File name: Pandora135s1_ManhattanNY-CCNY_20230324_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T103553.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230324_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230324 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230324T160127.6Z 8483.667681 223 1 46.61 2 41.65 156.83 51.12 103.77 0.00 1 0.00 1 0 17 7.838e-03 5.598e-03 1.644e-03 9.602e-04 1.824344e-01 4.851232e-04 2.211568e-03 -6.000000e+00 4.462925e-03 226.87 -2.00 3.51 -2.00 315.62 0.00e+00 3.994819e-04 4.694181e-05 3.215060e-05 -6.000000e+00 1.947828e-04 277.94 -2.00 20.00 -2.00 315.05 0.00e+00 1.337 0.000 302.00 328.00 3 4.8387e+00 1.2506e-03 1.6247e-02 -6.0000e+00 1.1083e-02 2.1804e-02 1.3962e-03 9.2859e-03 -6.0000e+00 1.2054e-02 -2.3252e-03 8.0067e-04 4.5711e-03 -6.0000e+00 7.1655e-03 1.8858e-04 3.6182e-04 1.3034e-03 -6.0000e+00 3.0331e-03 9.1731e-04 -2.9005e-04 2.7236e-05 1.5794e-05 -6.0000e+00 2.1279e-04 -6.3447e-03 0.0000e+00 10 0 0 10 0 0 99.94 19.95 0.17 -0.00634 -0.00852 71 20 1 5 0 656.370 24.75 20.01 19.95 13.59 20.8 936.82 -185 -1127 -1822 -2678 -1792 -2310 -70 1142 745 -1199 -1317 -761 214 516 227 -293 322 491 1167 1234 876 667 0 1029 486 377 -464 -504 136 470 1138 1908 1201 -1306 -1560 -1463 -1025 72 333 -397 -997 -888 -852 -854 -191 -494 -874 -862 -556 407 499 764 886 780 736 1132 346 350 598 870 1288 1543 1407 986 -298 -293 -563 131 709 353 173 241 58 111 17 -168 -522 -498 -243 -815 -1048 -1301 -1984 -1244 -739 -541 -325 -169 34 295 331 -72 451 550 244 332 474 361 -11 -254 -428 -504 43 -94 -747 -668 -692 -432 -26 481 176 356 121 251 194 376 70 138 288 -19 -188 254 320 585 609 1 419 686 360 71 -56 238 -208 -322 -176 -58 368 230 -200 -62 -245 -490 -534 -47 -310 -508 -699 -427 -521 -16 291 210 -343 -370 -222 65 175 83 -116 131 203 493 536 387 292 0 473 227 182 -222 -235 58 201 497 848 572 -646 -725 -659 -495 39 205 -275 -730 -676 -664 -669 -148 -380 -658 -646 -402 289 367 576 702 644 603 939 293 295 509 736 1081 1380 1317 975 -295 -266 -481 110 606 331 172 251 61 112 17 -152 -438 -404 -202 -733 -992 -1313 -2141 -1354 -854 -652 -402 -216 43 362 387 -82 471 547 253 365 560 455 -14 -328 -533 -594 49 -108 -918 -846 -916 -577 -36 685 256 520 174 342 254 471 88 175 379 -26 -269 359 441 792 803 2 510 827 460 94 -76 326 -289 -452 -253 -88 558 357 -314 -95 -375 -727 -796 SS 20230324T160603.7Z 8483.670877 226 1 46.47 2 41.31 158.49 50.28 104.65 0.00 1 0.00 1 0 17 9.559e-03 5.717e-03 3.086e-03 1.585e-03 1.818419e-01 7.966404e-04 2.194310e-03 -6.000000e+00 5.442237e-03 226.87 -2.00 3.51 -2.00 316.12 0.00e+00 4.641014e-04 8.544629e-05 3.679558e-05 -6.000000e+00 2.375282e-04 277.94 -2.00 20.00 -2.00 315.51 0.00e+00 1.330 0.000 302.00 328.00 3 5.5265e+00 2.0660e-03 1.6174e-02 -6.0000e+00 1.3515e-02 2.4069e-02 2.3091e-03 9.2558e-03 -6.0000e+00 1.4699e-02 2.0084e-03 1.3334e-03 4.5573e-03 -6.0000e+00 8.7379e-03 -2.4419e-03 6.1484e-04 1.3117e-03 -6.0000e+00 3.6985e-03 4.6352e-04 -2.7758e-04 4.5368e-05 1.5500e-05 -6.0000e+00 2.5949e-04 -6.2134e-03 0.0000e+00 10 0 0 10 0 0 99.97 19.94 0.33 -0.00621 -0.00830 91 26 1 5 0 510.560 24.75 19.99 19.94 13.64 20.9 937.29 -1018 -1096 -2062 -3347 -1466 -3321 -239 965 -469 -2405 -983 -1224 547 562 616 52 605 -81 334 941 530 457 5636 800 314 