File name: Pandora135s1_ManhattanNY-CCNY_20230705_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T150539.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230705_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230705 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230705T134422.2Z 8586.572480 339 1 38.49 2 44.71 98.37 111.42 258.49 0.00 1 0.00 1 0 17 7.969e-03 5.718e-03 1.940e-04 1.141e-04 1.925134e-01 5.858010e-05 2.286755e-03 -6.000000e+00 4.615049e-03 232.89 -2.00 3.51 -2.00 315.66 0.00e+00 3.840861e-04 5.814646e-06 5.473949e-05 -6.000000e+00 2.068234e-04 288.52 -2.00 20.00 -2.00 314.89 0.00e+00 1.405 0.000 302.00 328.00 3 3.6388e-01 1.5298e-04 1.7322e-02 -6.0000e+00 1.1585e-02 -2.3814e-03 1.7045e-04 1.0018e-02 -6.0000e+00 1.2547e-02 2.4768e-03 9.7139e-05 4.8259e-03 -6.0000e+00 7.4675e-03 -1.2841e-03 4.3231e-05 1.3108e-03 -6.0000e+00 3.1297e-03 7.4129e-02 -3.8796e-04 3.2246e-06 1.5927e-05 -6.0000e+00 2.1720e-04 3.8012e-02 0.0000e+00 10 0 0 10 0 0 20.56 22.07 0.28 0.03801 0.03510 3644 1028 1 5 0 10.090 26.62 20.00 22.07 32.65 23.1 1069.39 -18 -453 -1474 -3034 -2348 -1497 354 1059 55 -1767 -1630 -782 -148 683 396 -80 157 707 848 1058 480 594 609 820 647 286 -257 -648 -90 517 1325 1666 373 -1764 -2063 -1660 -1046 -33 -109 -546 -854 -617 -711 -354 -225 -359 -728 -772 -493 329 626 815 1051 658 731 847 489 421 580 973 1159 1609 1525 943 -186 -314 -536 279 812 459 351 192 205 2 -129 -409 -884 -858 -733 -982 -1159 -1641 -1724 -1228 -716 -413 -152 99 260 460 321 -34 266 425 153 295 477 285 69 -279 -624 -705 -112 -458 -728 -664 -617 -427 100 371 309 429 199 126 14 237 119 199 222 59 164 344 383 638 569 69 478 499 324 226 -11 182 -131 -376 -166 30 319 132 -146 -39 -332 -416 -679 -5 -122 -395 -750 -564 -347 87 290 15 -505 -455 -224 -47 242 156 -31 63 287 355 455 209 256 269 380 314 142 -125 -294 -38 231 569 764 184 -875 -959 -770 -536 -19 -72 -385 -648 -453 -532 -265 -167 -282 -557 -570 -353 235 470 650 823 537 609 717 420 358 485 813 1008 1412 1439 931 -179 -275 -460 235 740 445 347 196 207 2 -123 -370 -727 -723 -615 -927 -1148 -1678 -1860 -1386 -818 -504 -185 123 319 567 364 -37 279 436 159 336 567 353 89 -349 -765 -798 -130 -534 -924 -842 -817 -586 136 534 440 635 279 171 18 293 149 263 301 80 229 472 535 849 719 88 575 609 423 297 -16 252 -185 -530 -248 45 484 205 -228 -59 -512 -620 -1005 SS 20230705T134937.9Z 8586.576134 342 1 38.30 2 43.73 99.38 112.35 259.26 0.00 1 0.00 1 0 17 7.948e-03 5.793e-03 1.880e-04 1.122e-04 1.901308e-01 5.769250e-05 2.261399e-03 -6.000000e+00 4.603028e-03 232.89 -2.00 3.51 -2.00 315.60 0.00e+00 3.943766e-04 5.639037e-06 5.299024e-05 -6.000000e+00 2.062932e-04 288.52 -2.00 20.00 -2.00 314.84 0.00e+00 1.382 0.000 302.00 328.00 3 3.5633e-01 1.5047e-04 1.7063e-02 -6.0000e+00 1.1555e-02 -1.7285e-03 1.6751e-04 9.8955e-03 -6.0000e+00 1.2514e-02 1.8482e-03 9.5534e-05 4.7655e-03 -6.0000e+00 7.4481e-03 -1.0080e-03 4.2486e-05 1.2939e-03 -6.0000e+00 3.1215e-03 7.6738e-02 -4.1343e-04 3.1732e-06 1.5725e-05 -6.0000e+00 2.1664e-04 3.8283e-02 0.0000e+00 10 0 0 10 0 0 16.55 22.09 0.26 0.03828 0.03518 3681 1038 1 5 0 9.960 26.62 20.00 22.09 33.25 23.1 1073.93 144 -461 -1463 -2952 -2265 -1441 380 1073 164 -1691 -1642 -808 -151 664 389 -134 196 762 855 1083 469 599 