File name: Pandora135s1_ManhattanNY-CCNY_20221224_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T090457.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20221224_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20221224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221224T130438.6Z 8393.544891 64 1 46.55 2 83.60 128.70 98.23 119.40 0.00 1 0.00 1 0 25 8.408e-01 3.714e-02 4.269e-01 1.945e-02 1.267149e+00 1.284268e-02 1.421325e-02 -6.000000e+00 5.056490e-01 223.06 -2.00 3.51 -2.00 322.67 0.00e+00 5.675651e-03 7.316029e-03 1.617387e-02 -6.000000e+00 2.770316e-02 276.57 -2.00 20.00 -2.00 322.30 0.00e+00 8.113 0.010 302.00 328.00 3 1.1750e+00 5.0703e-02 1.4216e-01 -6.0000e+00 1.2528e+00 2.2453e+00 6.2321e-02 1.3411e-01 -6.0000e+00 1.3844e+00 -2.7269e+00 4.9557e-02 4.6049e-02 -6.0000e+00 8.0813e-01 1.0489e+00 2.5390e-02 1.4081e-02 -6.0000e+00 3.4597e-01 1.0524e-05 -3.5124e-03 5.0777e-04 2.8998e-04 -6.0000e+00 2.6699e-02 -4.0486e-02 0.0000e+00 12 8 8 10 0 0 79.78 17.96 0.59 -0.04049 -0.06688 39 11 1 5 0 1193.410 23.01 20.00 17.96 -8.07 18.0 771.28 900000 77647 188225 107491 900000 -94780 18844 900000 87213 900000 184172 900000 23627 900000 -23675 900000 900000 106162 223593 116254 900000 22656 234239 -30685 900000 -32194 900000 900000 900000 36878 -61812 900000 900000 900000 3824 900000 42723 900000 900000 900000 900000 8951 900000 -43536 900000 29067 900000 52610 900000 346781 13344 148026 335976 900000 123848 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-472 4375 -5864 -1047 -1142 -4538 -2312 -2650 -1164 -2902 2394 -4717 775 -555 2932 -4882 3031 -3799 -675 -2274 -1648 -2118 -3503 5898 -3137 -78 -3750 4099 -3169 5113 3781 5225 8765 -3534 -7486 -3885 5317 -193 3584 1879 3345 726 40 -2650 -4430 5287 2109 -2179 -1265 7670 -9807 -216 SS 20221224T131521.4Z 8393.552331 67 1 46.58 2 82.04 130.61 96.55 120.96 0.00 1 0.00 1 0 25 7.525e-01 1.632e-02 4.014e-01 6.789e-03 1.158317e+00 4.148448e-03 1.256901e-02 -6.000000e+00 4.339055e-01 223.06 -2.00 3.51 -2.00 322.46 0.00e+00 1.025932e-02 2.548445e-03 1.263543e-02 -6.000000e+00 2.259915e-02 276.57 -2.00 20.00 -2.00 322.08 0.00e+00 6.749 0.006 302.00 328.00 3 1.2823e+00 1.7045e-02 1.2364e-01 -6.0000e+00 1.0720e+00 9.9006e-01 2.9243e-02 1.3159e-01 -6.0000e+00 1.1740e+00 -1.2939e+00 3.3427e-02 5.4271e-02 -6.0000e+00 6.9363e-01 5.1548e-01 1.4690e-02 1.5020e-02 -6.0000e+00 2.9867e-01 5.0254e-05 -2.5488e-03 1.7356e-04 2.1446e-04 -6.0000e+00 2.2259e-02 -4.1213e-02 0.0000e+00 12 8 8 10 0 0 81.45 17.96 0.38 -0.04121 -0.06037 104 29 1 5 0 447.810 23.01 20.00 17.96 -7.75 18.0 773.22 900000 -87408 -189357 -192641 900000 -330086 -282001 900000 -36018 -125109 900000 900000 -136946 900000 -153713 900000 900000 -92750 -25066 -72322 900000 -75130 900000 -162712 900000 -135882 -17727 