File name: Pandora135s1_ManhattanNY-CCNY_20230202_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T100410.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230202_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230202 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230202T125840.8Z 8433.540749 251 1 39.30 2 81.75 120.72 108.36 335.80 0.00 1 0.00 1 0 25 5.238e-01 1.566e-02 2.936e-01 6.283e-03 7.582837e-01 3.503598e-03 8.426964e-03 -6.000000e+00 3.014564e-01 224.41 -2.00 3.51 -2.00 321.64 0.00e+00 1.415275e-02 1.782706e-03 3.265654e-03 -6.000000e+00 1.542134e-02 275.16 -2.00 20.00 -2.00 321.19 0.00e+00 6.547 0.005 302.00 328.00 3 1.7917e+00 1.2092e-02 8.1207e-02 -6.0000e+00 7.4833e-01 3.8476e-01 1.7695e-02 5.7072e-02 -6.0000e+00 8.1877e-01 -4.0812e-01 1.9722e-02 2.2894e-02 -6.0000e+00 4.8009e-01 1.6139e-01 9.2358e-03 1.6305e-02 -6.0000e+00 2.0658e-01 5.9433e-05 -2.2824e-03 1.7555e-04 1.3646e-04 -6.0000e+00 1.4822e-02 -1.4184e-02 0.0000e+00 12 9 9 12 1 1 99.91 19.17 0.43 -0.01418 -0.03133 51 17 1 5 0 752.380 24.14 19.99 19.17 4.37 19.7 865.60 900000 -226471 900000 -252164 900000 -298684 900000 108167 900000 900000 11213 900000 -55439 900000 -133816 900000 2535 140061 -31960 22317 115506 -29512 21117 -77868 62660 -58308 900000 4016 133609 -39619 -16103 -14768 67578 9373 -17331 82203 11383 115855 11600 76683 12993 8266 -2961 820 17256 13198 30429 21470 57003 13581 19478 13569 27569 1800 17812 14259 5351 8251 -682 12344 12511 14998 1075 11762 -2520 4763 4166 4043 1206 1421 3910 3965 3152 -903 4919 1073 -353 -4520 -3571 -1365 -965 648 -3131 -239 -3379 -838 -707 1197 -19 1392 951 413 -725 -2335 -613 -2928 -622 515 -112 -832 109 -11 -1072 -1170 -1680 -1344 -2610 205 -1270 1329 -878 904 -341 194 687 -364 51 -638 727 -1398 1170 599 1754 924 364 -2430 845 1475 432 712 332 1327 236 231 -716 36 -83 -330 -456 234 236 -790 -192 900000 -3651 900000 -5748 900000 -9216 900000 661 900000 900000 69 900000 -339 900000 -2884 900000 21 856 -456 205 706 -430 194 -1882 402 -1284 900000 48 817 -848 -340 -388 930 252 -594 1005 299 1240 422 1712 616 445 -181 51 981 815 1656 1352 2684 1016 1531 1276 2489 228 2028 1732 721 1069 -94 1467 1537 1996 191 2161 -581 1026 894 897 303 391 1164 1234 978 -274 1341 272 -85 -1153 -1024 -463 -371 284 -1579 -125 -1929 -496 -440 756 -12 851 548 223 -382 -1294 -377 -2178 -510 486 -118 -906 111 -10 -925 -988 -1519 -1288 -2556 210 -1457 1691 -1235 1352 -527 293 981 -525 73 -928 1104 -2262 1827 899 2596 1336 512 -3391 1103 1983 667 1214 634 2602 496 517 -1730 87 -206 -836 -1158 568 557 -1753 -404 SS 20230202T131512.0Z 8433.552222 256 1 46.73 2 79.11 123.70 109.51 339.31 0.00 1 0.00 1 0 25 2.880e-01 6.187e-03 5.463e-02 1.283e-03 6.249911e-01 6.678726e-04 7.122281e-03 -6.000000e+00 1.626361e-01 224.41 -2.00 3.51 -2.00 320.79 0.00e+00 4.403500e-03 2.728505e-04 8.074092e-04 -6.000000e+00 7.073917e-03 275.16 -2.00 20.00 -2.00 320.30 0.00e+00 5.100 0.002 302.00 328.00 3 8.6411e-01 2.0491e-03 6.0316e-02 -6.0000e+00 4.0202e-01 9.2575e-02 2.7255e-03 3.4181e-02 -6.0000e+00 4.3801e-01 -5.7216e-02 2.8652e-03 1.7509e-02 -6.0000e+00 2.6046e-01 1.0638e-02 1.4207e-03 7.2643e-03 -6.0000e+00 1.1071e-01 7.2545e-04 -1.2422e-03 3.5378e-05 6.8735e-05 -6.0000e+00 7.8088e-03 -1.5404e-02 0.0000e+00 