File name: Pandora135s1_ManhattanNY-CCNY_20230629_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T142733.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230629_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230629 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230629T134007.1Z 8580.569526 242 1 46.54 2 45.04 97.26 156.76 13.45 0.00 1 0.00 1 0 17 8.550e-03 5.571e-03 3.362e-03 1.598e-03 2.063908e-01 8.184061e-04 2.441857e-03 -6.000000e+00 4.960334e-03 232.90 -2.00 3.51 -2.00 316.37 0.00e+00 4.226939e-04 9.429365e-05 6.422068e-05 -6.000000e+00 2.212563e-04 287.95 -2.00 20.00 -2.00 315.56 0.00e+00 1.413 0.000 302.00 328.00 3 5.5268e+00 2.1555e-03 1.7854e-02 -6.0000e+00 1.2456e-02 3.0093e-02 2.4080e-03 1.0754e-02 -6.0000e+00 1.3482e-02 3.9857e-03 1.3846e-03 5.1820e-03 -6.0000e+00 8.0218e-03 -3.7889e-03 6.3754e-04 1.4128e-03 -6.0000e+00 3.3678e-03 4.0292e-04 -2.3924e-04 4.5549e-05 1.6394e-05 -6.0000e+00 2.3288e-04 2.4266e-02 0.0000e+00 10 0 0 10 0 0 99.97 21.42 0.07 0.02427 0.02247 42 12 1 5 0 1107.910 26.11 20.01 21.42 28.70 22.6 1042.54 23 -1106 -1680 -3981 -840 -3084 6 1529 787 -1426 -1714 -372 1 812 -1095 84 575 48 934 1336 -337 805 248 826 208 157 -562 159 29 48 1107 1667 1227 -1403 -2220 -1346 -1023 440 265 -655 -844 -952 -762 -774 -223 -4 -629 -927 -718 1068 525 722 848 561 857 1255 461 306 350 824 1424 1656 1192 791 -195 -329 -469 -277 834 144 321 273 398 73 -55 -29 -594 -864 -787 -775 -1430 -1356 -1776 -982 -864 -532 -91 4 259 599 177 -128 421 355 19 97 453 531 178 -212 -649 -557 155 -309 -738 -487 -823 -321 79 185 470 432 108 39 129 -15 348 -7 347 -46 83 308 390 660 425 -660 316 736 317 453 -252 178 -167 -253 -322 21 426 287 -237 -68 -185 -456 -480 4 -226 -343 -762 -145 -524 1 299 164 -310 -366 -81 0 220 -326 26 185 16 318 467 -121 283 90 312 83 64 -226 59 11 17 407 654 496 -580 -898 -536 -431 216 150 -413 -573 -650 -530 -539 -159 -3 -435 -621 -467 685 356 521 621 429 668 993 372 245 275 645 1150 1435 1084 754 -182 -290 -381 -220 710 135 314 277 400 70 -51 -25 -476 -664 -637 -681 -1368 -1372 -1906 -1064 -1003 -641 -115 5 323 733 206 -139 428 352 20 110 545 681 232 -279 -796 -647 178 -363 -945 -636 -1096 -443 113 274 704 662 158 54 168 -19 441 -9 484 -67 123 448 550 912 559 -854 385 903 415 613 -358 255 -238 -376 -494 34 678 466 -389 -109 -292 -698 -745 SS 20230629T134517.8Z 8580.573123 246 1 42.78 2 44.07 98.24 156.54 16.36 0.00 1 0.00 1 0 17 8.469e-03 5.583e-03 1.314e-03 6.888e-04 2.023356e-01 3.544089e-04 2.407614e-03 -6.000000e+00 4.913140e-03 232.90 -2.00 3.51 -2.00 316.03 0.00e+00 3.146385e-04 3.789805e-05 6.027421e-05 -6.000000e+00 2.191622e-04 287.95 -2.00 20.00 -2.00 315.24 0.00e+00 1.390 0.000 302.00 328.00 3 3.9450e+00 9.2931e-04 1.7542e-02 -6.0000e+00 1.2337e-02 2.4212e-02 1.0364e-03 1.0548e-02 -6.0000e+00 1.3354e-02 2.7052e-03 5.9317e-04 5.0959e-03 -6.0000e+00 7.9456e-03 -2.1700e-03 2.6902e-04 1.3839e-03 -6.0000e+00 3.3356e-03 2.0270e-03 -2.2985e-04 1.9584e-05 1.6605e-05 -6.0000e+00 2.3068e-04 2.4560e-02 0.0000e+00 12 1 1 12 9 1 99.99 21.43 0.29 0.02456 0.02283 175 54 1 5 0 242.050 26.11 20.01 21.43 29.38 22.7 1047.38 -411 -841 -1765 -3900 -1920 -2122 1038 633 789 -1823 -1258 -898 -20 732 -126 103 75 575 494 1022 -87 550 2566 799 566 276 -164 -536 244 365 1356 1632 702 -1830 -2034 -1359 -814 11 -201 -535 -1066 -827 -851 -449 -444 -289 -845 -679 -536 292 757 687 1189 673 782 887 511 388 659 974 1015 1609 1393 1099 -300 -188 -560 218 758 475 344 201 177 17 102 -137 -487 -693 -414 -825 -1098 -1593 -1672 -1266 -678 -487 -254 -49 61 354 95 -37 354 544 293 281 446 250 105 -267 -487 -663 -50 -232 -729 -718 -571 -486 34 373 251 438 115 128 23 258 37 200 178 -17 32 270 393 579 637 -71 585 584 434 106 69 168 -100 -195 -267 24 354 132 -211 43 -365 -357 -732 -91 -198 -417 -862 -372 -398 202 139 190 -460 -309 -226 -5 228 -44 35 26 207 184 389 -34 211 982 327 244 122 -71 -217 100 146 565 666 307 -818 -852 -561 -369 6 -117 -358 -772 -619 -650 -343 -337 -217 -621 -481 -369 200 542 524 949 522 619 715 418 315 523 772 835 1415 1322 1020 -275 -167 -460 174 653 463 339 205 179 17 99 -119 -411 -560 -352 -733 -1091 -1619 -1798 -1422 -762 -584 -321 -63 79 433 107 -41 375 562 300 316 520 319 140 -349 -593 -794 -58 -282 -905 -939 -778 -647 47 546 383 664 166 171 30 315 45 258 248 -24 46 379 534 797 831 -88 734 740 549 143 98 240 -145 -278 -404 37 540 207 -331 66 -572 -540 -1095 SS 20230629T134939.0Z 8580.576146 249 1 42.43 2 43.25 99.08 156.32 18.76 0.00 1 0.00 1 0 17 7.725e-03 5.564e-03 2.621e-04 1.521e-04 1.990690e-01 7.829176e-05 2.370687e-03 -6.000000e+00 4.481086e-03 232.90 -2.00 3.51 -2.00 315.69 0.00e+00 3.616608e-04 7.777761e-06 4.739971e-05 -6.000000e+00 1.999128e-04 287.95 -2.00 20.00 -2.00 314.93 0.00e+00 1.371 0.000 302.00 328.00 3 1.0705e+00 2.0446e-04 1.7282e-02 -6.0000e+00 1.1252e-02 5.5918e-03 2.2767e-04 1.0367e-02 -6.0000e+00 1.2180e-02 5.6144e-04 1.2988e-04 5.0026e-03 -6.0000e+00 7.2471e-03 -5.4067e-04 5.8056e-05 1.3618e-03 -6.0000e+00 3.0420e-03 3.7117e-02 -2.5739e-04 4.2925e-06 1.6607e-05 -6.0000e+00 2.1042e-04 2.5270e-02 0.0000e+00 10 0 0 10 0 0 99.92 21.46 0.27 0.02527 0.02334 2015 568 1 5 0 20.470 26.11 20.00 21.46 29.88 22.6 1050.81 -161 -643 -1680 -2957 -2411 -1318 329 1170 192 -1559 -1500 -742 -35 647 480 -150 185 577 812 1036 478 520 120 848 584 285 -375 -554 -29 696 1303 1782 562 -1493 -1831 -1374 -951 -2 -36 -642 -884 -693 -755 -476 -290 -441 -754 -727 -499 364 637 810 1000 683 758 856 513 414 609 941 1160 1490 1476 856 -178 -277 -457 317 840 452 281 128 176 8 -47 -232 -562 -526 -453 -787 -1078 -1569 -1774 -1333 -819 -587 -344 -105 79 292 282 -13 419 618 285 354 431 195 14 -301 -513 -568 50 -274 -708 -672 -661 -447 54 303 222 308 168 134 80 357 247 243 218 -34 8 248 320 631 615 193 606 675 368 256 -35 219 -101 -308 -176 -1 272 77 -233 -81 -335 -391 -634 -40 -169 -443 -723 -572 -298 78 311 52 -437 -412 -208 -11 224 186 -58 73 232 336 441 206 223 52 387 281 141 -182 -251 -12 308 555 810 275 -741 -853 -632 -481 -1 -23 -450 -668 -508 -565 -356 -215 -326 -579 -539 -359 260 477 605 783 559 634 728 443 355 511 788 1008 1306 1394 849 -173 -245 -397 268 764 438 279 131 180 8 -45 -213 -467 -445 -379 -741 -1068 -1609 -1926 -1433 -940 -684 -422 -131 98 347 324 -15 443 637 295 404 514 242 19 -382 -639 -652 58 -320 -900 -855 -878 -587 74 438 320 441 240 185 101 446 311 306 296 -47 12 344 430 850 787 247 735 826 481 338 -48 305 -144 -436 -263 -1 417 121 -368 -124 -498 -588 -943 SS 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