -608 -317 -226 -312 -521 -547 -303 278 470 639 796 525 642 697 420 371 530 870 1013 1391 1259 704 -234 -193 -262 499 814 445 241 34 87 -122 -87 -200 -371 -302 -349 -770 -1128 -1702 -1847 -1414 -956 -694 -433 -161 -1 335 256 63 581 762 313 448 498 77 -156 -483 -702 -562 186 -449 -899 -833 -774 -511 160 429 211 378 155 199 213 573 411 392 246 -169 -7 305 399 899 763 305 934 821 504 272 -39 326 -29 -333 -258 3 346 45 -433 -205 -555 -554 -912 SS 20220606T134312.1Z 8192.571668 223 1 26.77 2 43.88 99.38 108.93 50.26 0.00 1 0.00 1 0 17 7.983e-03 5.575e-03 2.300e-04 1.274e-04 2.083299e-01 6.538769e-05 2.477291e-03 -6.000000e+00 4.615508e-03 232.39 -2.00 3.51 -2.00 315.85 0.00e+00 4.384653e-04 6.709837e-06 4.173684e-05 -6.000000e+00 2.047734e-04 285.74 -2.00 20.00 -2.00 315.11 0.00e+00 1.386 0.000 302.00 328.00 3 2.0851e-01 1.7092e-04 1.7678e-02 -6.0000e+00 1.1583e-02 2.2407e-03 1.9059e-04 1.0820e-02 -6.0000e+00 1.2554e-02 -1.7911e-03 1.0893e-04 5.2304e-03 -6.0000e+00 7.4628e-03 3.2719e-04 4.8928e-05 1.4359e-03 -6.0000e+00 3.1232e-03 8.5350e-02 -1.6860e-04 3.6013e-06 1.7137e-05 -6.0000e+00 2.1754e-04 3.6588e-02 0.0000e+00 10 0 0 10 0 0 6.26 21.28 0.30 0.03659 0.03532 2997 845 1 5 0 8.490 26.00 20.00 21.28 27.98 19.0 1032.41 -334 -1117 -1918 -3363 -2407 -1524 313 959 -126 -1758 -1566 -610 -108 686 309 -169 172 698 852 968 548 682 739 780 638 118 -331 -565 220 767 1410 1727 308 -1520 -1714 -1177 -750 107 -118 -678 -933 -719 -804 -411 -279 -452 -719 -803 -411 392 657 809 1028 690 815 847 459 454 663 1097 1207 1565 1382 710 -221 -233 -303 566 913 404 248 41 98 -102 -50 -187 -466 -356 -374 -764 -1112 -1651 -1732 -1268 -832 -591 -405 -150 4 261 228 67 575 733 366 371 422 83 -98 -363 -559 -484 167 -366 -704 -634 -595 -366 103 303 160 291 95 128 139 431 322 278 169 -133 -5 219 304 631 612 239 759 668 384 223 -29 241 -28 -246 -181 4 231 30 -268 -121 -363 -376 -609 -76 -272 -465 -822 -523 -320 70 239 -32 -457 -398 -159 -31 224 113 -66 64 265 333 390 223 275 305 339 291 55 -151 -241 94 324 624 755 145 -720 -761 -521 -368 57 -75 -461 -682 -543 -619 -316 -214 -344 -532 -575 -286 273 482 631 788 552 665 705 387 379 543 897 1029 1348 1284 691 -210 -213 -257 471 827 389 243 42 98 -104 -47 -167 -379 -297 -312 -719 -1101 -1690 -1872 -1434 -954 -723 -494 -186 5 322 258 73 600 753 381 426 508 104 -128 -460 -692 -552 195 -430 -898 -809 -792 -506 142 440 232 416 136 176 175 541 409 354 233 -186 -7 305 410 850 783 306 922 826 508 299 -41 340 -38 -353 -263 7 360 47 -427 -188 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