File name: Pandora135s1_ManhattanNY-CCNY_20220904_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T064000.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20220904_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20220904 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220904T131301.0Z 8282.550706 140 1 45.25 2 59.59 108.58 154.23 64.52 0.00 1 0.00 1 0 17 8.376e-03 5.208e-03 1.468e-03 4.984e-04 2.507384e-01 2.506474e-04 2.974162e-03 -6.000000e+00 4.800363e-03 230.16 -2.00 3.51 -2.00 317.20 0.00e+00 3.994051e-04 3.579499e-05 1.101442e-04 -6.000000e+00 2.175695e-04 288.71 -2.00 20.00 -2.00 316.35 0.00e+00 1.967 0.000 302.00 328.00 3 2.6931e+00 6.6413e-04 2.3549e-02 -6.0000e+00 1.1968e-02 -1.1370e-02 7.4822e-04 1.2991e-02 -6.0000e+00 1.2991e-02 5.0558e-03 4.4248e-04 6.3000e-03 -6.0000e+00 7.7508e-03 -3.4581e-03 2.1487e-04 1.7301e-03 -6.0000e+00 3.2657e-03 3.8054e-03 -5.9500e-05 1.4248e-05 1.8764e-05 -6.0000e+00 2.2818e-04 4.2369e-02 0.0000e+00 10 0 0 10 0 0 99.96 21.74 0.27 0.04237 0.04192 541 153 1 5 0 83.630 26.41 20.00 21.74 29.54 20.5 1030.06 -391 -1071 -2217 -3274 -2960 -1288 -677 1433 -556 -1578 -1913 -730 108 802 -149 -706 298 157 993 353 207 142 716 294 358 -132 -651 -675 -183 987 972 1788 -249 -1860 -2254 -1211 -897 101 -125 -739 -915 -864 -756 -648 -129 -456 -812 -841 -370 579 604 799 990 689 725 890 296 474 512 1171 1207 1697 1560 799 -152 -78 -124 795 1100 431 383 110 157 -141 -86 -329 -549 -286 -442 -686 -1244 -1559 -1683 -1027 -783 -458 -217 -99 81 295 341 93 724 697 446 412 523 97 -208 -468 -672 -499 137 -407 -869 -651 -666 -331 98 261 124 278 87 56 185 389 301 188 137 -311 -22 175 247 620 445 80 707 653 310 256 -86 317 36 -352 -199 54 299 13 -180 -108 -299 -325 -430 -47 -138 -287 -391 -319 -135 -77 180 -78 -228 -275 -110 18 155 -33 -168 73 40 260 96 57 39 202 88 113 -43 -207 -201 -51 274 290 574 -87 -656 -750 -403 -334 41 -60 -408 -502 -493 -440 -378 -75 -264 -499 -504 -217 344 382 498 650 475 512 642 217 343 365 833 898 1361 1260 680 -126 -64 -95 604 917 379 363 108 152 -130 -73 -269 -411 -209 -349 -613 -1162 -1596 -1702 -1088 -889 -554 -259 -120 97 358 381 101 723 695 481 460 648 124 -277 -604 -859 -586 156 -494 -1146 -845 -905 -468 146 389 193 430 128 81 245 525 386 255 201 -454 -33 254 368 878 601 102 923 876 421 372 -130 489 53 -551 -331 88 499 22 -307 -180 -506 -530 -698 SS 20220904T131743.0Z 8282.553970 143 1 44.69 2 58.75 109.52 153.47 65.98 0.00 1 0.00 1 0 17 8.666e-03 5.352e-03 7.480e-04 2.986e-04 2.445265e-01 1.507364e-04 2.904479e-03 -6.000000e+00 4.966382e-03 230.16 -2.00 3.51 -2.00 316.85 0.00e+00 3.519729e-04 1.981475e-05 9.044361e-05 -6.000000e+00 2.251012e-04 288.71 -2.00 20.00 -2.00 316.01 0.00e+00 1.920 0.000 302.00 328.00 3 1.8563e+00 3.9739e-04 2.2965e-02 -6.0000e+00 1.2382e-02 -1.7572e-02 4.4680e-04 1.2644e-02 -6.0000e+00 1.3441e-02 2.2756e-03 2.6013e-04 6.1323e-03 -6.0000e+00 8.0189e-03 -1.4453e-03 1.2345e-04 1.6823e-03 -6.0000e+00 3.3785e-03 9.3323e-03 -6.1233e-05 8.5379e-06 1.8788e-05 -6.0000e+00 2.3608e-04 4.2688e-02 0.0000e+00 10 0 0 10 0 0 99.92 21.75 0.23 0.04269 0.04223 784 221 1 5 0 56.800 26.41 20.00 21.75 29.64 20.5 1030.59 -610 -1328 -2476 -3893 -2354 -2429 302 -47 -400 -2525 -1665 -1008 -276 774 126 -223 -48 724 524 742 190 595 