10 0 0 10 0 0 16.91 19.16 0.23 -0.01540 -0.02474 375 106 1 5 0 124.590 24.04 19.99 19.16 5.48 20.0 876.12 -101160 -82972 -66281 -113901 -35578 -140217 -93777 -99648 -66829 -101315 -77246 -68670 -72740 -30885 -47204 -14684 -21460 -10584 -20841 -9581 -20005 -13815 -19346 -23268 -11949 -22745 -11896 -15805 -14981 -14164 -11186 -5759 827 -3802 -7353 -5338 -6917 -202 -1716 -858 -1191 -1131 -2053 -539 1730 2095 1289 1667 2627 1963 2516 3381 4146 2516 2859 2608 349 23 -177 824 1471 2274 1494 2610 825 1777 947 1801 1790 1418 918 602 348 -490 -2 -920 -645 -1776 -974 -1603 -1387 -1681 -2319 -1591 -1207 -447 -412 77 337 1315 1202 955 912 717 461 234 471 280 145 -332 -433 -694 -269 -762 -1419 -1280 -1025 -407 45 400 298 607 248 403 168 588 309 114 -283 -525 -402 -64 144 93 248 -309 409 704 410 76 278 465 17 -78 -339 -255 102 92 -455 -74 -143 107 160 -684 -561 -415 -1140 -151 -1649 -739 -948 -518 -1204 -764 -705 -983 -359 -827 -226 -405 -200 -477 -209 -501 -327 -501 -678 -338 -760 -365 -496 -465 -468 -424 -251 39 -206 -404 -283 -403 -13 -126 -75 -118 -122 -237 -63 203 252 160 214 350 281 397 594 796 534 642 613 86 6 -43 195 357 601 453 884 303 637 334 643 702 589 426 294 170 -229 -1 -388 -251 -699 -421 -755 -767 -1066 -1629 -1180 -949 -373 -363 64 281 1137 974 723 657 526 376 221 474 323 184 -429 -527 -761 -267 -758 -1521 -1458 -1225 -514 61 569 470 1014 419 655 258 857 450 174 -460 -894 -683 -105 225 141 362 -437 593 1045 634 134 500 887 33 -167 -724 -576 235 215 -1076 -169 -307 229 331 SS 20230202T132048.5Z 8433.556117 259 1 46.87 2 78.23 124.74 109.86 340.53 0.00 1 0.00 1 0 25 2.107e-01 6.107e-03 3.454e-02 1.014e-03 5.886826e-01 5.216098e-04 6.760015e-03 -6.000000e+00 1.190180e-01 224.41 -2.00 3.51 -2.00 320.53 0.00e+00 4.129021e-03 1.974462e-04 4.827958e-04 -6.000000e+00 5.176687e-03 275.16 -2.00 20.00 -2.00 320.03 0.00e+00 4.749 0.002 302.00 328.00 3 8.3499e-01 1.5690e-03 5.6144e-02 -6.0000e+00 2.9420e-01 8.4711e-02 2.0054e-03 3.1449e-02 -6.0000e+00 3.2054e-01 -4.7634e-02 2.0175e-03 1.6365e-02 -6.0000e+00 1.9061e-01 6.5922e-03 1.0209e-03 6.6972e-03 -6.0000e+00 8.1020e-02 1.0784e-03 -1.1622e-03 2.8205e-05 6.4561e-05 -6.0000e+00 5.7145e-03 -1.5448e-02 0.0000e+00 10 0 0 10 0 0 10.02 19.16 0.24 -0.01545 -0.02418 463 131 1 5 0 101.000 24.04 20.00 19.16 6.17 19.9 879.86 -50149 -74339 -62682 -81800 -62137 -93530 -77794 -59925 -69319 -48831 -66124 -31526 -50771 -21786 -31686 -12549 -14221 -18539 -9318 -15802 -3834 -17544 -7087 -18747 -8327 -16352 -8986 -9828 -11789 -11934 -9102 71 -3061 -739 -5581 -1271 -7019 -240 -635 241 -1675 -2138 -741 -1931 938 -150 2817 262 2747 1673 2360 3299 2970 3108 2131 2346 -377 1028 -670 544 981 2128 1845 2049 1127 770 942 752 1756 893 1018 670 403 -177 -302 -947 -1425 -1537 -1375 -1070 -1533 -1380 -2200 -1597 -1410 -562 -254 211 487 943 1285 658 1104 673 581 219 683 531 -29 -385 -511 -678 -310 -439 -1573 -1149 -1141 -247 44 683 335 527 339 328 287 557 166 30 -146 -611 -385 -40 107 171 138 -285 450 872 160 212 77 491 85 -328 -294 -120 147 -2 -415 -146 3 -42 244 -308 -691 -564 -882 -510 -1018 -769 -563 -809 -502 -850 -321 -783 -325 -661 -261 -342 -515 -257 -494 -110 -580 -218 -699 -303 -683 -355 -385 -466 -503 -436 4 -192 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