File name: Pandora135s1_ManhattanNY-CCNY_20230411_L2Fit_fwvt1c15d20200411p1-8.txt File generation date: 20240123T190016.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230411_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230411 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 1654 1803 Nominal wavelengths inside fitting window [nm]: 492.0457 492.1668 492.2878 492.4089 492.5299 492.6509 492.7719 492.8929 493.0138 493.1347 493.2557 493.3766 493.4975 493.6183 493.7392 493.8600 493.9808 494.1016 494.2224 494.3432 494.4639 494.5847 494.7054 494.8261 494.9468 495.0674 495.1881 495.3087 495.4293 495.5499 495.6705 495.7911 495.9116 496.0321 496.1527 496.2732 496.3936 496.5141 496.6345 496.7550 496.8754 496.9958 497.1162 497.2365 497.3569 497.4772 497.5975 497.7178 497.8381 497.9583 498.0786 498.1988 498.3190 498.4392 498.5594 498.6795 498.7997 498.9198 499.0399 499.1600 499.2801 499.4001 499.5202 499.6402 499.7602 499.8802 500.0001 500.1201 500.2400 500.3600 500.4799 500.5997 500.7196 500.8395 500.9593 501.0791 501.1989 501.3187 501.4385 501.5582 501.6779 501.7977 501.9174 502.0370 502.1567 502.2763 502.3960 502.5156 502.6352 502.7548 502.8743 502.9939 503.1134 503.2329 503.3524 503.4719 503.5913 503.7108 503.8302 503.9496 504.0690 504.1883 504.3077 504.4270 504.5464 504.6657 504.7849 504.9042 505.0235 505.1427 505.2619 505.3811 505.5003 505.6195 505.7386 505.8577 505.9769 506.0959 506.2150 506.3341 506.4531 506.5722 506.6912 506.8102 506.9291 507.0481 507.1670 507.2860 507.4049 507.5238 507.6426 507.7615 507.8803 507.9991 508.1179 508.2367 508.3555 508.4742 508.5930 508.7117 508.8304 508.9491 509.0677 509.1864 509.3050 509.4236 509.5422 509.6608 509.7794 509.8979 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230411T125858.5Z 8501.540954 298 1 47.93 2 61.64 104.38 85.35 225.49 0.00 1 0.00 1 0 8 2.334e-03 2.324e-03 8.386e-04 8.378e-04 1.217553e+03 4.808228e+01 8.569394e+01 -6.000000e+00 1.301572e+02 279.83 -2.00 20.00 -2.00 505.27 0.00e+00 9.364575e-04 2.298699e-05 5.092865e-05 -6.000000e+00 6.546688e-05 279.83 -2.00 20.00 -2.00 500.51 0.00e+00 6.112259e-02 1.664947e-02 1.267108e-02 -6.000000e+00 4.696682e-02 228.27 -2.00 3.51 -2.00 502.09 0.00e+00 2.095 0.000 489.00 513.00 1 7.7547e+00 1.2735e-03 3.3975e-03 -6.0000e+00 3.5949e-03 1.1621e-03 3.3129e-04 2.9528e-04 -6.0000e+00 9.3680e-04 6.1205e-04 3.2072e-04 8.6085e-05 2.0882e-05 -6.0000e+00 2.4436e-04 -4.4724e-02 6.8894e-05 10 0 0 10 0 0 -50.95 20.38 0.80 -0.04472 -0.04250 13 4 1 4 0 3686.350 25.17 19.99 20.38 18.16 21.2 969.91 -464 -612 -349 -85 -98 173 366 429 242 -6 329 298 -98 -165 -119 -192 -241 -114 186 91 -62 662 170 228 149 169 197 235 216 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444 52 71 114 65 182 414 72 112 285 212 37 362 241 -193 101 -200 -229 42 119 -221 -190 251 -55 22 80 125 -30 20 -174 -121 -238 -415 SQ 20230411T131103.3Z 8501.549344 305 1 3.86 2 59.44 106.70 86.95 227.50 0.00 1 0.00 1 0 15 1.916e-03 1.913e-03 1.016e-04 1.015e-04 9.111327e+02 5.743913e+00 6.963630e+01 -6.000000e+00 1.068512e+02 279.83 -2.00 20.00 -2.00 505.26 0.00e+00 8.186658e-04 2.781478e-06 4.720009e-05 -6.000000e+00 5.374202e-05 279.83 -2.00 20.00 -2.00 500.50 0.00e+00 5.624276e-02 2.015412e-03 9.600937e-03 -6.000000e+00 3.855271e-02 228.27 -2.00 3.51 -2.00 502.09 0.00e+00 1.959 0.000 489.00 513.00 1 1.0951e+00 1.5420e-04 3.1183e-03 -6.0000e+00 2.9510e-03 