File name: Pandora135s1_ManhattanNY-CCNY_20230602_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T131205.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230602_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230602 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230602T133352.5Z 8553.565191 317 1 18.04 2 45.77 98.28 148.61 303.39 0.00 1 0.00 1 0 17 8.280e-03 5.497e-03 4.689e-04 2.429e-04 2.251364e-01 1.242272e-04 2.676004e-03 -6.000000e+00 4.786966e-03 232.16 -2.00 3.51 -2.00 316.08 0.00e+00 3.477949e-04 1.338726e-05 5.297522e-05 -6.000000e+00 2.119649e-04 285.34 -2.00 20.00 -2.00 315.34 0.00e+00 1.432 0.000 302.00 328.00 3 1.0525e+00 3.2547e-04 1.8602e-02 -6.0000e+00 1.2008e-02 -6.5591e-03 3.6322e-04 1.1674e-02 -6.0000e+00 1.3014e-02 -2.6708e-03 2.0811e-04 5.6593e-03 -6.0000e+00 7.7363e-03 2.1457e-04 9.4669e-05 1.5460e-03 -6.0000e+00 3.2415e-03 3.4072e-02 -3.6111e-04 6.8849e-06 1.8191e-05 -6.0000e+00 2.2552e-04 2.9810e-02 0.0000e+00 12 1 1 12 1 1 35.58 21.78 0.25 0.02981 0.02710 800 538 1 5 0 21.790 26.41 20.00 21.78 30.52 22.4 1056.35 -401 -1104 -1894 -3421 -2734 -1968 98 823 -141 -1856 -1777 -937 -198 629 338 -96 108 638 841 1009 516 597 1407 831 741 258 -324 -592 86 812 1469 2016 529 -1416 -1717 -1241 -875 27 -42 -658 -945 -678 -774 -429 -262 -471 -696 -858 -527 307 547 782 978 607 662 720 435 385 583 986 1151 1484 1362 793 -196 -185 -271 581 958 503 298 78 138 -71 -81 -167 -448 -362 -267 -713 -1052 -1566 -1800 -1331 -847 -581 -383 -127 24 357 374 204 682 817 371 386 409 87 -59 -338 -612 -535 77 -292 -658 -692 -648 -437 70 264 123 238 59 68 105 436 343 336 241 -66 -10 189 275 605 522 168 652 664 368 214 -41 237 -60 -238 -132 43 275 76 -282 -72 -380 -387 -601 -86 -256 -439 -738 -525 -364 19 180 -34 -429 -440 -239 -51 184 112 -34 40 240 302 373 194 222 532 333 313 112 -138 -236 35 320 609 828 235 -640 -729 -523 -406 14 -25 -427 -662 -492 -574 -318 -193 -346 -499 -597 -357 208 391 596 734 477 533 590 362 318 472 796 964 1257 1248 765 -186 -160 -230 484 814 484 293 80 139 -69 -77 -151 -367 -285 -224 -635 -1051 -1623 -1977 -1449 -984 -685 -475 -161 30 428 433 226 690 812 394 429 479 111 -76 -444 -748 -634 87 -351 -819 -908 -846 -593 100 379 185 356 84 94 139 545 432 445 328 -91 -14 262 388 812 699 214 829 814 484 286 -58 336 -86 -344 -203 66 432 121 -455 -113 -576 -591 -908 SS 20230602T134023.5Z 8553.569716 321 1 40.51 2 44.56 99.54 149.59 305.49 0.00 1 0.00 1 0 17 8.182e-03 5.527e-03 2.499e-04 1.309e-04 2.208163e-01 6.698989e-05 2.628934e-03 -6.000000e+00 4.729875e-03 232.16 -2.00 3.51 -2.00 316.08 0.00e+00 3.527388e-04 7.202718e-06 6.065680e-05 -6.000000e+00 2.094638e-04 285.34 -2.00 20.00 -2.00 315.34 0.00e+00 1.401 0.000 302.00 328.00 3 6.1687e-01 1.7529e-04 1.8223e-02 -6.0000e+00 1.1865e-02 -5.7196e-03 1.9571e-04 1.1441e-02 -6.0000e+00 1.2860e-02 -3.0217e-03 1.1192e-04 5.5419e-03 -6.0000e+00 7.6443e-03 7.6094e-04 5.0850e-05 1.5111e-03 -6.0000e+00 3.2025e-03 5.4651e-02 -4.4599e-04 3.7086e-06 1.7904e-05 -6.0000e+00 2.2286e-04 3.0674e-02 0.0000e+00 10 0 0 10 0 0 30.22 21.81 0.26 0.03067 0.02732 3119 880 1 5 0 12.250 26.41 20.01 21.81 31.10 22.5 1061.47 -419 -1043 -1930 -3400 -2660 -1796 30 814 -110 -1831 -1725 -805 -196 664 313 -185 155 612 782 1076 573 664 826 859 628 