467 -478 13 -589 155 415 1350 983 -1372 -1832 -1533 -621 44 98 -665 -561 -906 -882 -1043 -292 -413 -978 -778 -542 883 379 1025 934 900 786 1104 337 351 536 703 1464 1350 1346 835 -99 -643 -332 -248 460 467 197 266 -127 308 44 187 -607 -599 -715 -790 -1102 -1263 -1786 -985 -841 -563 33 -92 187 349 191 -242 376 427 47 227 355 410 15 -55 -283 -636 9 -199 -693 -773 -672 -515 77 460 335 332 222 80 -20 104 -30 120 301 81 -3 234 335 936 536 -303 195 617 447 128 -66 101 -178 -335 -170 -30 416 264 -148 101 -244 -599 -566 -223 -258 -493 -753 -287 -623 -45 203 -110 -597 -236 -296 141 164 201 17 209 -29 122 351 201 172 2116 315 131 199 -203 5 -227 57 157 539 420 -608 -764 -618 -267 21 56 -422 -386 -652 -649 -773 -213 -300 -696 -533 -358 593 255 729 698 701 628 894 279 289 432 562 1196 1180 1219 800 -95 -567 -276 -197 384 422 195 265 -127 308 41 164 -480 -462 -567 -670 -1048 -1267 -1913 -1054 -959 -687 40 -118 239 430 227 -272 379 427 47 248 412 523 19 -71 -356 -737 10 -236 -861 -1020 -891 -709 110 667 508 507 324 112 -26 128 -37 153 413 115 -4 341 474 1309 713 -386 243 759 560 171 -93 143 -257 -482 -258 -46 658 427 -243 162 -381 -937 -866 SS 20230324T161630.0Z 8483.678125 229 1 45.35 2 40.65 162.34 48.40 106.71 0.00 1 0.00 1 0 17 7.465e-03 5.472e-03 6.918e-04 4.119e-04 1.765528e-01 2.084908e-04 2.147367e-03 -6.000000e+00 4.249860e-03 226.87 -2.00 3.51 -2.00 315.57 0.00e+00 3.160598e-04 1.982285e-05 3.867219e-05 -6.000000e+00 1.854896e-04 277.94 -2.00 20.00 -2.00 315.00 0.00e+00 1.317 0.000 302.00 328.00 3 3.1599e+00 5.3720e-04 1.5913e-02 -6.0000e+00 1.0554e-02 1.5211e-02 5.9936e-04 8.9935e-03 -6.0000e+00 1.1479e-02 -1.6416e-04 3.4365e-04 4.4306e-03 -6.0000e+00 6.8235e-03 -1.0645e-03 1.5474e-04 1.2580e-03 -6.0000e+00 2.8882e-03 5.0887e-03 -2.7771e-04 1.1689e-05 1.5525e-05 -6.0000e+00 2.0264e-04 -6.0821e-03 0.0000e+00 10 0 0 10 0 0 99.98 19.96 0.24 -0.00608 -0.00817 523 148 1 5 0 86.690 24.86 20.00 19.96 14.15 20.9 941.23 -243 -498 -1700 -2822 -2128 -1059 492 1526 621 -1391 -1075 -746 113 440 423 -216 200 360 802 981 574 469 540 810 456 312 -496 -434 -158 704 1148 1747 914 -1196 -1689 -1174 -811 44 36 -630 -871 -815 -851 -560 -282 -461 -852 -675 -634 323 579 809 1038 756 743 914 482 430 745 885 1129 1414 1461 938 -196 -208 -432 195 765 518 285 119 86 -13 -31 -149 -512 -415 -344 -713 -1061 -1444 -1860 -1338 -857 -784 -396 -183 -39 200 227 -70 514 794 349 294 389 340 -23 -241 -508 -452 82 -65 -698 -596 -595 -447 31 274 228 359 148 136 93 483 236 343 260 26 -111 233 196 525 532 133 519 762 273 198 -104 155 -115 -309 -190 -55 239 100 -194 -60 -280 -390 -531 -66 -145 -502 -782 -519 -241 115 395 179 -424 -319 -221 36 158 155 -86 81 149 340 426 254 206 239 372 221 156 -246 -201 -68 314 524 772 433 -586 -779 -522 -387 24 22 -444 -669 -604 -645 -425 -212 -372 -672 -511 -463 231 429 636 856 605 608 760 408 362 614 724 949 1265 1407 891 -186 -194 -367 170 650 497 279 122 89 -13 -31 -134 -446 -337 -287 -616 -1028 -1436 -1972 -1476 -1005 -925 -493 -235 -51 247 260 -78 548 805 371 318 464 418 -30 -311 -616 -538 93 -76 -836 -756 -789 -615 41 387 337 533 210 190 118 610 296 421 343 38 -153 319 278 712 684 163 639 926 352 255 -141 213 -160 -444 -272 -82 369 158 -310 -94 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