File name: Pandora135s1_ManhattanNY-CCNY_20220608_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T034257.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20220608_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20220608 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220608T133841.8Z 8194.568540 248 1 26.84 2 44.68 98.22 129.44 35.20 0.00 1 0.00 1 0 17 7.851e-03 5.527e-03 2.428e-04 1.373e-04 2.019999e-01 7.034845e-05 2.402811e-03 -6.000000e+00 4.537742e-03 232.51 -2.00 3.51 -2.00 315.79 0.00e+00 3.237915e-04 7.144875e-06 4.528763e-05 -6.000000e+00 2.015360e-04 285.94 -2.00 20.00 -2.00 315.05 0.00e+00 1.404 0.000 302.00 328.00 3 3.4798e-01 1.8397e-04 1.7612e-02 -6.0000e+00 1.1390e-02 -7.7448e-04 2.0527e-04 1.0497e-02 -6.0000e+00 1.2346e-02 -8.8339e-04 1.1700e-04 5.0708e-03 -6.0000e+00 7.3392e-03 5.5258e-05 5.2278e-05 1.3803e-03 -6.0000e+00 3.0692e-03 7.4046e-02 -1.8726e-04 3.8826e-06 1.6673e-05 -6.0000e+00 2.1394e-04 4.1010e-02 0.0000e+00 10 0 0 10 0 0 69.94 21.64 0.29 0.04101 0.03960 2652 748 1 5 0 9.630 26.32 20.01 21.64 29.58 18.9 1042.02 -343 -942 -2027 -3309 -2268 -1304 455 935 -43 -1718 -1358 -546 -15 640 265 -138 202 715 831 935 558 838 676 817 497 125 -341 -527 275 781 1415 1728 172 -1631 -1650 -1215 -715 106 -105 -690 -955 -737 -788 -425 -344 -452 -774 -794 -407 435 609 829 996 648 810 849 448 473 705 1083 1181 1533 1374 676 -261 -191 -290 649 871 413 201 31 88 -104 -70 -196 -435 -326 -413 -798 -1132 -1699 -1686 -1245 -790 -571 -370 -170 12 255 209 34 587 728 327 360 418 50 -110 -359 -542 -421 192 -392 -670 -619 -572 -347 100 271 135 254 82 125 173 436 293 286 163 -151 -18 208 278 661 581 234 754 643 384 190 -19 211 -6 -238 -184 12 238 45 -247 -111 -371 -363 -615 -81 -237 -508 -832 -507 -282 104 241 -11 -460 -355 -147 -4 215 99 -55 76 277 332 384 231 344 285 362 232 59 -158 -228 120 334 634 764 82 -779 -737 -543 -355 58 -68 -474 -704 -561 -611 -329 -265 -345 -575 -570 -284 303 448 647 764 519 661 706 378 394 576 887 1008 1406 1277 657 -247 -174 -244 537 787 397 209 31 87 -105 -65 -174 -374 -271 -343 -748 -1115 -1729 -1809 -1399 -899 -694 -448 -210 15 311 234 36 607 743 357 410 498 62 -142 -448 -661 -501 221 -457 -849 -783 -755 -475 137 391 203 377 115 169 225 539 368 380 222 -209 -26 286 389 879 772 296 905 788 503 252 -26 294 -8 -337 -278 18 366 70 -388 -170 -574 -542 -914 SS 20220608T133908.9Z 8194.568853 248 2 26.82 2 44.60 98.30 129.39 35.32 0.00 1 0.00 1 0 17 7.859e-03 5.527e-03 2.471e-04 1.402e-04 2.014136e-01 7.189623e-05 2.398073e-03 -6.000000e+00 4.542594e-03 232.51 -2.00 3.51 -2.00 315.81 0.00e+00 3.132191e-04 7.313679e-06 4.644158e-05 -6.000000e+00 2.017450e-04 285.94 -2.00 20.00 -2.00 315.07 0.00e+00 1.402 0.000 302.00 328.00 3 3.8688e-01 1.8777e-04 1.7579e-02 -6.0000e+00 1.1402e-02 -8.6555e-04 2.0914e-04 1.0472e-02 -6.0000e+00 1.2360e-02 -7.5863e-04 1.1949e-04 5.0623e-03 -6.0000e+00 7.3469e-03 1.2222e-04 5.3599e-05 1.3783e-03 -6.0000e+00 3.0726e-03 7.1447e-02 -1.3522e-04 3.9686e-06 1.6602e-05 -6.0000e+00 2.1416e-04 4.0751e-02 0.0000e+00 10 0 0 10 0 0 95.15 21.64 0.28 0.04075 0.03974 2652 748 1 5 0 9.630 26.32 20.01 21.64 29.58 18.9 1042.02 -421 -1008 -1998 -3287 -2328 -1360 474 1011 -80 -1695 -1383 -564 -28 722 290 -124 173 669 800 954 499 725 721 