900000 -74100 -27412 -128939 81442 89240 239098 -23220 900000 -28756 900000 151029 107622 165665 -24824 73843 -38430 87127 -7177 125604 36838 289380 43868 22662 48370 35116 49740 23321 66092 -473 54494 16816 27761 26327 32942 8051 18506 20611 7589 31531 6026 19281 10363 16787 9666 11985 12173 6476 20090 -774 6460 -6277 2987 1942 12260 -582 5805 2276 2121 6095 513 3708 226 1542 -3052 3924 -3499 -1763 -2669 -2363 -1838 -1786 -1260 -1111 331 -2368 -1466 -3591 111 -3075 -375 -1949 -615 -771 -1195 -797 -841 995 -983 -61 -532 1107 -486 1244 1838 2017 2242 -448 -1355 401 1598 -114 916 719 910 229 -195 -282 -566 720 117 -162 -210 620 -1172 -621 900000 -577 -1364 -1387 900000 -7330 -3723 900000 -238 -826 900000 900000 -904 900000 -1937 900000 900000 -1113 -165 -781 900000 -767 900000 -4004 900000 -2691 -117 900000 -756 -217 -3328 538 589 1578 -376 900000 -513 900000 997 782 1094 -760 975 -1453 1035 -223 1078 827 1910 1129 823 1565 1461 1970 1293 2487 -32 2302 977 1356 1286 1631 601 1355 1695 752 2536 669 2095 1424 2418 1566 1863 1739 863 2038 -90 729 -946 515 418 2848 -176 1784 764 747 2147 196 1366 83 526 -1031 1227 -1266 -739 -1386 -1495 -1387 -1423 -1057 -893 254 -1603 -906 -2341 74 -2235 -288 -1724 -586 -874 -1553 -1107 -1195 1366 -1340 -82 -751 1616 -741 1802 2454 2501 2681 -536 -1595 452 1855 -158 1538 1416 2008 513 -475 -744 -1586 2031 334 -457 -568 1519 -2846 -1380 SS 20221224T132559.1Z 8393.559712 70 1 46.22 2 80.53 132.55 94.91 122.53 0.00 1 0.00 1 0 25 9.365e-01 9.125e-03 2.830e-01 3.176e-03 1.016911e+00 1.783922e-03 1.095581e-02 -6.000000e+00 5.283934e-01 223.06 -2.00 3.51 -2.00 322.08 0.00e+00 8.371512e-03 1.026644e-03 5.396325e-03 -6.000000e+00 2.355715e-02 276.57 -2.00 20.00 -2.00 321.67 0.00e+00 5.792 0.003 302.00 328.00 3 1.2090e+00 6.8067e-03 8.8176e-02 -6.0000e+00 1.3012e+00 3.2694e-01 1.2073e-02 7.9995e-02 -6.0000e+00 1.4169e+00 -4.4760e-01 1.4401e-02 3.7771e-02 -6.0000e+00 8.4377e-01 1.7869e-01 6.3991e-03 1.4029e-02 -6.0000e+00 3.6214e-01 1.7204e-04 -1.6495e-03 7.8938e-05 1.4314e-04 -6.0000e+00 2.5703e-02 -4.1611e-02 0.0000e+00 11 8 0 10 0 0 17.64 17.96 0.24 -0.04161 -0.05401 210 59 1 5 0 220.030 23.01 20.01 17.96 -7.51 18.0 775.56 -380293 -249019 -333575 -296469 900000 -377134 -304366 -205671 -270917 -300341 17373 -236016 -163293 -200085 -187310 -147039 -76549 -126379 -124913 -107656 16799 -116143 -117187 -146418 -93936 -91425 -57365 -25130 -103496 -103321 -98918 -26444 2244 -32231 -23182 -28383 -18811 -11890 1159 2244 27347 -29839 -7378 -18615 49 -3961 -3712 5330 24876 13414 -3555 12094 11424 10842 7773 12479 2958 2244 2081 -489 8241 6035 8593 9299 10002 4326 6212 3207 6083 5676 4506 6228 3142 3830 24 4952 -3252 571 -2934 -862 570 1325 -657 157 -221 -67 1013 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