File name: Pandora135s1_ManhattanNY-CCNY_20220702_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T041516.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20220702_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20220702 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220702T133858.2Z 8218.568730 201 1 12.87 2 45.49 97.17 78.77 73.75 0.00 1 0.00 1 0 17 8.585e-03 5.872e-03 4.715e-03 2.441e-03 2.000527e-01 1.275665e-03 2.408508e-03 -6.000000e+00 5.055116e-03 232.89 -2.00 3.51 -2.00 316.06 0.00e+00 3.102318e-04 1.363177e-04 7.324526e-05 -6.000000e+00 2.238354e-04 288.24 -2.00 20.00 -2.00 315.29 0.00e+00 1.424 0.000 302.00 328.00 3 5.1341e+00 3.3371e-03 1.7779e-02 -6.0000e+00 1.2698e-02 1.6434e-03 3.6989e-03 1.0496e-02 -6.0000e+00 1.3675e-02 6.0928e-04 2.1327e-03 5.0758e-03 -6.0000e+00 8.1338e-03 2.6195e-04 9.9263e-04 1.3948e-03 -6.0000e+00 3.5000e-03 6.0386e-04 -4.7228e-05 6.9538e-05 1.6656e-05 -6.0000e+00 2.3460e-04 5.2115e-02 0.0000e+00 12 1 1 12 1 1 99.35 22.27 0.16 0.05211 0.05176 10 11 1 5 0 1154.730 26.83 20.00 22.27 33.81 19.6 1068.05 91 544 -2112 -2572 -1239 -2752 1185 1323 626 -1732 -970 -1733 -248 1234 -679 -477 597 1009 -98 781 495 1445 516 879 454 311 -525 462 1161 899 1288 1673 -122 -2289 -1246 -1222 324 -544 -568 -1040 -542 -625 -1521 -769 -363 -617 -1258 -1360 -987 1330 573 485 749 682 1260 853 582 108 761 727 1588 1777 1613 847 -219 -564 -19 226 859 654 -91 -137 422 -31 7 -494 -425 -442 -489 -738 -1358 -1853 -1163 -862 -471 -376 -74 115 238 302 19 -66 321 571 -5 257 528 536 -135 -325 -545 -776 78 -780 -367 -664 -704 -316 77 331 181 725 206 218 284 -61 -25 -105 -69 341 -88 220 248 697 566 14 379 242 581 -109 -299 243 88 -356 -318 264 497 -10 -195 -135 -337 -669 900000 20 123 -479 -530 -237 -527 237 286 147 -422 -230 -433 -68 379 -226 -168 213 369 -37 304 194 557 206 369 193 134 -229 185 434 335 506 702 -55 -1030 -520 -518 152 -294 -352 -704 -376 -448 -1119 -561 -263 -443 -881 -953 -672 897 412 359 579 548 994 688 475 88 622 599 1316 1586 1500 794 -205 -495 -16 188 760 630 -92 -141 428 -30 6 -421 -341 -356 -410 -675 -1346 -1941 -1235 -961 -547 -453 -94 143 302 363 22 -72 329 582 -5 293 644 692 -175 -419 -670 -911 89 -935 -459 -876 -944 -439 109 481 273 1072 296 295 361 -77 -32 -138 -96 484 -128 311 350 956 738 17 476 302 775 -150 -418 342 126 -524 -484 416 780 -16 -313 -216 -522 -1030 900000 SS 20220702T134809.3Z 8218.575107 208 1 3.11 2 43.77 98.92 77.16 75.12 0.00 1 0.00 1 0 17 9.205e-03 6.670e-03 6.033e-03 3.573e-03 1.956396e-01 1.873879e-03 2.380080e-03 -6.000000e+00 5.408232e-03 232.89 -2.00 3.51 -2.00 315.59 0.00e+00 2.499156e-04 1.805203e-04 4.723821e-05 -6.000000e+00 2.398592e-04 288.24 -2.00 20.00 -2.00 314.86 0.00e+00 1.383 0.000 302.00 328.00 3 4.3948e+00 4.8794e-03 1.7325e-02 -6.0000e+00 1.3584e-02 2.3733e-02 5.3946e-03 1.0295e-02 -6.0000e+00 1.4641e-02 -3.8188e-03 3.0947e-03 4.9848e-03 -6.0000e+00 8.7095e-03 1.9923e-03 1.4121e-03 1.3638e-03 -6.0000e+00 3.7365e-03 1.3186e-03 -2.3034e-03 1.0116e-04 1.7188e-05 -6.0000e+00 2.5175e-04 6.9536e-02 0.0000e+00 12 9 1 12 1 1 -26.01 22.28 0.17 0.06954 0.05223 3 18 1 5 0 734.290 26.83 20.00 22.28 33.99 19.6 1069.22 -919 -384 -197 -3013 -462 -2291 2482 1673 -769 -2454 -1875 121 677 1765 -219 -386 712 688 984 -179 235 -664 57 546 953 663 350 900 508 851 2109 1752 -491 -2115 -1874 364 -1146 919 -934 -962 -1080 -420 -1775 -1058 -228 -1197 -238 -767 505 352 686 83 938 1117 1177 921 149 99 260 1414 811 2056 1038 780 -379 -1245 -262 191 1215 476 547 64 778 -112 210 -840 -79 -488 -894 -931 -1686 -2125 -1224 -778 -704 -322 -306 440 242 403 716 -682 323 681 -315 -152 1230 637 160 -217 -354 -954 -17 -510 -693 -453 -410 -464 -213 312 306 588 334 21 -153 127 77 -64 69 -64 223 243 647 215 757 -9 809 127 48 76 -552 283 -518 -152 23 828 86 20 -306 -107 -163 -830 900000 -247 -108 -54 -761 -107 -533 598 438 -223 -730 -543 36 214 622 -84 -156 291 289 425 -80 105 -298 26 252 458 325 166 407 217 359 927 827 -240 -1028 -883 170 -588 530 -627 -681 -814 -324 -1368 -835 -178 -929 -177 -572 363 257 510 66 748 923 991 791 130 85 220 1191 698 1885 1000 755 -364 -1127 -224 163 1093 470 561 66 805 -111 197 -755 -66 -398 -763 -866 -1703 -2268 -1323 -858 -812 -385 -384 558 303 491 819 -733 334 698 -340 -176 1465 809 205 -274 -426 -1098 -19 -614 -880 -586 -540 -635 -298 448 443 856 471 27 -196 159 95 -83 94 -90 315 337 885 288 984 -12 978 158 62 102 -749 386 -726 -217 34 1260 132 32 -479 -162 -244 -1241 900000 SS 20220702T135220.2Z 8218.578011 211 1 41.32 2 42.99 99.74 76.42 75.74 0.00 1 0.00 1 0 17 7.880e-03 5.656e-03 2.883e-04 1.670e-04 1.908173e-01 8.729068e-05 2.295332e-03 -6.000000e+00 4.639472e-03 232.89 -2.00 3.51 -2.00 315.67 0.00e+00 3.091720e-04 8.537016e-06 7.455084e-05 -6.000000e+00 2.054361e-04 288.24 -2.00 20.00 -2.00 314.92 0.00e+00 1.365 0.000 302.00 328.00 3 1.1786e+00 2.2752e-04 1.6988e-02 -6.0000e+00 1.1654e-02 -1.9788e-03 2.5168e-04 9.9684e-03 -6.0000e+00 1.2551e-02 3.6340e-04 1.4441e-04 4.8224e-03 -6.0000e+00 7.4652e-03 -5.6708e-04 6.6149e-05 1.3255e-03 -6.0000e+00 3.2120e-03 3.4100e-02 6.5272e-05 4.7430e-06 1.5959e-05 -6.0000e+00 2.1533e-04 5.2624e-02 0.0000e+00 10 0 0 10 0 0 99.94 22.30 0.26 0.05262 0.05311 2442 689 1 5 0 16.300 26.83 20.00 22.30 34.08 19.6 1070.87 -154 -699 -1868 -3127 -2228 -1178 698 1102 60 -1723 -1322 -478 5 793 265 -108 169 714 863 1065 447 677 660 846 663 228 -258 -439 214 757 1447 1695 108 -1797 -1727 -1417 -823 39 -178 -667 -880 -727 -801 -409 -365 -513 -813 -867 -511 394 574 784 1008 616 793 798 425 375 563 1028 1189 1581 1426 750 -241 -315 -353 631 901 525 429 214 236 -27 -92 -371 -713 -607 -616 -929 -1139 -1656 -1610 -1105 -676 -395 -198 43 165 359 213 -46 406 541 226 420 472 90 -40 -339 -645 -606 4 -578 -778 -700 -670 -385 102 338 266 396 223 152 161 344 307 275 285 -17 178 335 405 702 549 108 545 442 249 85 -68 111 -94 -405 -229 13 244 42 -254 -169 -437 -528 900000 -40 -193 -507 -775 -494 -255 161 286 17 -499 -374 -140 2 264 98 -42 68 292 363 461 195 293 293 395 324 113 -125 -196 89 312 625 781 53 -881 -792 -658 -427 22 -111 -470 -660 -562 -630 -320 -285 -395 -608 -626 -358 278 426 617 829 493 645 661 356 310 458 839 1016 1451 1317 719 -222 -281 -292 517 810 498 437 223 243 -26 -89 -321 -603 -498 -544 -863 -1104 -1747 -1785 -1209 -792 -466 -245 54 204 445 242 -51 406 538 242 465 577 113 -51 -424 -793 -690 5 -692 -1009 -900 -899 -535 140 491 400 584 311 204 211 429 389 350 392 -24 248 459 567 934 735 138 662 550 331 114 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