File name: Pandora135s1_ManhattanNY-CCNY_20230521_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20240123T190849.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230521_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230521 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230521T132549.5Z 8541.559601 190 1 47.39 2 48.21 99.20 62.88 76.99 0.00 1 0.00 1 0 17 1.145e-02 5.581e-03 4.466e-03 1.843e-03 2.315288e-01 9.575645e-04 2.792411e-03 -6.000000e+00 6.748123e-03 231.46 -2.00 3.51 -2.00 316.67 0.00e+00 4.969537e-04 1.164186e-04 1.089309e-04 -6.000000e+00 2.938074e-04 284.15 -2.00 20.00 -2.00 315.96 0.00e+00 1.498 0.000 302.00 328.00 3 5.7160e+00 2.5171e-03 1.9374e-02 -6.0000e+00 1.6918e-02 6.6489e-03 2.7967e-03 1.2085e-02 -6.0000e+00 1.8211e-02 -3.6355e-03 1.6437e-03 5.8953e-03 -6.0000e+00 1.0818e-02 -2.1879e-04 7.9552e-04 1.6574e-03 -6.0000e+00 4.6867e-03 2.9354e-04 -7.5200e-05 5.2540e-05 1.8349e-05 -6.0000e+00 3.1180e-04 -4.7472e-02 2.0534e-04 10 0 0 10 0 0 99.78 20.68 0.30 -0.04747 -0.04804 20 6 1 5 0 2369.180 25.47 20.00 20.68 21.30 21.7 991.68 -349 -682 -3058 -4497 649 -8517 -1030 -198 909 -2924 -689 -680 613 1474 -1107 634 -440 385 461 2008 306 790 1277 751 746 392 -110 -101 63 -1002 1272 70 621 -1358 -1386 -1217 -1422 668 -22 196 -1303 -799 -1122 -1372 2 -81 -356 -778 213 699 291 632 899 391 1261 1177 167 214 554 885 1533 1677 1244 924 -242 52 141 151 436 209 254 40 72 202 332 -60 -845 -1017 -526 -1105 -1159 -1495 -1636 -1171 -591 -352 -64 175 304 354 -81 -191 231 360 -297 -11 400 380 32 -97 -630 -759 -200 -349 -763 -670 -544 -85 -119 444 466 613 228 2 226 377 -177 192 392 -214 122 428 421 597 565 -671 88 349 392 380 -22 52 -10 -33 -160 -35 473 -21 -371 -30 -444 -627 -54 -110 -512 -745 91 -1248 -148 -32 159 -553 -126 -127 125 326 -284 173 -126 113 140 622 98 249 408 253 266 144 -40 -35 20 -316 412 25 235 -532 -509 -437 -556 287 -11 112 -824 -504 -728 -898 1 -54 -233 -497 131 430 188 436 627 287 943 899 131 167 421 668 1187 1392 1080 850 -223 44 114 119 365 191 243 40 72 193 307 -52 -665 -792 -409 -970 -1098 -1504 -1752 -1262 -677 -417 -80 216 377 436 -95 -213 234 366 -308 -12 487 492 42 -127 -799 -916 -229 -416 -957 -888 -727 -118 -167 661 705 933 344 3 309 484 -229 258 545 -310 181 624 616 836 777 -888 113 450 519 540 -32 77 -15 -49 -255 -57 787 -35 -620 -50 -721 -1015 SS 20230521T134632.0Z 8541.573981 203 1 41.53 2 44.37 103.32 59.14 79.80 0.00 1 0.00 1 0 17 7.602e-03 5.430e-03 4.671e-04 2.536e-04 2.149600e-01 1.330960e-04 2.602348e-03 -6.000000e+00 4.478494e-03 231.46 -2.00 3.51 -2.00 315.85 0.00e+00 2.860581e-04 1.344346e-05 4.642803e-05 -6.000000e+00 1.949954e-04 284.15 -2.00 20.00 -2.00 315.19 0.00e+00 1.397 0.000 302.00 328.00 3 1.9628e+00 3.4577e-04 1.8021e-02 -6.0000e+00 1.1228e-02 1.1734e-02 3.8206e-04 1.1195e-02 -6.0000e+00 1.2086e-02 -3.0865e-03 2.2068e-04 5.4521e-03 -6.0000e+00 7.1797e-03 5.5801e-04 1.0285e-04 1.5210e-03 -6.0000e+00 3.1102e-03 1.4235e-02 1.0951e-05 7.1937e-06 1.8184e-05 -6.0000e+00 2.0696e-04 -4.6969e-02 2.0232e-04 12 1 1 12 1 1 99.79 20.73 0.24 -0.04697 -0.04689 858 261 1 5 0 47.920 25.47 19.98 20.73 22.46 21.7 998.85 -409 -1121 -1541 -3004 -2066 -1905 279 814 53 -1470 -1374 -833 -228 596 169 -173 26 598 813 1005 655 697 1000 770 614 213 -191 -471 210 658 1191 1598 583 -1168 -1595 -1246 -1033 -106 -195 -603 -972 -710 -882 -531 -291 -425 -778 -737 -516 300 640 693 1039 755 754 859 558 486 689 965 1135 1423 1282 791 -202 -99 -317 416 754 378 241 76 74 -75 8 -176 -381 -331 -236 -735 -993 -1463 -1770 -1281 -893 -657 -452 -201 -93 235 232 62 565 824 440 414 511 84 6 -288 -422 -520 175 -130 -696 -627 -634 -422 23 276 117 277 55 168 143 585 340 392 261 -49 -138 113 195 458 520 94 628 763 449 248 -81 227 -104 -180 -156 -47 226 44 -369 -222 -496 -506 -93 -278 -386 -709 -430 -377 57 186 14 -393 -361 -222 -61 180 58 -64 10 233 327 415 276 291 422 315 266 95 -84 -196 87 265 498 716 260 -537 -749 -570 -473 -57 -115 -413 -677 -514 -655 -395 -215 -313 -560 -514 -373 215 448 517 813 620 634 690 456 395 585 813 924 1239 1209 743 -189 -90 -265 357 647 368 241 79 77 -75 8 -157 -327 -268 -199 -655 -993 -1517 -1955 -1394 -1035 -772 -560 -256 -119 286 276 67 584 821 464 453 618 106 8 -379 -519 -621 198 -154 -852 -811 -857 -563 32 406 172 408 77 230 188 721 441 504 362 -69 -201 162 271 640 689 119 789 959 571 337 -110 313 -145 -262 -229 -73 358 72 -603 -354 -766 -753 SS 20230521T135128.9Z 8541.577417 206 1 17.13 2 43.46 104.36 58.24 80.48 0.00 1 0.00 1 0 17 8.839e-03 5.608e-03 2.532e-03 1.208e-03 2.115883e-01 6.306416e-04 2.574829e-03 -6.000000e+00 5.207579e-03 231.46 -2.00 3.51 -2.00 316.25 0.00e+00 3.743313e-04 6.968733e-05 6.759395e-05 -6.000000e+00 2.267397e-04 284.15 -2.00 20.00 -2.00 315.56 0.00e+00 1.376 0.000 302.00 328.00 3 3.9831e+00 1.6493e-03 1.7781e-02 -6.0000e+00 1.3056e-02 2.7346e-02 1.8269e-03 1.1083e-02 -6.0000e+00 1.4054e-02 1.3230e-04 1.0619e-03 5.4052e-03 -6.0000e+00 8.3484e-03 -1.4463e-03 5.0408e-04 1.5146e-03 -6.0000e+00 3.6165e-03 1.9242e-03 4.2340e-05 3.4426e-05 1.7693e-05 -6.0000e+00 2.4063e-04 -4.6742e-02 2.2000e-04 12 1 1 12 1 1 100.00 20.74 0.21 -0.04674 -0.04642 97 75 1 5 0 173.020 25.47 20.00 20.74 22.37 21.7 998.60 -882 203 -1152 -3066 -1842 -1530 1536 760 1023 -1211 -230 -634 621 241 -28 109 709 699 836 1068 551 1005 -5354 776 313 515 -342 -133 381 784 1436 1268 823 -1346 -1259 -1690 -859 55 197 -470 -1089 -982 -963 -322 -453 -275 -668 -577 -496 285 591 736 967 690 886 888 749 295 701 1135 1365 1453 1347 944 -162 -94 -342 447 707 544 19 73 -118 -85 13 38 -479 -520 -112 -590 -962 -1497 -1574 -1232 -881 -726 -401 -86 -15 312 126 15 437 741 398 359 392 300 18 -368 -381 -631 215 -231 -654 -837 -520 -508 -26 302 128 304 116 48 221 479 297 369 231 -17 -68 272 126 447 416 -83 685 778 432 190 -13 269 84 -326 -268 -63 206 163 -374 -102 -566 -413 -166 41 -236 -594 -328 -258 265 148 220 -264 -51 -143 147 65 -8 34 229 241 286 376 198 356 -2048 293 125 211 -139 -51 140 279 529 502 336 -567 -518 -682 -374 27 110 -292 -740 -694 -671 -232 -326 -197 -467 -390 -325 185 401 531 733 528 694 708 606 239 553 889 1101 1255 1215 900 -154 -82 -283 356 600 504 19 74 -120 -83 12 33 -393 -404 -91 -516 -911 -1511 -1687 -1334 -1017 -869 -506 -108 -20 386 149 16 453 739 420 402 470 383 24 -489 -473 -745 248 -270 -834 -1096 -708 -698 -38 444 197 468 172 68 292 612 379 477 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