File name: Pandora135s1_ManhattanNY-CCNY_20220607_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T034206.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20220607_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20220607 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220607T133429.5Z 8193.565619 231 1 8.21 2 45.49 97.56 120.03 42.04 0.00 1 0.00 1 0 17 8.551e-03 5.816e-03 2.692e-03 1.497e-03 2.072152e-01 7.678901e-04 2.462803e-03 -6.000000e+00 4.944111e-03 232.45 -2.00 3.51 -2.00 315.84 0.00e+00 1.979396e-04 7.844305e-05 7.736768e-05 -6.000000e+00 2.194369e-04 285.84 -2.00 20.00 -2.00 315.10 0.00e+00 1.424 0.000 302.00 328.00 3 3.8565e+00 2.0059e-03 1.7929e-02 -6.0000e+00 1.2409e-02 1.9331e-02 2.2369e-03 1.0745e-02 -6.0000e+00 1.3449e-02 -4.6702e-03 1.2780e-03 5.1950e-03 -6.0000e+00 7.9949e-03 7.0533e-04 5.7317e-04 1.4065e-03 -6.0000e+00 3.3452e-03 2.1381e-03 -1.2954e-04 4.2399e-05 1.7123e-05 -6.0000e+00 2.3303e-04 3.7686e-02 0.0000e+00 12 1 1 12 1 1 98.85 21.46 0.19 0.03769 0.03671 20 34 1 5 0 382.890 26.11 20.01 21.46 27.65 18.9 1028.77 -280 -946 -1659 -3527 -1209 -2912 1666 745 851 -2182 -1037 -740 688 424 -102 -244 -243 909 375 1288 390 1070 749 877 727 177 -411 -521 106 310 1596 1345 931 -2191 -1597 -1191 -1122 -411 -343 -674 -1313 -347 -974 -69 -558 -126 -838 -617 -736 606 637 779 1152 527 1136 720 616 167 702 882 1302 1690 1513 973 -359 -286 -505 657 741 484 273 100 63 -61 196 -345 -579 -787 -584 -952 -1030 -1762 -1636 -1161 -683 -607 -206 65 -48 337 191 -171 269 512 167 547 486 101 -76 -272 -557 -769 161 -523 -628 -616 -609 -309 246 350 298 416 287 188 160 452 62 155 101 21 -112 252 460 852 352 -221 808 391 455 70 -21 -24 -172 -260 -21 1 203 248 -159 -62 -438 -247 -660 -68 -235 -409 -836 -251 -601 355 181 224 -581 -278 -198 201 141 -37 -93 -92 351 150 527 162 438 315 388 338 82 -191 -225 44 127 683 598 441 -1056 -716 -533 -559 -226 -217 -470 -958 -259 -725 -51 -413 -95 -615 -436 -523 429 462 600 902 432 919 596 516 139 587 738 1100 1491 1401 942 -340 -253 -424 556 665 464 276 102 64 -60 188 -305 -478 -646 -495 -885 -1012 -1848 -1762 -1276 -784 -727 -252 81 -60 405 221 -185 279 521 178 623 583 126 -100 -344 -687 -898 186 -629 -781 -787 -811 -418 340 500 434 613 409 251 205 563 78 202 139 29 -159 351 634 1141 460 -282 996 481 584 94 -29 -33 -241 -374 -31 1 316 386 -248 -96 -672 -372 -991 SS 20220607T133905.8Z 8193.568817 235 1 47.75 2 44.62 98.43 119.47 43.13 0.00 1 0.00 1 0 17 7.869e-03 5.578e-03 2.022e-04 1.157e-04 2.019019e-01 5.927851e-05 2.403273e-03 -6.000000e+00 4.548834e-03 232.45 -2.00 3.51 -2.00 315.75 0.00e+00 3.316231e-04 5.951001e-06 4.395800e-05 -6.000000e+00 2.019298e-04 285.84 -2.00 20.00 -2.00 315.01 0.00e+00 1.403 0.000 302.00 328.00 3 5.9393e-01 1.5485e-04 1.7597e-02 -6.0000e+00 1.1417e-02 6.5797e-03 1.7270e-04 1.0491e-02 -6.0000e+00 1.2375e-02 -1.9085e-03 9.8562e-05 5.0677e-03 -6.0000e+00 7.3561e-03 1.0046e-04 4.4002e-05 1.3799e-03 -6.0000e+00 3.0773e-03 5.7826e-02 -1.4545e-04 3.2692e-06 1.6663e-05 -6.0000e+00 2.1444e-04 3.8900e-02 0.0000e+00 10 0 0 10 0 0 93.93 21.48 0.27 0.03890 0.03781 3624 1022 1 5 0 12.630 26.11 20.00 21.48 27.91 18.9 1030.74 -334 -1003 -2033 -3253 -2252 -1306 469 995 -41 -1756 -1354 -508 -7 711 288 -139 172 712 793 1017 