File name: Pandora135s1_ManhattanNY-CCNY_20220615_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T034728.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20220615_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20220615 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220615T134005.0Z 8201.569503 341 1 26.67 2 44.43 97.69 125.53 262.56 0.00 1 0.00 1 0 17 7.734e-03 5.604e-03 2.238e-04 1.349e-04 1.885119e-01 6.937905e-05 2.238796e-03 -6.000000e+00 4.475378e-03 232.91 -2.00 3.51 -2.00 315.57 0.00e+00 3.548597e-04 6.689804e-06 3.995945e-05 -6.000000e+00 1.991132e-04 286.63 -2.00 20.00 -2.00 314.83 0.00e+00 1.398 0.000 302.00 328.00 3 3.5024e-01 1.8097e-04 1.7127e-02 -6.0000e+00 1.1242e-02 -7.2230e-06 2.0152e-04 9.8112e-03 -6.0000e+00 1.2183e-02 -6.2458e-04 1.1490e-04 4.7238e-03 -6.0000e+00 7.2421e-03 -2.2627e-04 5.0783e-05 1.2846e-03 -6.0000e+00 3.0268e-03 7.6477e-02 -2.0677e-04 3.8096e-06 1.5875e-05 -6.0000e+00 2.1081e-04 4.3788e-02 0.0000e+00 10 0 0 10 0 0 30.10 21.73 0.27 0.04379 0.04223 2605 735 1 5 0 9.810 26.41 19.99 21.73 30.25 19.3 1046.77 -291 -813 -1771 -3151 -2039 -1184 641 1061 11 -1663 -1361 -559 -77 744 307 -182 178 734 824 1040 475 715 682 786 559 128 -373 -608 92 710 1428 1652 174 -1762 -1701 -1334 -763 59 -224 -645 -897 -690 -783 -373 -324 -434 -738 -705 -404 439 628 848 1030 634 801 802 469 435 682 1086 1226 1563 1372 675 -282 -272 -412 534 798 393 283 98 126 -58 -46 -258 -526 -483 -488 -848 -1127 -1685 -1720 -1222 -782 -524 -321 -113 31 278 206 11 512 672 308 369 437 104 -66 -330 -557 -476 179 -412 -686 -646 -610 -346 126 271 185 305 109 108 166 419 281 273 181 -104 33 259 305 650 607 213 717 633 363 189 -49 183 -47 -254 -185 -4 250 57 -238 -94 -340 -357 -665 -78 -230 -495 -808 -507 -285 164 304 3 -493 -393 -166 -25 274 116 -73 73 307 355 460 212 316 309 374 279 65 -185 -281 39 323 627 774 88 -886 -799 -629 -399 33 -153 -464 -691 -514 -595 -282 -244 -345 -570 -525 -292 317 477 683 814 522 671 685 406 372 573 913 1075 1385 1308 670 -271 -252 -353 449 734 384 280 100 128 -60 -44 -232 -430 -406 -410 -804 -1120 -1727 -1856 -1380 -896 -640 -391 -141 38 341 232 12 531 687 319 420 520 129 -85 -410 -677 -564 206 -481 -869 -818 -806 -474 171 389 263 448 152 145 214 513 350 359 244 -142 46 353 424 857 801 267 855 769 471 248 -67 251 -66 -356 -275 -6 379 88 -368 -142 -520 -527 -979 SS 20220615T134032.0Z 8201.569815 341 2 26.78 2 44.35 97.77 125.61 262.62 0.00 1 0.00 1 0 17 7.724e-03 5.612e-03 2.224e-04 1.337e-04 1.884012e-01 6.867111e-05 2.237217e-03 -6.000000e+00 4.469676e-03 232.91 -2.00 3.51 -2.00 315.59 0.00e+00 3.654937e-04 6.647947e-06 4.177636e-05 -6.000000e+00 1.988598e-04 286.63 -2.00 20.00 -2.00 314.86 0.00e+00 1.396 0.000 302.00 328.00 3 3.4069e-01 1.7918e-04 1.7105e-02 -6.0000e+00 1.1228e-02 5.7672e-05 1.9953e-04 9.8002e-03 -6.0000e+00 1.2167e-02 -6.4483e-04 1.1367e-04 4.7199e-03 -6.0000e+00 7.2329e-03 -3.3808e-04 5.0296e-05 1.2845e-03 -6.0000e+00 3.0229e-03 7.7375e-02 -1.9981e-04 3.7798e-06 1.5556e-05 -6.0000e+00 2.1054e-04 4.3800e-02 0.0000e+00 10 0 0 10 0 0 13.56 21.73 0.26 0.04380 0.04230 2605 735 1 5 0 9.810 26.41 20.00 21.73 30.25 19.3 1047.76 -264 -826 -1842 -3059 -2066 -1211 613 1001 19 -1691 -1325 -531 -93 657 277 -209 211 741 841 1050 505 736 718 