File name: Pandora135s1_ManhattanNY-CCNY_20220811_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T053709.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20220811_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20220811 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220811T132252.1Z 8258.557547 292 1 47.16 2 53.51 102.06 135.64 279.27 0.00 1 0.00 1 0 17 1.343e-02 6.366e-03 7.252e-03 2.638e-03 2.322085e-01 1.337859e-03 2.724441e-03 -6.000000e+00 7.743806e-03 231.94 -2.00 3.51 -2.00 317.13 0.00e+00 2.966377e-04 1.864312e-04 1.004570e-04 -6.000000e+00 3.508249e-04 290.10 -2.00 20.00 -2.00 316.24 0.00e+00 1.677 0.000 302.00 328.00 3 6.0600e+00 3.5574e-03 2.0712e-02 -6.0000e+00 1.9382e-02 2.6247e-02 4.0009e-03 1.2055e-02 -6.0000e+00 2.1007e-02 5.5940e-03 2.3461e-03 5.8072e-03 -6.0000e+00 1.2525e-02 -5.8359e-03 1.1238e-03 1.5703e-03 -6.0000e+00 5.2632e-03 1.7547e-04 -4.3575e-05 7.6154e-05 1.7230e-05 -6.0000e+00 3.6597e-04 4.4109e-02 0.0000e+00 11 1 0 11 8 0 99.96 21.75 -0.01 0.04411 0.04378 24 7 1 5 0 1964.690 26.41 19.99 21.75 29.26 20.2 1030.92 494 -840 -3754 -5968 2735 -8526 -1610 -1538 890 -2073 -736 -1406 1017 2915 -1706 1633 -75 51 938 -543 651 117 1414 -593 -77 -789 274 1436 1441 -167 1033 874 187 -3220 -2551 -942 -790 1571 157 -500 -713 -1504 -956 -1748 230 209 -44 -1121 -98 1545 245 160 1123 652 1438 1508 48 581 185 1079 1686 2184 1459 435 -70 -183 -623 -384 1029 392 414 -120 374 -21 228 -958 -921 -939 -867 -1450 -1155 -1614 -2036 -554 -532 -178 163 517 200 527 397 -405 -454 13 70 183 799 438 132 -309 -605 -579 30 -576 -1056 -441 -744 -135 57 289 368 281 -191 -107 491 -85 40 -368 453 -209 600 423 270 729 352 73 365 223 394 203 -78 260 101 -815 -297 261 576 529 -230 97 -230 -816 -679 65 -119 -541 -801 315 -1084 -208 -216 133 -325 -112 -227 181 581 -399 395 -19 14 253 -153 183 33 404 -183 -25 -261 87 420 397 -47 305 279 64 -1123 -829 -304 -285 660 77 -270 -414 -912 -588 -1086 140 126 -26 -669 -57 895 152 103 752 457 1024 1095 35 425 133 776 1260 1755 1233 386 -60 -149 -473 -290 843 352 387 -115 354 -20 196 -769 -672 -690 -662 -1257 -1077 -1595 -2132 -602 -602 -214 200 643 247 635 454 -422 -449 13 74 207 961 561 175 -399 -746 -679 34 -700 -1352 -589 -1011 -191 85 440 583 442 -286 -151 652 -109 52 -504 644 -316 912 632 391 1034 476 94 462 289 531 291 -113 383 152 -1260 -485 443 969 908 -396 167 -382 -1313 -1083 SS 20220811T132806.9Z 8258.561191 295 1 43.20 2 52.54 103.08 136.56 280.28 0.00 1 0.00 1 0 17 8.242e-03 5.387e-03 7.189e-04 3.070e-04 2.207024e-01 1.557898e-04 2.612467e-03 -6.000000e+00 4.752583e-03 231.94 -2.00 3.51 -2.00 316.67 0.00e+00 3.298507e-04 1.942515e-05 9.741970e-05 -6.000000e+00 2.153198e-04 290.10 -2.00 20.00 -2.00 315.80 0.00e+00 1.640 0.000 302.00 328.00 3 1.9874e+00 4.1040e-04 2.0055e-02 -6.0000e+00 1.1895e-02 5.8318e-04 4.6048e-04 1.1468e-02 -6.0000e+00 1.2893e-02 5.9410e-03 2.6610e-04 5.5358e-03 -6.0000e+00 7.6868e-03 -3.3492e-03 1.2465e-04 1.5026e-03 -6.0000e+00 3.2300e-03 1.1034e-02 9.9446e-05 8.7852e-06 1.6820e-05 -6.0000e+00 2.2462e-04 4.4510e-02 0.0000e+00 10 0 0 10 0 0 100.00 21.75 0.25 0.04451 0.04526 1558 439 1 5 0 27.180 26.41 20.00 21.75 29.32 20.2 1030.89 -115 -977 -1667 -3743 -1869 -2116 883 487 74 -2143 -1233 -911 -254 695 -96 -172 -239 