635 814 666 275 -316 -647 -85 532 1297 1675 389 -1741 -2062 -1651 -1050 -36 -106 -588 -853 -661 -725 -369 -237 -395 -719 -777 -507 336 610 808 1048 686 786 874 534 422 563 944 1181 1594 1532 923 -179 -312 -563 291 798 458 350 206 221 12 -95 -427 -859 -891 -739 -991 -1170 -1632 -1750 -1248 -729 -434 -174 97 254 423 320 -19 289 441 137 303 495 281 88 -276 -621 -686 -101 -467 -738 -669 -626 -417 110 395 342 439 203 111 24 232 132 191 229 54 147 327 378 653 586 78 467 491 348 215 -7 171 -144 -370 -176 26 309 145 -160 -34 -321 -412 -709 38 -128 -404 -753 -561 -344 96 278 47 -497 -472 -238 -49 242 145 -54 80 317 366 477 209 265 286 385 331 140 -157 -299 -37 224 568 782 195 -879 -975 -779 -547 -20 -67 -422 -616 -493 -551 -280 -179 -295 -558 -582 -368 244 465 612 831 567 662 749 464 363 476 799 1039 1415 1463 921 -174 -276 -488 247 734 448 349 212 225 11 -91 -390 -712 -757 -625 -943 -1168 -1681 -1901 -1418 -838 -506 -213 121 315 498 365 -20 304 455 143 346 591 349 114 -347 -765 -780 -117 -548 -941 -852 -832 -547 151 571 490 621 286 150 30 287 165 239 311 74 206 450 530 871 743 100 563 601 455 283 -10 238 -204 -522 -264 39 470 225 -250 -51 -474 -616 -1052 SS 20230705T135449.8Z 8586.579743 345 1 38.23 2 42.76 100.41 113.26 260.02 0.00 1 0.00 1 0 17 7.987e-03 5.830e-03 1.811e-04 1.104e-04 1.868942e-01 5.678560e-05 2.222184e-03 -6.000000e+00 4.625156e-03 232.89 -2.00 3.51 -2.00 315.52 0.00e+00 3.868734e-04 5.451092e-06 5.022084e-05 -6.000000e+00 2.072897e-04 288.52 -2.00 20.00 -2.00 314.76 0.00e+00 1.360 0.000 302.00 328.00 3 3.4737e-01 1.4796e-04 1.6783e-02 -6.0000e+00 1.1610e-02 -1.1409e-03 1.6466e-04 9.7190e-03 -6.0000e+00 1.2574e-02 1.8820e-03 9.3841e-05 4.6827e-03 -6.0000e+00 7.4840e-03 -9.7144e-04 4.1593e-05 1.2725e-03 -6.0000e+00 3.1364e-03 7.9581e-02 -4.0424e-04 3.1209e-06 1.5709e-05 -6.0000e+00 2.1769e-04 3.8428e-02 0.0000e+00 10 0 0 10 0 0 18.52 22.11 0.28 0.03843 0.03539 3743 1056 1 5 0 9.750 26.73 20.00 22.11 33.95 23.1 1077.32 280 -578 -1214 -3151 -2116 -1545 554 1072 169 -1664 -1690 -641 -246 880 229 12 35 808 812 1115 479 576 704 733 696 199 -226 -748 23 430 1366 1591 424 -1721 -2097 -1577 -1123 55 -163 -535 -898 -600 -761 -343 -256 -393 -729 -803 -519 275 660 762 1054 660 799 839 501 428 580 964 1129 1612 1478 956 -226 -283 -596 308 793 464 361 172 231 -10 -99 -418 -818 -905 -691 -1058 -1175 -1669 -1769 -1249 -752 -452 -198 107 221 465 311 -11 259 470 143 305 470 283 102 -291 -580 -730 -68 -509 -734 -701 -610 -410 100 385 336 437 185 145 18 278 131 206 229 35 170 329 406 641 583 61 511 491 361 203 1 155 -164 -369 -176 47 297 144 -165 -28 -337 -410 -700 76 -167 -346 -832 -541 -382 144 287 50 -505 -501 -194 -82 328 88 5 15 344 357 503 219 260 325 355 353 104 -114 -354 10 185 610 757 216 -883 -1009 -756 -596 31 -104 -390 -659 -454 -587 -264 -196 -298 -538 -610 -381 202 508 584 844 551 680 726 440 372 495 823 1004 1445 1425 961 -222 -251 -521 263 691 457 362 177 236 -10 -95 -384 -682 -725 -587 -952 -1178 -1726 -1929 -1349 -868 -530 -243 134 275 549 356 -12 273 486 149 350 562 352 132 -365 -713 -831 -80 -599 -937 -895 -811 -539 137 556 481 618 260 197 23 344 163 258 310 48 237 453 542 855 738 78 614 601 471 267 2 214 -231 -519 -262 70 450 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