772 557 117 -405 -602 110 732 1382 1663 237 -1732 -1709 -1300 -729 92 -156 -668 -919 -713 -785 -401 -286 -445 -755 -735 -390 465 638 839 1028 631 752 801 477 463 670 1091 1247 1569 1369 674 -279 -302 -398 537 814 377 286 103 146 -41 -86 -271 -571 -504 -512 -850 -1162 -1693 -1698 -1229 -753 -526 -331 -117 39 255 230 16 527 646 274 358 436 82 -63 -304 -565 -467 158 -411 -701 -660 -609 -363 141 296 196 297 101 116 176 388 283 292 209 -83 51 250 333 653 577 234 738 624 373 175 -53 199 -54 -258 -196 11 240 32 -239 -105 -353 -366 -635 -71 -234 -516 -786 -515 -293 157 264 5 -503 -383 -158 -31 242 105 -84 86 311 363 465 226 326 326 368 278 60 -201 -278 47 309 608 780 119 -872 -804 -613 -382 53 -99 -482 -665 -532 -597 -304 -216 -332 -585 -548 -282 337 486 635 814 520 632 685 413 396 563 919 1096 1393 1307 671 -269 -264 -342 453 749 368 284 106 148 -43 -81 -244 -467 -424 -431 -807 -1157 -1738 -1835 -1391 -864 -644 -404 -146 48 314 260 17 548 661 284 409 520 102 -81 -378 -686 -553 183 -481 -890 -837 -805 -497 192 426 278 437 141 156 227 476 352 384 282 -113 71 342 463 862 762 294 881 759 485 229 -72 274 -76 -362 -291 17 364 50 -371 -159 -541 -542 -936 SS 20220615T134521.8Z 8201.573169 344 1 26.73 2 43.44 98.70 126.47 263.30 0.00 1 0.00 1 0 17 7.722e-03 5.643e-03 2.162e-04 1.320e-04 1.854135e-01 6.793001e-05 2.201926e-03 -6.000000e+00 4.468365e-03 232.91 -2.00 3.51 -2.00 315.52 0.00e+00 3.646795e-04 6.477287e-06 4.121852e-05 -6.000000e+00 1.988034e-04 286.63 -2.00 20.00 -2.00 314.80 0.00e+00 1.376 0.000 302.00 328.00 3 3.3291e-01 1.7705e-04 1.6843e-02 -6.0000e+00 1.1224e-02 -1.8849e-04 1.9704e-04 9.6423e-03 -6.0000e+00 1.2163e-02 -4.5056e-04 1.1229e-04 4.6433e-03 -6.0000e+00 7.2308e-03 -5.3536e-04 4.9558e-05 1.2646e-03 -6.0000e+00 3.0220e-03 8.0070e-02 -2.0143e-04 3.7315e-06 1.5585e-05 -6.0000e+00 2.1048e-04 4.3881e-02 0.0000e+00 10 0 0 10 0 0 15.10 21.73 0.27 0.04388 0.04237 2704 763 1 5 0 9.440 26.41 20.00 21.73 30.85 19.3 1051.77 -189 -786 -1812 -3005 -2105 -1234 591 1116 16 -1723 -1267 -542 -42 735 294 -191 173 766 783 991 529 705 722 781 521 93 -391 -596 137 683 1438 1683 195 -1703 -1706 -1320 -745 111 -194 -688 -916 -701 -768 -376 -301 -461 -745 -775 -383 479 611 853 1044 625 768 823 463 458 684 1087 1205 1547 1335 681 -280 -294 -390 552 823 376 274 99 160 -33 -87 -266 -581 -505 -514 -837 -1166 -1696 -1706 -1213 -796 -521 -332 -100 48 283 231 28 482 650 256 355 430 69 -75 -339 -555 -496 148 -406 -722 -657 -611 -356 128 287 167 305 113 120 160 423 304 319 227 -66 75 267 328 654 590 223 740 656 385 169 -42 192 -54 -294 -194 -20 245 32 -236 -94 -343 -360 -673 -52 -228 -521 -790 -537 -305 155 301 5 -524 -375 -165 -14 276 113 -78 72 326 344 447 241 318 333 378 265 48 -197 -279 59 292 640 799 99 -866 -811 -629 -394 64 -124 -501 -669 -528 -589 -287 -229 -347 -581 -583 -279 349 468 692 830 518 648 707 403 394 578 920 1063 1379 1280 680 -271 -274 -335 466 758 367 272 101 162 -34 -82 -240 -476 -425 -432 -794 -1160 -1739 -1841 -1370 -912 -638 -405 -124 58 348 261 30 500 664 264 404 511 85 -96 -420 -672 -586 170 -473 -914 -830 -805 -486 174 411 248 447 157 159 206 515 376 417 305 -89 105 363 454 860 776 279 877 793 497 221 -56 263 -76 -409 -287 -31 369 49 -364 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