587 880 516 188 -474 -788 110 541 1515 1526 98 -1966 -1759 -1469 -747 98 -161 -579 -908 -677 -793 -348 -314 -283 -747 -776 -410 621 635 902 1105 648 830 677 362 322 657 973 1306 1705 1411 726 -266 -67 -174 779 917 442 280 110 89 -167 -195 -247 -520 -352 -404 -875 -1115 -1694 -1621 -1172 -675 -445 -301 -76 59 346 278 121 673 832 361 430 434 53 -191 -441 -672 -544 177 -473 -795 -704 -615 -362 145 266 177 241 105 120 140 461 319 261 80 -252 -42 207 263 608 512 128 788 679 384 213 4 249 55 -304 -181 33 278 36 -266 -132 -389 -267 -515 -91 -212 -396 -576 -310 -316 42 -7 -69 -452 -293 -186 -57 182 31 -59 -13 203 153 223 58 180 183 290 180 67 -166 -258 34 166 492 538 38 -759 -636 -536 -303 43 -85 -325 -550 -425 -509 -223 -201 -180 -466 -472 -244 373 406 615 793 488 598 499 271 239 510 758 990 1395 1252 635 -228 -55 -135 600 777 397 271 110 88 -158 -170 -205 -424 -279 -323 -793 -1063 -1773 -1686 -1279 -788 -524 -372 -96 73 409 320 127 687 844 373 493 522 66 -249 -558 -832 -656 206 -557 -1018 -946 -819 -502 211 392 273 368 153 169 191 600 422 347 114 -363 -61 296 383 843 677 170 995 881 510 303 7 374 80 -468 -282 54 462 62 -452 -217 -619 -430 -824 SS 20220904T132253.5Z 8282.557563 146 1 44.17 2 57.83 110.58 152.63 67.52 0.00 1 0.00 1 0 17 8.601e-03 5.371e-03 6.144e-04 2.578e-04 2.389029e-01 1.303546e-04 2.841385e-03 -6.000000e+00 4.928529e-03 230.16 -2.00 3.51 -2.00 316.73 0.00e+00 3.575999e-04 1.657150e-05 8.502781e-05 -6.000000e+00 2.233910e-04 288.71 -2.00 20.00 -2.00 315.89 0.00e+00 1.871 0.000 302.00 328.00 3 1.6163e+00 3.4286e-04 2.2399e-02 -6.0000e+00 1.2287e-02 -1.7656e-02 3.8521e-04 1.2350e-02 -6.0000e+00 1.3338e-02 1.4490e-03 2.2368e-04 5.9872e-03 -6.0000e+00 7.9579e-03 -1.0430e-03 1.0528e-04 1.6414e-03 -6.0000e+00 3.3526e-03 1.2559e-02 -9.2620e-05 7.3624e-06 1.8725e-05 -6.0000e+00 2.3429e-04 4.2938e-02 0.0000e+00 10 0 0 10 0 0 99.82 21.75 0.23 0.04294 0.04224 1008 284 1 5 0 43.550 26.41 20.00 21.75 29.87 20.5 1032.48 -773 -1393 -2325 -3884 -2462 -2089 -130 519 -576 -2317 -1876 -1019 -362 822 23 -165 123 778 692 715 323 554 599 726 552 75 -411 -612 269 716 1495 1600 149 -1813 -1801 -1371 -823 163 -184 -636 -873 -710 -756 -360 -232 -431 -672 -765 -386 496 753 812 1082 660 819 738 420 392 628 1056 1210 1668 1448 742 -195 -145 -208 746 990 473 312 68 103 -155 -132 -283 -466 -402 -432 -828 -1091 -1662 -1678 -1175 -758 -457 -249 -85 67 278 219 96 647 816 366 455 427 -190 -211 -441 -686 -534 176 -458 -787 -699 -635 -322 150 294 136 271 75 149 193 437 315 245 103 -223 -35 182 254 623 531 168 805 684 385 225 3 262 29 -253 -179 31 261 54 -284 -130 -368 -295 -552 -124 -238 -396 -613 -346 -288 -19 86 -105 -439 -350 -199 -79 204 6 -46 35 229 211 225 103 175 196 251 201 28 -150 -209 86 228 505 585 59 -723 -674 -516 -345 74 -101 -369 -545 -460 -500 -238 -153 -283 -431 -478 -236 306 492 567 795 474 602 556 320 296 465 784 938 1394 1229 661 -170 -123 -164 584 851 432 306 69 103 -149 -116 -239 -359 -323 -349 -760 -1052 -1654 -1764 -1296 -845 -544 -311 -102 84 332 255 102 666 836 382 524 516 -240 -277 -560 -853 -612 207 -543 -1014 -896 -852 -448 209 434 200 415 110 211 250 570 418 326 147 -322 -51 260 371 867 703 224 1019 889 511 319 5 374 42 -388 -278 51 433 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