File name: Pandora135s1_ManhattanNY-CCNY_20230208_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T100410.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230208_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230208 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230208T124155.2Z 8439.529111 271 1 47.18 2 83.30 116.43 80.58 270.95 0.00 1 0.00 1 0 17 7.242e-01 3.168e-02 3.733e-01 1.313e-02 9.696944e-01 7.885687e-03 1.057818e-02 -6.000000e+00 4.240678e-01 224.63 -2.00 3.51 -2.00 322.31 0.00e+00 1.731879e-02 4.497785e-03 4.033400e-03 -6.000000e+00 2.264249e-02 275.15 -2.00 20.00 -2.00 321.90 0.00e+00 7.819 0.009 302.00 328.00 3 1.3830e+00 2.9983e-02 1.0043e-01 -6.0000e+00 1.0503e+00 1.3193e+00 3.9130e-02 7.4476e-02 -6.0000e+00 1.1507e+00 -1.6722e+00 3.6175e-02 2.7754e-02 -6.0000e+00 6.7804e-01 6.7416e-01 1.7141e-02 1.5677e-02 -6.0000e+00 2.9095e-01 1.8715e-05 -2.8169e-03 3.6184e-04 1.8220e-04 -6.0000e+00 2.1833e-02 -8.5156e-03 0.0000e+00 12 8 8 10 0 0 74.30 19.73 0.57 -0.00852 -0.02968 45 13 1 5 0 1048.130 24.56 20.00 19.73 11.09 20.3 914.96 900000 -57807 213735 -78193 900000 -175526 -92596 900000 47236 900000 -63761 900000 -67170 900000 -72971 900000 231430 216031 185142 128958 900000 23810 900000 -22556 900000 -45255 900000 900000 900000 -30796 63798 206899 152454 900000 -26616 900000 23865 900000 20299 264439 149757 29698 57555 4680 331724 30254 900000 10046 900000 95227 71495 52875 112128 57163 66610 102000 16288 72452 5752 71975 31034 76439 -7995 29792 11142 17809 32995 6966 34286 -75 29083 10467 24216 9655 37320 11847 1151 -2244 -3035 4852 -6574 16026 -11145 18367 -2513 4322 2861 6906 1107 1053 2396 -1422 2423 -13022 -2403 -8408 -1690 -364 353 -3306 -5 1215 -5364 -768 -5086 -8680 -5190 1274 -5943 2880 -2141 143 -1925 -1356 1003 -2369 826 -1850 3086 -1575 4688 2642 5072 3280 2153 -5793 1195 3322 1144 2628 109 3147 -615 -1485 -1099 81 124 938 106 -5 1061 -3024 -779 900000 -1747 2727 -2625 900000 -10842 -2238 900000 603 900000 -942 900000 -1488 900000 -3038 900000 2952 2756 2362 1645 900000 489 900000 -655 900000 -1507 900000 900000 900000 -895 904 2639 1945 900000 -1320 900000 660 900000 734 3373 1910 1242 1987 262 4232 1329 900000 584 900000 2858 3004 2976 3786 3560 3899 4210 1478 3806 522 3403 2236 3843 -1026 3040 1500 2272 3625 1037 4277 -15 4761 2122 4136 1745 4789 1629 165 -348 -555 1011 -1854 4203 -4273 5571 -988 1669 1170 2780 469 430 903 -525 847 -5667 -1097 -4934 -1116 -266 288 -2885 -4 894 -3707 -488 -3568 -6712 -4105 1028 -5830 2870 -2601 188 -2695 -1884 1319 -3134 1069 -2582 4337 -2391 6509 3522 6262 4008 2588 -7328 1374 3965 1638 4397 214 6560 -1358 -3565 -2823 216 338 2549 287 -13 2504 -7137 -1694 SS 20230208T125239.5Z 8439.536569 274 1 46.67 2 81.50 118.31 82.59 272.61 0.00 1 0.00 1 0 25 7.207e-01 1.378e-02 2.697e-01 4.039e-03 8.641460e-01 2.251808e-03 9.475760e-03 -6.000000e+00 4.079224e-01 224.63 -2.00 3.51 -2.00 321.87 0.00e+00 9.924012e-03 1.223895e-03 1.714594e-03 -6.000000e+00 1.906944e-02 275.15 -2.00 20.00 -2.00 321.44 0.00e+00 6.373 0.005 302.00 328.00 3 1.2366e+00 8.2114e-03 8.0432e-02 -6.0000e+00 1.0096e+00 3.6833e-01 1.2882e-02 5.5050e-02 -6.0000e+00 1.1015e+00 -4.7694e-01 1.4679e-02 2.7159e-02 -6.0000e+00 6.5325e-01 1.9396e-01 6.6860e-03 