File name: Pandora135s1_ManhattanNY-CCNY_20230218_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T100359.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230218_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230218 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230218T122536.4Z 8449.517782 67 1 47.00 2 83.72 111.26 79.35 136.71 0.00 1 0.00 1 0 17 6.999e-01 1.883e-02 4.004e-01 8.191e-03 9.668369e-01 4.924735e-03 1.021449e-02 -6.000000e+00 4.091523e-01 225.03 -2.00 3.51 -2.00 322.36 0.00e+00 9.917901e-03 2.947588e-03 5.811592e-03 -6.000000e+00 2.170758e-02 275.39 -2.00 20.00 -2.00 321.96 0.00e+00 8.247 0.010 302.00 328.00 3 3.3121e-01 1.9562e-02 1.0701e-01 -6.0000e+00 1.0210e+00 8.2853e-01 3.2029e-02 8.4377e-02 -6.0000e+00 1.1226e+00 -1.0826e+00 3.5991e-02 3.5562e-02 -6.0000e+00 6.5971e-01 4.4100e-01 1.5927e-02 1.3382e-02 -6.0000e+00 2.7818e-01 4.2129e-05 -1.6437e-03 2.3020e-04 1.4926e-04 -6.0000e+00 2.0585e-02 -1.5752e-02 0.0000e+00 12 8 8 10 0 0 -5.37 19.06 0.45 -0.01575 -0.02810 112 32 1 5 0 419.560 24.04 20.00 19.06 2.93 19.7 857.92 -209652 900000 -116693 900000 900000 -316629 -115061 -90288 900000 -248163 900000 -197766 900000 -131005 -44390 900000 900000 10183 122275 900000 25492 900000 900000 147783 -66826 900000 -22881 900000 63513 -36823 41106 -13470 900000 45732 900000 -6585 900000 60265 260168 84063 246933 14174 32895 19086 -19584 103135 -1378 160651 75390 155479 4407 79489 38766 32852 58374 42623 38809 3724 49183 -4214 87855 17144 16429 14793 12980 10031 12956 12364 7752 22785 4408 23936 -1426 13324 3025 17223 -2582 -563 3731 -3384 5233 -442 3479 1496 5053 -2190 5735 -318 1085 3812 -1741 3430 -2320 -1251 -4949 -66 -4436 604 -2476 -1009 -373 -1720 19 -3392 -168 -2737 -987 -3284 170 -962 -801 -1047 -970 -1041 -567 -247 -742 965 15 524 913 2822 1665 2436 1029 -3306 499 1036 1428 435 1115 335 668 -1041 -327 -117 436 852 -451 421 -446 -151 -1691 -2590 900000 -929 900000 900000 -10252 -916 -719 900000 -4565 900000 -2606 900000 -1676 -353 900000 900000 81 974 900000 203 900000 900000 1177 -1007 900000 -229 900000 506 -467 327 -218 900000 526 900000 -117 900000 658 2071 1016 1966 414 834 568 -866 1421 -54 1377 1578 1666 233 2250 1829 1792 2616 2313 2220 296 2364 -332 2906 1223 1381 1479 1458 1186 1509 1535 1087 3175 816 3791 -285 2122 494 2164 -372 -84 622 -721 1240 -130 1104 519 1792 -883 2239 -131 454 1499 -680 1205 -853 -488 -2337 -35 -2922 447 -2125 -879 -305 -1266 12 -2173 -114 -1967 -739 -2735 155 -1037 -965 -1401 -1353 -1451 -763 -322 -981 1317 22 783 1324 3782 2145 3135 1307 -4121 604 1323 2059 751 2109 702 1499 -2485 -835 -316 1189 2338 -1246 1101 -1119 -345 -3725 SS 20230218T123622.3Z 8449.525258 70 1 46.80 2 81.84 113.12 78.01 138.69 0.00 1 0.00 1 0 25 6.342e-01 7.888e-03 2.290e-01 2.670e-03 8.178095e-01 1.456032e-03 8.859392e-03 -6.000000e+00 3.595211e-01 225.03 -2.00 3.51 -2.00 321.78 0.00e+00 7.656901e-03 7.744118e-04 1.337354e-03 -6.000000e+00 1.586722e-02 275.39 -2.00 20.00 -2.00 321.34 0.00e+00 6.605 0.005 302.00 328.00 3 3.1818e-01 5.1823e-03 7.9930e-02 -6.0000e+00 8.8936e-01 2.1422e-01 8.2590e-03 4.9802e-02 -6.0000e+00 9.6859e-01 -2.3776e-01 9.6211e-03 2.6397e-02 -6.0000e+00 5.7538e-01 9.1780e-02 4.4062e-03 1.2681e-02 -6.0000e+00 2.4451e-01 