1.6000e-03 4.0151e-05 2.3414e-04 -6.0000e+00 7.6887e-04 4.8823e-01 2.8530e-05 1.0418e-05 1.9286e-05 -6.0000e+00 2.0061e-04 -4.5354e-02 8.2877e-05 10 0 0 10 0 0 -12.87 20.41 0.87 -0.04535 -0.04516 791 223 1 4 0 4.620 25.17 20.01 20.41 18.77 21.5 975.80 -297 -286 -145 -14 -9 233 474 422 440 398 301 230 -5 -52 -67 -178 -178 -17 112 6 -37 125 136 211 285 208 72 192 6 -261 -212 -240 -281 168 172 -149 -125 97 -12 -121 -26 -54 -51 35 128 130 117 38 6 -92 -269 -294 -434 -458 -253 -139 -148 -147 -102 -9 92 191 158 125 127 93 45 -23 9 -92 -147 -151 -276 -110 45 -119 -319 -209 -43 -79 -156 -147 -277 -117 32 -101 -141 -35 -20 -97 -107 59 176 116 75 138 -33 -123 -64 -123 -330 -411 -337 -95 -228 -390 -237 -150 -100 60 63 -41 63 128 168 268 336 351 251 206 201 64 174 371 200 97 284 142 38 254 181 32 42 -70 -134 143 172 -115 -84 122 70 72 154 131 36 1 -32 -183 -250 -277 -283 -274 -142 -14 -9 233 483 435 455 408 304 229 -5 -52 -67 -177 -179 -18 114 6 -38 130 141 220 298 212 73 199 6 -259 -211 -237 -283 169 178 -152 -131 101 -12 -123 -26 -55 -53 36 130 132 119 40 6 -92 -270 -288 -418 -442 -249 -136 -149 -150 -104 -9 94 196 162 128 129 94 45 -23 9 -91 -144 -147 -272 -110 43 -116 -318 -205 -41 -76 -150 -142 -272 -116 32 -99 -138 -34 -20 -96 -106 60 179 116 75 139 -33 -120 -63 -118 -315 -395 -331 -94 -230 -386 -240 -150 -99 60 63 -41 63 129 171 274 344 360 256 208 200 63 174 372 201 95 278 139 37 247 181 31 41 -67 -128 138 168 -115 -82 122 70 73 156 133 36 1 -32 -178 -247 -271 SQ 20230411T131109.5Z 8501.549415 305 2 3.91 2 59.42 106.72 86.96 227.52 0.00 1 0.00 1 0 15 1.901e-03 1.896e-03 1.042e-04 1.041e-04 9.311831e+02 5.883046e+00 7.260481e+01 -6.000000e+00 1.060076e+02 279.83 -2.00 20.00 -2.00 505.26 0.00e+00 8.345573e-04 2.861768e-06 4.800236e-05 -6.000000e+00 5.331753e-05 279.83 -2.00 20.00 -2.00 500.52 0.00e+00 5.003794e-02 2.064207e-03 9.552253e-03 -6.000000e+00 3.824786e-02 228.27 -2.00 3.51 -2.00 502.10 0.00e+00 1.958 0.000 489.00 513.00 1 1.1397e+00 1.5791e-04 3.1240e-03 -6.0000e+00 2.9277e-03 1.7943e-03 4.1150e-05 2.3364e-04 -6.0000e+00 7.6278e-04 4.6709e-01 4.6406e-06 1.0675e-05 1.9966e-05 -6.0000e+00 1.9903e-04 -4.5215e-02 8.3437e-05 10 0 0 10 0 0 3.20 20.41 0.87 -0.04521 -0.04518 791 223 1 4 0 4.620 25.17 20.01 20.41 18.77 21.5 975.80 -283 -265 -134 -1 -12 210 468 417 462 369 281 226 18 -41 -51 -186 -156 -25 106 0 -39 135 151 197 255 202 67 198 32 -233 -240 -232 -276 190 167 -152 -145 67 -6 -116 -22 -36 -35 42 131 109 84 11 -2 -75 -247 -305 -424 -454 -218 -165 -154 -174 -106 -3 128 197 134 115 121 108 42 2 11 -88 -147 -156 -293 -122 16 -114 -324 -209 -28 -56 -116 -147 -286 -117 44 -124 -127 -41 -19 -52 -110 77 192 138 83 138 -44 -128 2 -125 -342 -435 -333 -82 -238 -419 -215 -143 -136 73 78 -53 41 109 178 243 324 357 234 214 194 61 154 380 214 99 272 157 72 267 177 5 25 -82 -144 119 158 -77 -64 130 60 71 166 128 30 7 -27 -162 -256 -276 -274 -258 -129 -1 -12 214 485 424 470 374 289 229 18 -41 -51 -188 -154 -25 110 0 -41 138 155 203 263 209 69 202 32 -235 -236 -226 -274 193 170 -157 -150 69 -6 -120 -23 -37 -35 43 135 113 86 11 -2 -76 -245 -304 -416 -445 -211 -164 -158 -175 -106 -3 129 199 136 116 122 108 43 2 11 -85 -143 -150 -285 -120 16 -113 -318 -202 -28 -55 -114 -145 -277 -114 43 -123 -127 -41 -19 -52 -111 76 192 139 84 137 -44 -126 2 -118 -332 -425 -323 -82 -237 -421 -214 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