1.3857e-02 -6.0000e+00 2.8183e-01 1.1399e-04 -1.3238e-03 1.0816e-04 1.5167e-04 -6.0000e+00 1.9960e-02 -9.0466e-03 0.0000e+00 12 8 8 10 0 0 85.70 19.76 0.35 -0.00905 -0.01899 142 40 1 5 0 328.620 24.65 20.00 19.76 11.78 20.4 919.68 900000 -299913 900000 -283825 900000 -314836 -236455 -166766 -242135 900000 -236958 57322 -186119 900000 -153621 82327 -34727 -70992 -12921 -87294 39192 -92517 93138 -101516 189380 -92238 143157 -26161 2073 -13338 -45276 -7913 12591 58146 -39612 106397 -41247 69794 -4106 25335 14814 -1876 10660 -7427 35712 -1743 42136 380 49132 9238 20434 9345 16262 19838 12398 23571 -797 16652 -5548 13771 5379 17759 917 10667 5357 6864 10271 4305 10069 2825 8077 3228 6028 1010 3571 2079 -837 -1672 -3283 908 -982 2766 -2789 1784 -2305 1399 -517 684 1311 1358 1050 -1533 774 -2496 -1063 -2767 -56 -1620 -133 -1135 -482 -566 -1103 -367 -2793 -2377 -1845 113 -844 377 -414 449 -508 -545 405 -263 430 -506 809 -364 1309 450 1359 941 584 -1195 228 1491 -47 536 86 1322 13 116 -717 -96 391 146 -285 -233 130 -616 -405 900000 -5042 900000 -4366 900000 -5744 -2030 -776 -2598 900000 -2712 226 -2064 900000 -2308 324 -260 -787 -97 -1312 185 -1456 366 -1888 745 -1887 563 -278 17 -147 -873 -134 208 664 -1169 712 -1298 851 -128 698 513 -83 445 -386 1237 -91 1492 22 1875 578 1295 685 1239 1597 1144 2024 -89 1549 -621 1366 545 1950 127 1553 899 1149 1675 785 1941 677 2031 888 1583 260 806 425 -166 -350 -811 263 -348 1098 -1303 850 -1214 753 -298 401 760 758 551 -779 377 -1330 -644 -2034 -44 -1495 -134 -1182 -468 -488 -931 -301 -2294 -2064 -1685 109 -924 470 -594 695 -815 -861 608 -384 628 -781 1303 -610 2112 693 1977 1335 805 -1622 296 2020 -75 914 165 2730 28 277 -1852 -240 997 377 -733 -617 318 -1400 -876 SS 20230208T130721.0Z 8439.546771 279 1 46.75 2 79.08 120.95 85.33 274.88 0.00 1 0.00 1 0 17 4.798e-01 5.854e-03 8.077e-02 1.545e-03 7.211781e-01 8.152726e-04 7.991385e-03 -6.000000e+00 2.709649e-01 224.63 -2.00 3.51 -2.00 321.22 0.00e+00 4.885066e-03 3.800860e-04 7.812808e-04 -6.000000e+00 1.178732e-02 275.15 -2.00 20.00 -2.00 320.75 0.00e+00 5.088 0.002 302.00 328.00 3 1.0623e+00 2.6762e-03 6.3160e-02 -6.0000e+00 6.7011e-01 8.3324e-02 3.8326e-03 3.9153e-02 -6.0000e+00 7.3023e-01 -8.5758e-02 4.2667e-03 2.2107e-02 -6.0000e+00 4.3413e-01 2.7451e-02 2.0412e-03 9.4698e-03 -6.0000e+00 1.8426e-01 5.4474e-04 -8.9015e-04 4.1545e-05 9.7897e-05 -6.0000e+00 1.3015e-02 -9.0514e-03 0.0000e+00 10 0 0 10 0 0 88.18 19.77 0.25 -0.00905 -0.01574 358 101 1 5 0 130.560 24.65 20.00 19.77 12.46 20.5 925.60 -153578 -175005 -152055 -165824 -125453 -185986 -157964 -132544 -144759 -154258 -124644 -124579 -80140 -87481 -73231 -46626 -40519 -42195 -40869 -43018 -46724 -34201 -32566 -31751 -32063 -23573 -28136 -13650 -32183 -26320 -23297 -9659 -1451 -8907 -14652 -8453 -4104 -8412 868 -2040 -11 -4020 -913 -2408 1375 929 2483 1578 3861 4513 729 5499 4152 4739 2182 2427 -125 235 -214 1041 3496 3270 3392 3949 2327 2095 1685 1275 2053 1909 1146 1262 78 890 -308 -107 -1550 -1741 -1268 -601 -716 -997 -1763 -1277 -859 -422 -234 -213 552 586 588 42 62 163 -243 225 338 108 173 -254 -502 -623 -233 -242 -1138 -1463 -861 -315 26 438 295 285 83 45 -57 372 139 290 -1 -161 17 424 370 368 -24 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