817 571 149 -337 -504 274 795 1365 1657 222 -1626 -1646 -1217 -699 109 -145 -694 -930 -730 -795 -436 -325 -451 -721 -782 -427 418 622 834 999 672 786 821 454 455 676 1071 1225 1535 1374 680 -247 -234 -308 671 866 450 246 53 106 -122 -81 -209 -449 -338 -415 -790 -1120 -1669 -1706 -1201 -798 -569 -361 -166 -5 256 198 63 572 726 331 402 440 40 -135 -342 -549 -442 200 -371 -698 -647 -595 -339 104 284 159 281 86 131 171 425 330 281 166 -175 6 214 283 661 592 261 751 668 354 189 -30 234 -8 -234 -186 1 235 26 -268 -123 -382 -372 -619 -108 -252 -496 -819 -516 -292 108 258 -22 -450 -391 -151 -8 240 108 -49 70 278 316 387 205 295 300 358 263 70 -155 -215 118 337 605 725 105 -768 -727 -538 -343 63 -93 -472 -678 -549 -609 -333 -247 -340 -529 -555 -294 288 452 643 808 531 633 674 377 374 545 866 1032 1390 1261 652 -230 -211 -256 548 772 427 251 55 110 -122 -75 -183 -381 -277 -363 -731 -1089 -1775 -1806 -1330 -896 -682 -454 -203 -6 309 232 67 584 730 357 451 517 52 -172 -443 -660 -518 227 -450 -873 -850 -775 -457 146 404 234 410 119 175 220 518 408 368 222 -250 9 305 390 866 775 325 938 851 457 259 -41 321 -12 -343 -277 1 372 40 -414 -194 -584 -549 -907 SS 20220608T134343.2Z 8194.572027 251 1 26.90 2 43.74 99.18 128.92 36.60 0.00 1 0.00 1 0 17 7.797e-03 5.586e-03 2.342e-04 1.360e-04 1.976129e-01 6.960945e-05 2.350099e-03 -6.000000e+00 4.506586e-03 232.51 -2.00 3.51 -2.00 315.69 0.00e+00 3.447343e-04 6.925734e-06 4.493385e-05 -6.000000e+00 2.001482e-04 285.94 -2.00 20.00 -2.00 314.96 0.00e+00 1.382 0.000 302.00 328.00 3 3.6044e-01 1.8186e-04 1.7291e-02 -6.0000e+00 1.1312e-02 7.1675e-04 2.0283e-04 1.0265e-02 -6.0000e+00 1.2262e-02 -6.3987e-04 1.1557e-04 4.9555e-03 -6.0000e+00 7.2887e-03 -2.8100e-04 5.1443e-05 1.3487e-03 -6.0000e+00 3.0482e-03 7.5327e-02 -1.3662e-04 3.8357e-06 1.6501e-05 -6.0000e+00 2.1247e-04 4.0841e-02 0.0000e+00 10 0 0 10 0 0 95.01 21.65 0.27 0.04084 0.03981 2642 745 1 5 0 9.670 26.32 20.00 21.65 30.00 18.8 1044.40 -489 -798 -2081 -3122 -2247 -1307 647 883 78 -1756 -1139 -676 115 597 362 -140 161 701 776 1073 498 813 672 828 512 218 -406 -523 192 823 1420 1622 276 -1678 -1571 -1266 -628 70 -143 -739 -919 -736 -834 -386 -378 -447 -815 -767 -445 516 591 832 1015 660 806 785 457 438 688 1060 1256 1533 1384 657 -248 -234 -310 641 859 436 211 87 44 -96 -95 -199 -467 -336 -405 -801 -1096 -1679 -1673 -1243 -773 -567 -369 -166 -3 223 200 51 546 774 305 420 375 70 -147 -344 -544 -439 179 -400 -704 -647 -588 -370 112 248 143 253 105 110 188 459 312 315 161 -128 11 235 292 706 596 270 765 631 368 191 -10 209 -10 -259 -194 -15 254 15 -247 -101 -374 -357 -634 -122 -210 -545 -817 -524 -295 155 237 21 -489 -309 -189 35 208 141 -54 63 280 319 453 213 344 291 377 245 107 -194 -232 86 361 602 735 134 -819 -717 -579 -318 39 -94 -518 -690 -571 -618 -304 -297 -347 -616 -560 -315 366 441 658 789 535 666 661 390 370 570 878 1084 1423 1301 645 -236 -215 -264 534 783 422 208 88 45 -98 -90 -178 -379 -280 -338 -755 -1085 -1716 -1801 -1402 -883 -692 -449 -206 -3 273 226 55 567 791 315 478 447 86 -189 -429 -663 -521 207 -467 -892 -819 -776 -507 152 358 204 374 147 149 245 566 390 416 219 -176 16 322 407 935 790 340 916 771 481 252 -14 290 -14 -365 -290 -23 387 23 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