File name: Pandora135s1_ManhattanNY-CCNY_20220831_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T063827.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20220831_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20220831 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220831T130849.6Z 8278.547796 146 1 41.51 2 59.58 106.27 107.07 88.34 0.00 1 0.00 1 0 17 9.767e-03 5.383e-03 5.006e-04 1.773e-04 2.681180e-01 8.959864e-05 3.179580e-03 -6.000000e+00 5.605525e-03 230.49 -2.00 3.51 -2.00 317.09 0.00e+00 3.875085e-04 1.254393e-05 1.234169e-04 -6.000000e+00 2.540186e-04 289.02 -2.00 20.00 -2.00 316.23 0.00e+00 1.967 0.000 302.00 328.00 3 6.1492e-01 2.3711e-04 2.4097e-02 -6.0000e+00 1.3985e-02 -7.0185e-03 2.6686e-04 1.3888e-02 -6.0000e+00 1.5175e-02 3.8760e-04 1.5737e-04 6.7369e-03 -6.0000e+00 9.0528e-03 -7.8273e-04 7.6088e-05 1.8429e-03 -6.0000e+00 3.8140e-03 2.9393e-02 -1.8904e-04 5.0444e-06 1.9954e-05 -6.0000e+00 2.6606e-04 4.0254e-02 0.0000e+00 10 0 0 10 0 0 96.86 21.53 0.24 0.04025 0.03883 2328 657 1 5 0 17.240 26.21 20.00 21.53 28.56 20.4 1024.75 -680 -1513 -2642 -4359 -3735 -3248 -1007 -133 -1122 -2661 -2586 -1389 -902 295 -14 -301 -61 519 695 806 333 477 605 700 546 54 -488 -865 -224 522 1216 1676 127 -1861 -2043 -1583 -901 28 -83 -599 -803 -557 -642 -253 -99 -260 -540 -673 -346 518 715 899 1104 712 797 879 447 363 564 1046 1301 1674 1572 874 -207 -175 -268 629 901 467 323 93 109 -193 -217 -390 -605 -519 -565 -893 -1145 -1678 -1708 -1183 -776 -507 -292 -63 96 322 317 67 528 707 361 448 495 87 -99 -436 -707 -647 59 -482 -816 -698 -637 -360 144 357 216 345 154 133 126 396 258 210 102 -191 12 268 327 627 520 97 661 613 350 225 -6 221 -31 -286 -188 15 298 91 -229 -123 -378 -325 -558 -85 -204 -359 -552 -426 -363 -120 -18 -166 -410 -396 -223 -164 61 -3 -71 -15 131 182 218 91 130 170 209 173 18 -156 -260 -63 147 367 549 45 -674 -697 -543 -343 12 -41 -342 -460 -331 -391 -154 -60 -157 -321 -392 -198 301 442 594 770 522 560 632 327 263 428 793 961 1336 1362 750 -174 -145 -207 483 759 418 311 93 107 -181 -188 -323 -458 -411 -451 -812 -1097 -1664 -1793 -1302 -862 -602 -363 -76 120 384 369 71 546 729 379 522 606 111 -133 -566 -898 -755 70 -577 -1061 -904 -862 -508 203 538 324 516 232 184 169 533 334 288 143 -283 18 392 464 892 705 125 859 818 478 330 -8 327 -48 -437 -304 25 490 152 -385 -210 -622 -515 -878 SS 20220831T131401.3Z 8278.551404 149 1 41.05 2 58.64 107.29 106.14 89.19 0.00 1 0.00 1 0 17 9.463e-03 5.375e-03 4.509e-04 1.680e-04 2.610966e-01 8.475302e-05 3.097809e-03 -6.000000e+00 5.430704e-03 230.49 -2.00 3.51 -2.00 317.00 0.00e+00 3.858359e-04 1.158395e-05 1.175340e-04 -6.000000e+00 2.461133e-04 289.02 -2.00 20.00 -2.00 316.15 0.00e+00 1.914 0.000 302.00 328.00 3 5.5989e-01 2.2402e-04 2.3451e-02 -6.0000e+00 1.3549e-02 -7.1671e-03 2.5197e-04 1.3511e-02 -6.0000e+00 1.4702e-02 5.1001e-04 1.4785e-04 6.5546e-03 -6.0000e+00 8.7706e-03 -6.7823e-04 7.1129e-05 1.7931e-03 -6.0000e+00 3.6948e-03 3.3062e-02 -2.2452e-04 4.7731e-06 1.9555e-05 -6.0000e+00 2.5779e-04 4.0777e-02 0.0000e+00 10 0 0 10 0 0 10.71 21.54 0.24 0.04078 0.03909 2536 715 1 5 0 15.590 26.21 20.00 21.54 29.18 20.5 1029.38 -762 -1192 -2608 -4051 -3659 -2787 -936 -62 -957 -2784 -2412 -1406 -666 275 142 -334 109 521 679 845 292 