File name: Pandora135s1_ManhattanNY-CCNY_20230606_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T132849.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230606_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230606 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230606T134532.5Z 8557.573293 327 1 23.87 2 43.45 99.87 112.83 252.46 0.00 1 0.00 1 0 17 1.192e-02 6.086e-03 5.615e-03 2.335e-03 2.278162e-01 1.190105e-03 2.702328e-03 -6.000000e+00 6.907696e-03 232.39 -2.00 3.51 -2.00 316.73 0.00e+00 7.477112e-04 1.481184e-04 7.764803e-05 -6.000000e+00 3.055099e-04 285.74 -2.00 20.00 -2.00 315.94 0.00e+00 1.376 0.000 302.00 328.00 3 5.5376e+00 3.1440e-03 1.8313e-02 -6.0000e+00 1.7338e-02 2.2453e-02 3.5184e-03 1.1857e-02 -6.0000e+00 1.8771e-02 -1.5297e-03 2.0445e-03 5.7437e-03 -6.0000e+00 1.1159e-02 -2.0812e-03 9.6191e-04 1.6230e-03 -6.0000e+00 4.6881e-03 3.9634e-04 -2.3002e-04 6.6718e-05 1.7850e-05 -6.0000e+00 3.2428e-04 1.4039e-02 0.0000e+00 12 1 1 12 1 1 99.98 21.00 0.32 0.01404 0.01231 24 14 1 5 0 947.810 25.79 20.00 21.00 22.42 22.1 1000.17 1170 357 -1491 -6162 1773 -6116 822 -2437 2513 -2016 121 -2199 937 1087 -1356 655 -1018 1483 -571 2215 -134 791 -1010 764 198 -146 -274 -374 2090 -1332 2382 507 2281 -3053 -693 -1059 -758 467 -164 -238 -1276 -890 -1483 -394 -295 142 -585 -843 -285 524 -88 444 1090 384 1833 572 598 36 453 674 1952 1551 1441 1105 -224 -365 -792 461 541 717 234 472 -2 135 164 -269 -59 -938 -59 -1185 -751 -1412 -1548 -1275 -645 -729 -287 -103 -161 565 -38 642 325 841 71 347 -7 453 -125 -351 -605 -801 70 -622 -619 -885 -226 -288 50 480 43 561 -157 153 -163 739 246 304 163 4 -356 448 439 685 572 -848 523 604 477 -69 48 449 -37 -19 -260 -121 376 279 -294 106 -403 -240 -789 184 59 -259 -1038 247 -883 118 -406 438 -378 22 -419 193 246 -355 182 -297 436 -177 690 -43 251 -332 259 71 -54 -100 -127 650 -421 765 179 847 -1203 -250 -378 -295 204 -86 -139 -788 -570 -978 -259 -193 92 -384 -539 -176 323 -58 298 767 284 1369 441 467 28 344 511 1514 1258 1265 993 -200 -309 -639 359 439 657 227 473 -2 130 150 -229 -45 -716 -46 -1037 -710 -1427 -1612 -1388 -725 -879 -354 -130 -203 697 -43 702 325 839 74 382 -8 574 -168 -460 -763 -956 79 -743 -778 -1179 -304 -403 71 723 66 862 -231 220 -221 935 313 406 228 5 -531 652 638 951 775 -1107 658 764 626 -95 68 651 -54 -29 -404 -196 625 462 -491 178 -651 -383 -1242 SS 20230606T135038.3Z 8557.576832 330 1 46.39 2 42.50 100.89 113.71 253.15 0.00 1 0.00 1 0 17 9.757e-03 5.629e-03 2.607e-03 1.091e-03 2.228258e-01 5.563908e-04 2.649222e-03 -6.000000e+00 5.656146e-03 232.39 -2.00 3.51 -2.00 316.72 0.00e+00 4.241828e-04 6.914273e-05 6.784208e-05 -6.000000e+00 2.501599e-04 285.74 -2.00 20.00 -2.00 315.93 0.00e+00 1.355 0.000 302.00 328.00 3 4.7337e+00 1.4704e-03 1.7990e-02 -6.0000e+00 1.4197e-02 1.3380e-02 1.6457e-03 1.1607e-02 -6.0000e+00 1.5370e-02 2.3289e-04 9.5434e-04 5.6188e-03 -6.0000e+00 9.1375e-03 -2.8633e-03 4.4815e-04 1.5418e-03 -6.0000e+00 3.8386e-03 9.1714e-04 -1.5791e-04 3.1296e-05 1.7605e-05 -6.0000e+00 2.6553e-04 1.4169e-02 0.0000e+00 10 0 0 10 0 0 100.00 21.00 0.22 0.01417 0.01298 166 47 1 5 0 279.430 25.79 20.00 21.00 22.87 22.1 1003.37 689 -124 -1946 -2117 -1161 -1628 1078 1312 1027 -1417 -606 -195 830 797 -19 39 351 