2.4874e-04 -9.7305e-04 7.2422e-05 1.2973e-04 -6.0000e+00 1.7382e-02 -1.6384e-02 0.0000e+00 11 8 0 10 0 0 27.76 19.05 0.23 -0.01638 -0.02370 300 85 1 5 0 155.970 24.04 19.99 19.05 3.51 19.7 861.69 -176777 -241922 -176209 -241861 900000 -319216 -103830 -168593 -81174 -247458 -160155 -102617 -170900 -85862 -135687 -51872 -76733 -40908 -84419 4760 -80942 -51528 -109058 -65464 -53440 -65444 -31737 -49629 -13221 -71673 -30165 -31323 29158 -22190 -1942 -12470 -20268 6976 -13456 10694 -7630 -1443 -3561 2872 2105 6643 5876 4265 3307 3640 5744 2493 12538 6240 7492 5311 3343 -705 3462 -17 1740 6631 2281 7854 2896 4463 2370 2922 2930 4261 2438 2556 1675 86 1314 -900 -1025 -3677 -944 -600 1032 362 -1522 -631 -866 106 -206 869 175 1419 590 456 -50 -362 -557 -223 -193 -421 188 -878 -279 -1147 347 -718 -1270 -1555 -1156 -637 -230 263 -292 241 -561 148 -169 506 162 338 362 -27 153 736 629 192 481 -1058 373 792 362 4 226 300 -43 -18 -481 -78 203 166 -404 107 22 -63 -240 -460 -1489 -688 -1660 900000 -4306 -270 -658 -211 -2343 -750 -321 -1424 -425 -1484 -311 -699 -298 -1055 26 -1075 -510 -1987 -835 -654 -954 -339 -633 -120 -1325 -463 -620 380 -531 -37 -263 -501 156 -455 342 -336 -65 -176 139 106 332 310 244 207 249 437 204 1036 604 768 583 386 -85 387 -2 200 808 339 1279 541 831 453 583 653 1087 705 774 506 25 339 -212 -228 -869 -249 -192 389 160 -762 -335 -491 58 -119 512 104 876 345 251 -27 -206 -362 -157 -161 -409 202 -972 -290 -1068 285 -585 -1110 -1448 -1133 -669 -268 350 -408 364 -876 225 -246 765 247 497 563 -43 242 1104 978 291 702 -1517 511 1131 551 7 447 644 -99 -42 -1178 -200 534 441 -1077 272 52 -150 -547 SS 20230218T125237.0Z 8449.536540 75 1 46.68 2 79.04 115.99 76.09 141.77 0.00 1 0.00 1 0 17 3.020e-01 5.334e-03 4.762e-02 9.629e-04 6.507984e-01 5.047540e-04 7.329127e-03 -6.000000e+00 1.710058e-01 225.03 -2.00 3.51 -2.00 320.88 0.00e+00 3.886826e-03 2.133861e-04 7.031750e-04 -6.000000e+00 7.425247e-03 275.39 -2.00 20.00 -2.00 320.39 0.00e+00 5.071 0.002 302.00 328.00 3 2.7422e-01 1.5705e-03 6.0620e-02 -6.0000e+00 4.2328e-01 8.3928e-02 2.1243e-03 3.4621e-02 -6.0000e+00 4.6091e-01 -6.1818e-02 2.2701e-03 1.9239e-02 -6.0000e+00 2.7399e-01 1.5834e-02 1.1159e-03 7.9098e-03 -6.0000e+00 1.1636e-01 1.3086e-03 -6.2152e-04 2.6389e-05 8.1616e-05 -6.0000e+00 8.1901e-03 -1.7054e-02 0.0000e+00 10 0 0 10 0 0 26.28 19.04 0.27 -0.01705 -0.02172 722 204 1 5 0 64.640 23.93 20.01 19.04 3.95 19.8 865.53 -123792 -54015 -109530 -97170 -73583 -135392 -86151 -103853 -58311 -107996 -55711 -89646 -55197 -59864 -39906 -32910 -28643 -11849 -24463 -6849 -24388 -7211 -32677 -14863 -23300 -18553 -22472 -21403 -19920 -18684 -12651 -12488 2106 -9796 -2498 -12043 -5023 -5612 -1555 -1653 -1007 305 -3192 1432 -381 2029 -580 1873 1544 3069 2022 3213 3098 1952 3272 1433 1804 -418 716 -188 2157 2152 2875 2616 1334 1626 801 1650 1495 2288 593 839 -354 104 -413 -379 -845 -1602 -268 -740 -401 -1281 -1598 -1716 -926 -781 -157 -169 267 775 317 382 65 610 58 257 395 679 70 -283 -433 -748 74 -274 -962 -1082 -703 -600 105 308 20 222 2 142 -113 590 299 489 86 -116 -142 350 300 354 253 -527 334 617 173 -73 -116 74 -128 -434 -277 -112 284 292 -260 79 -108 -26 -18 -837 -218 -843 -657 -366 -1221 -510 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