550 551 745 582 118 -471 -719 -220 570 1221 1642 135 -1931 -2042 -1628 -959 54 -128 -566 -773 -550 -623 -262 -91 -271 -550 -681 -348 522 706 888 1127 722 849 890 458 369 570 1042 1265 1664 1561 852 -195 -176 -286 612 901 434 353 80 108 -157 -222 -390 -675 -540 -588 -854 -1102 -1663 -1701 -1211 -730 -523 -288 -32 95 320 302 19 509 645 329 452 495 109 -133 -418 -713 -636 76 -457 -791 -689 -624 -349 135 368 211 348 184 149 107 387 239 210 106 -164 14 263 327 648 500 106 663 603 331 195 -1 247 -30 -320 -174 5 309 89 -254 -109 -381 -325 -563 -102 -172 -378 -546 -444 -331 -119 -9 -150 -457 -391 -239 -128 60 35 -82 28 138 186 239 84 157 162 232 192 40 -157 -224 -65 167 382 557 50 -722 -718 -575 -377 23 -66 -309 -454 -335 -389 -164 -57 -168 -335 -406 -204 309 444 598 801 502 606 649 339 271 410 750 950 1348 1372 741 -167 -147 -223 474 765 392 343 81 107 -149 -194 -325 -516 -431 -473 -779 -1059 -1654 -1791 -1336 -814 -622 -359 -38 119 383 351 20 527 666 345 526 604 138 -177 -540 -903 -740 90 -546 -1026 -890 -843 -491 190 551 315 517 274 215 143 517 307 285 147 -241 21 383 461 916 674 144 855 799 449 284 -1 362 -46 -506 -279 8 526 147 -422 -184 -621 -510 -877 SS 20220831T131915.3Z 8278.555038 152 1 40.84 2 57.70 108.33 105.20 90.03 0.00 1 0.00 1 0 17 9.288e-03 5.434e-03 4.104e-04 1.623e-04 2.533906e-01 8.199503e-05 3.010060e-03 -6.000000e+00 5.330049e-03 230.49 -2.00 3.51 -2.00 316.85 0.00e+00 3.951795e-04 1.076895e-05 1.098687e-04 -6.000000e+00 2.415574e-04 289.02 -2.00 20.00 -2.00 316.00 0.00e+00 1.864 0.000 302.00 328.00 3 5.5112e-01 2.1596e-04 2.2812e-02 -6.0000e+00 1.3298e-02 -6.8097e-03 2.4261e-04 1.3105e-02 -6.0000e+00 1.4429e-02 4.9379e-04 1.4194e-04 6.3538e-03 -6.0000e+00 8.6081e-03 -6.7681e-04 6.7718e-05 1.7384e-03 -6.0000e+00 3.6263e-03 3.5450e-02 -2.2718e-04 4.6158e-06 1.9268e-05 -6.0000e+00 2.5301e-04 4.0964e-02 0.0000e+00 10 0 0 10 0 0 7.18 21.56 0.26 0.04096 0.03926 2610 736 1 5 0 15.070 26.21 20.00 21.56 29.83 20.5 1034.02 -654 -1389 -2430 -4121 -3314 -2523 -659 126 -1034 -2614 -2522 -1385 -684 446 125 -218 30 588 695 918 368 555 628 717 719 146 -461 -745 -71 507 1282 1674 247 -1827 -1992 -1536 -934 98 -155 -568 -786 -549 -628 -243 -142 -270 -567 -713 -337 503 709 877 1078 719 862 833 456 411 582 1080 1238 1703 1538 844 -185 -205 -367 574 895 445 352 68 124 -125 -159 -376 -704 -568 -573 -892 -1114 -1648 -1712 -1206 -791 -491 -295 -43 94 313 267 33 480 674 296 400 508 111 -112 -411 -706 -634 76 -477 -792 -696 -607 -346 170 361 248 357 166 163 91 383 263 222 141 -176 12 284 351 654 543 98 657 591 330 194 -16 214 -29 -311 -198 7 296 99 -231 -108 -376 -346 -578 -95 -217 -381 -601 -433 -322 -90 19 -175 -460 -440 -252 -140 104 30 -57 8 164 201 274 112 167 195 236 249 52 -161 -244 -22 156 419 592 95 -710 -729 -564 -382 44 -82 -321 -479 -347 -406 -157 -92 -173 -357 -438 -203 307 459 606 785 513 630 623 347 309 429 795 951 1412 1296 749 -162 -174 -292 452 772 408 348 65 117 -121 -141 -319 -547 -429 -466 -772 -1082 -1655 -1820 -1343 -890 -589 -352 -52 113 378 296 35 501 699 312 467 623 143 -150 -532 -896 -740 91 -572 -1033 -904 -823 -489 240 542 370 531 247 223 121 510 337 300 195 -259 18 413 494 924 731 126 846 781 446 281 -24 312 -44 -489 -314 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