539 927 865 266 250 -6964 742 256 630 -452 -115 448 682 1729 2294 1153 -1784 -1920 -1271 -454 271 117 -589 -950 -920 -942 -539 -514 -464 -846 -670 -368 793 357 1021 1362 781 802 961 414 464 570 915 1401 1548 1481 859 -337 -220 -356 317 963 421 201 -52 -38 38 -198 125 -662 -341 -190 -704 -924 -1446 -1711 -1214 -674 -622 -194 -112 75 319 384 55 667 926 447 288 353 135 -28 -329 -533 -533 -28 -55 -738 -557 -735 -336 -146 211 90 207 103 58 165 507 360 258 105 -88 -104 144 319 686 399 -283 631 660 452 232 -69 174 -84 -278 -142 -35 433 43 -231 -89 -364 -273 -388 108 -21 -337 -339 -172 -233 160 218 181 -263 -110 -36 169 185 -5 11 103 162 288 278 87 81 -2370 257 90 226 -168 -40 144 215 566 805 438 -701 -708 -459 -178 119 62 -344 -603 -608 -612 -364 -346 -310 -554 -424 -226 484 230 698 978 566 596 727 319 354 427 682 1076 1275 1271 780 -304 -188 -281 243 788 376 196 -50 -38 37 -178 105 -522 -255 -149 -601 -851 -1466 -1778 -1316 -778 -743 -243 -140 96 391 450 58 666 898 461 316 429 175 -37 -439 -663 -631 -31 -65 -920 -733 -1011 -463 -210 313 139 321 152 82 221 659 469 340 149 -129 -157 214 457 969 537 -363 790 831 587 322 -98 249 -123 -422 -221 -57 722 71 -384 -149 -590 -441 -616 SS 20230606T135540.9Z 8557.580334 333 1 17.91 2 41.57 101.93 114.57 253.83 0.00 1 0.00 1 0 17 7.933e-03 5.521e-03 1.159e-03 6.226e-04 2.195773e-01 3.195734e-04 2.623964e-03 -6.000000e+00 4.598823e-03 232.39 -2.00 3.51 -2.00 315.92 0.00e+00 3.441232e-04 3.335003e-05 5.299981e-05 -6.000000e+00 2.033999e-04 285.74 -2.00 20.00 -2.00 315.19 0.00e+00 1.335 0.000 302.00 328.00 3 3.0292e+00 8.3627e-04 1.7719e-02 -6.0000e+00 1.1543e-02 6.1427e-03 9.3219e-04 1.1421e-02 -6.0000e+00 1.2497e-02 -3.7988e-03 5.3300e-04 5.5351e-03 -6.0000e+00 7.4295e-03 -1.5909e-04 2.4106e-04 1.5113e-03 -6.0000e+00 3.1210e-03 5.1974e-03 -2.8652e-04 1.7600e-05 1.8315e-05 -6.0000e+00 2.1590e-04 1.4353e-02 0.0000e+00 12 1 1 12 1 1 99.37 21.00 0.26 0.01435 0.01220 111 82 1 5 0 158.360 25.79 20.00 21.00 23.20 22.0 1004.86 -433 -642 -1488 -3523 -2161 -1950 250 853 667 -1772 -969 -1056 38 687 253 -464 -19 822 692 1171 140 811 963 974 440 222 -506 -649 195 517 1392 1668 670 -1532 -1561 -1170 -962 -10 -101 -686 -968 -659 -850 -532 -329 -370 -692 -715 -516 301 527 761 973 530 677 925 496 417 788 933 1275 1453 1453 813 -111 -115 -267 549 801 514 178 3 109 6 -140 -179 -372 -446 -241 -835 -1054 -1553 -1729 -1280 -861 -664 -485 -115 -32 275 225 150 548 930 439 286 467 152 -139 -416 -607 -456 167 -264 -825 -596 -604 -428 54 294 172 277 116 130 150 575 268 354 171 -87 -129 176 167 466 563 92 650 814 471 259 37 179 -40 -135 -135 -54 213 8 -280 -112 -386 -340 -517 -99 -145 -340 -826 -447 -386 52 197 170 -436 -254 -260 10 210 87 -174 -7 324 260 452 55 316 381 405 194 101 -227 -272 82 212 595 706 306 -719 -687 -505 -454 -5 -62 -452 -692 -489 -646 -405 -249 -278 -508 -509 -357 207 381 585 737 421 551 765 418 349 644 760 1071 1309 1332 787 -107 -101 -230 457 716 489 175 3 111 6 -134 -164 -307 -374 -199 -777 -1036 -1585 -1875 -1372 -984 -771 -593 -145 -40 328 262 166 552 962 455 327 560 191 -184 -540 -736 -534 196 -310 -1056 -763 -808 -567 75 431 251 405 170 176 194 737 344 454 236 -123 -186 249 230 643 737 115 806 1013 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