713 396 993 59 661 533 798 603 154 -299 -775 253 574 1735 1466 329 -2031 -1793 -1426 -825 78 -193 -637 -1061 -714 -934 -351 -360 -414 -815 -867 -484 435 626 715 1064 506 823 737 488 306 682 1014 1266 1689 1489 828 -243 -148 -356 730 865 554 388 174 133 -59 -166 -420 -653 -650 -452 -965 -1036 -1674 -1611 -1120 -644 -372 -111 96 229 463 311 80 443 713 205 381 493 227 -129 -449 -695 -755 71 -563 -783 -749 -618 -384 128 350 222 352 133 96 46 311 176 222 129 -84 57 314 323 610 485 -22 565 480 333 148 15 181 7 -371 -158 64 363 130 -213 -20 -333 -274 -596 -19 -171 -288 -601 -266 -297 131 82 14 -409 -230 -177 -55 171 -27 -51 -73 222 128 329 20 220 183 289 229 60 -113 -275 84 188 599 547 132 -820 -677 -543 -350 36 -106 -397 -655 -455 -608 -228 -233 -266 -511 -571 -310 281 428 481 750 373 619 567 380 235 514 768 1000 1436 1269 738 -210 -126 -282 570 742 497 375 174 130 -55 -155 -351 -498 -482 -360 -870 -967 -1711 -1735 -1264 -726 -448 -140 123 290 557 344 85 436 696 216 442 592 299 -176 -594 -851 -855 84 -662 -998 -1003 -864 -523 182 529 348 547 196 130 60 393 226 300 177 -122 84 454 452 865 654 -28 691 601 448 212 22 256 10 -565 -254 101 587 214 -351 -32 -548 -436 -944 SS 20220811T133226.8Z 8258.564199 298 1 42.34 2 51.74 103.94 137.32 281.12 0.00 1 0.00 1 0 17 8.216e-03 5.576e-03 3.284e-04 1.683e-04 2.170677e-01 8.594369e-05 2.577710e-03 -6.000000e+00 4.737389e-03 231.94 -2.00 3.51 -2.00 316.14 0.00e+00 3.285223e-04 9.569756e-06 7.753332e-05 -6.000000e+00 2.146476e-04 290.10 -2.00 20.00 -2.00 315.32 0.00e+00 1.611 0.000 302.00 328.00 3 9.9284e-01 2.2490e-04 1.9708e-02 -6.0000e+00 1.1857e-02 -5.6709e-03 2.5124e-04 1.1277e-02 -6.0000e+00 1.2852e-02 2.3517e-03 1.4403e-04 5.4350e-03 -6.0000e+00 7.6625e-03 -9.9131e-04 6.5803e-05 1.4690e-03 -6.0000e+00 3.2194e-03 3.1005e-02 -4.3096e-05 4.7788e-06 1.7594e-05 -6.0000e+00 2.2393e-04 4.5215e-02 0.0000e+00 10 0 0 10 0 0 98.68 21.74 0.25 0.04521 0.04489 1985 560 1 5 0 20.710 26.41 20.00 21.74 29.41 20.3 1031.85 -410 -914 -2014 -3389 -2595 -1747 261 740 -214 -1925 -1537 -763 -134 684 314 -240 240 625 777 1002 417 708 708 843 661 239 -294 -473 38 708 1371 1649 89 -1846 -1893 -1482 -919 62 -129 -631 -851 -725 -761 -343 -259 -455 -721 -776 -453 461 627 772 970 602 757 762 414 350 549 1024 1245 1661 1527 790 -191 -217 -310 587 928 461 361 112 137 -106 -201 -391 -727 -644 -649 -948 -1157 -1703 -1695 -1134 -664 -411 -170 67 209 393 298 0 455 613 228 392 465 79 -94 -396 -691 -637 80 -549 -804 -696 -650 -358 119 307 267 343 139 126 121 330 223 234 189 -75 105 307 360 676 543 107 614 553 354 232 7 224 -19 -338 -184 34 308 71 -212 -128 -357 -367 -638 -87 -206 -452 -700 -480 -315 50 160 -51 -472 -369 -191 -34 197 101 -83 85 228 292 388 163 275 283 355 270 100 -120 -194 15 270 551 712 38 -795 -829 -653 -416 33 -76 -424 -573 -505 -540 -243 -182 -319 -492 -550 -313 321 430 564 744 482 619 636 328 293 451 842 1002 1438 1426 726 -181 -188 -265 497 807 426 359 115 139 -102 -191 -333 -601 -517 -560 -866 -1112 -1790 -1774 -1243 -778 -487 -212 85 262 467 343 0 460 615 247 442 549 103 -120 -515 -834 -749 92 -671 -1011 -918 -850 -486 170 441 398 506 194 170 158 410 282 312 259 -109 154 443 502 898 722 135 782 682 469 311 10 317 -28 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