544 746 710 782 569 150 -369 -595 201 815 1433 1700 304 -1579 -1635 -1176 -691 117 -143 -684 -938 -741 -822 -439 -328 -462 -744 -791 -388 428 650 831 1039 684 805 820 477 450 651 1084 1221 1573 1359 659 -251 -242 -310 617 888 400 237 44 96 -107 -61 -205 -426 -310 -397 -791 -1112 -1685 -1725 -1264 -820 -585 -380 -169 -13 266 223 51 577 764 359 387 424 50 -123 -358 -515 -438 194 -366 -673 -652 -587 -361 118 273 160 272 94 140 161 459 315 305 187 -142 -1 207 281 653 592 261 746 664 367 199 -20 207 -16 -309 -179 -9 249 30 -240 -115 -350 -360 -598 -81 -258 -520 -834 -513 -288 110 261 -11 -479 -360 -139 -2 243 110 -52 66 280 321 424 229 311 303 351 268 73 -174 -261 89 354 601 762 147 -765 -740 -533 -346 64 -93 -475 -700 -570 -605 -344 -256 -357 -559 -575 -273 302 482 655 805 553 663 689 405 379 538 895 1051 1367 1273 646 -239 -222 -264 515 807 387 233 45 97 -109 -58 -184 -346 -259 -331 -745 -1101 -1723 -1861 -1427 -938 -715 -463 -210 -17 327 252 55 599 782 372 442 507 62 -159 -450 -632 -523 225 -428 -855 -827 -777 -496 162 394 229 405 132 190 211 569 395 384 255 -196 -1 286 394 870 749 330 896 812 482 264 -27 288 -23 -439 -269 -14 381 48 -377 -175 -543 -538 -888 SS 20220607T134417.4Z 8193.572424 238 1 47.80 2 43.65 99.44 118.84 44.33 0.00 1 0.00 1 0 17 7.780e-03 5.567e-03 1.982e-04 1.159e-04 1.985145e-01 5.941151e-05 2.360130e-03 -6.000000e+00 4.497419e-03 232.45 -2.00 3.51 -2.00 315.68 0.00e+00 3.409693e-04 5.875890e-06 4.020131e-05 -6.000000e+00 1.996552e-04 285.84 -2.00 20.00 -2.00 314.96 0.00e+00 1.380 0.000 302.00 328.00 3 6.3046e-01 1.5500e-04 1.7300e-02 -6.0000e+00 1.1288e-02 6.4465e-03 1.7273e-04 1.0301e-02 -6.0000e+00 1.2235e-02 -1.7561e-03 9.8550e-05 4.9773e-03 -6.0000e+00 7.2730e-03 6.6881e-05 4.3888e-05 1.3582e-03 -6.0000e+00 3.0425e-03 5.7381e-02 -1.6637e-04 3.2831e-06 1.6562e-05 -6.0000e+00 2.1202e-04 3.9169e-02 0.0000e+00 10 0 0 10 0 0 90.73 21.49 0.28 0.03917 0.03792 3479 981 1 5 0 13.170 26.21 20.01 21.49 28.23 18.9 1033.18 -238 -1092 -1823 -3277 -2059 -1356 551 1099 21 -1682 -1373 -482 -119 758 198 -110 62 710 759 1041 473 669 691 760 570 50 -320 -656 234 726 1492 1669 278 -1579 -1632 -1140 -690 176 -227 -693 -965 -763 -859 -438 -355 -446 -738 -801 -392 401 662 823 1044 621 822 783 482 465 652 1072 1202 1548 1303 635 -300 -211 -327 643 866 372 230 42 99 -115 -66 -201 -372 -330 -345 -799 -1104 -1663 -1745 -1230 -840 -593 -426 -152 -29 242 206 62 574 770 344 383 428 39 -84 -362 -513 -439 216 -375 -668 -629 -592 -354 93 259 128 272 85 140 177 450 307 311 167 -148 -10 200 325 646 609 231 753 646 391 179 -27 228 -11 -283 -191 -3 223 50 -270 -82 -369 -364 -605 -60 -293 -484 -802 -487 -311 134 299 6 -476 -379 -137 -38 267 78 -43 25 288 317 447 205 288 304 352 277 25 -155 -296 98 324 641 767 137 -783 -756 -528 -354 99 -142 -492 -690 -563 -646 -328 -265 -330 -566 -593 -281 288 501 619 823 511 689 669 417 398 547 900 1051 1369 1241 632 -291 -186 -282 543 751 365 229 43 100 -113 -63 -182 -306 -279 -291 -716 -1105 -1719 -1902 -1329 -971 -696 -524 -191 -36 285 235 68 602 795 360 441 515 49 -109 -458 -634 -500 252 -442 -855 -803 -790 -466 128 377 185 388 121 191 221 561 388 394 229 -206 -13 277 437 866 774 294 910 795 515 238 -38 319 -14 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