194 -346 -655 42 722 1443 1775 432 -1603 -1719 -1382 -860 50 -35 -560 -926 -662 -769 -409 -282 -422 -760 -764 -445 374 618 790 1008 632 748 821 501 425 661 984 1211 1553 1464 831 -231 -233 -376 526 919 486 333 114 132 8 -71 -219 -542 -471 -422 -804 -1062 -1629 -1761 -1252 -820 -558 -337 -107 29 278 278 38 489 706 321 355 417 120 -60 -345 -550 -558 122 -333 -740 -675 -640 -404 84 288 194 283 112 135 142 463 306 323 192 -99 -20 204 277 631 574 185 704 704 364 211 -46 194 -73 -304 -207 -30 274 72 -246 -69 -362 -361 -583 -91 -244 -452 -739 -515 -334 6 179 -27 -463 -428 -205 -51 195 103 -66 57 230 302 428 231 266 338 341 263 84 -146 -281 17 282 591 781 190 -715 -778 -621 -393 27 -21 -357 -637 -471 -560 -297 -204 -304 -534 -521 -295 248 431 587 788 484 586 656 407 342 521 774 989 1362 1305 780 -214 -209 -311 426 805 454 337 112 137 8 -65 -192 -461 -384 -366 -738 -1027 -1730 -1870 -1390 -921 -669 -425 -131 36 339 313 41 507 718 349 402 495 149 -79 -436 -682 -672 141 -387 -935 -854 -845 -554 115 417 294 425 160 187 189 585 390 433 264 -138 -29 285 394 854 777 239 859 872 483 285 -65 276 -106 -442 -319 -46 430 115 -397 -108 -549 -553 -884 SS 20230602T134536.6Z 8553.573340 324 1 39.63 2 43.58 100.57 150.36 307.25 0.00 1 0.00 1 0 17 8.103e-03 5.494e-03 2.404e-04 1.286e-04 2.176648e-01 6.584919e-05 2.595746e-03 -6.000000e+00 4.683994e-03 232.16 -2.00 3.51 -2.00 316.01 0.00e+00 3.528876e-04 6.966969e-06 5.795096e-05 -6.000000e+00 2.074409e-04 285.34 -2.00 20.00 -2.00 315.27 0.00e+00 1.379 0.000 302.00 328.00 3 6.0523e-01 1.7221e-04 1.7950e-02 -6.0000e+00 1.1750e-02 -5.1029e-03 1.9214e-04 1.1290e-02 -6.0000e+00 1.2735e-02 -3.2820e-03 1.0986e-04 5.4711e-03 -6.0000e+00 7.5702e-03 9.1095e-04 4.9709e-05 1.4922e-03 -6.0000e+00 3.1713e-03 5.6851e-02 -4.4877e-04 3.6470e-06 1.7716e-05 -6.0000e+00 2.2071e-04 3.0965e-02 0.0000e+00 10 0 0 10 0 0 28.00 21.82 0.26 0.03097 0.02759 3172 895 1 5 0 12.000 26.41 20.00 21.82 31.80 22.5 1065.45 -366 -903 -1902 -3346 -2550 -1797 167 883 -40 -1913 -1652 -757 -143 680 334 -89 160 745 797 1043 557 692 890 847 626 247 -352 -596 43 677 1388 1723 380 -1625 -1766 -1381 -882 93 -56 -539 -925 -684 -777 -401 -298 -441 -767 -777 -477 366 617 764 991 640 756 809 496 416 627 1012 1199 1532 1436 835 -202 -204 -361 513 861 455 302 98 124 -24 -41 -220 -555 -468 -423 -820 -1047 -1643 -1747 -1246 -808 -564 -346 -89 29 281 260 54 481 717 271 337 397 128 -74 -360 -547 -540 111 -348 -719 -663 -619 -377 85 292 167 279 127 146 130 477 306 308 208 -95 -19 221 289 627 585 176 683 691 366 218 -79 210 -79 -289 -190 -26 286 77 -244 -61 -357 -371 -595 -83 -218 -462 -753 -511 -347 34 201 -10 -501 -424 -199 -38 205 113 -33 60 287 317 426 213 284 345 345 269 109 -152 -241 17 271 582 715 170 -739 -752 -633 -411 51 -34 -349 -648 -496 -575 -297 -219 -323 -548 -538 -321 246 437 576 785 498 600 655 408 338 500 806 991 1361 1296 792 -188 -184 -301 419 762 429 308 98 123 -24 -38 -195 -475 -384 -346 -758 -1019 -1659 -1867 -1392 -914 -681 -417 -110 35 344 293 58 501 732 296 384 473 160 -97 -457 -679 -652 129 -406 -912 -842 -820 -518 117 423 241 421 183 202 165 602 390 393 287 -132 -26 308 412 850 753 227 834 857 487 293 -111 300 -115 -420 -292 -40 448 123 -393 -96 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