File name: Pandora135s1_ManhattanNY-CCNY_20230710_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T151226.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230710_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230710 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230710T134200.8Z 8591.570843 344 1 14.21 2 45.62 98.40 46.46 236.19 0.00 1 0.00 1 0 17 7.839e-03 5.703e-03 5.372e-04 3.152e-04 1.951110e-01 1.620688e-04 2.312100e-03 -6.000000e+00 4.543527e-03 232.89 -2.00 3.51 -2.00 315.66 0.00e+00 3.794255e-04 1.607818e-05 4.568804e-05 -6.000000e+00 2.038131e-04 288.99 -2.00 20.00 -2.00 314.89 0.00e+00 1.428 0.000 302.00 328.00 3 1.3931e+00 4.2296e-04 1.7581e-02 -6.0000e+00 1.1404e-02 6.4286e-03 4.7126e-04 1.0142e-02 -6.0000e+00 1.2346e-02 2.6183e-03 2.6877e-04 4.8829e-03 -6.0000e+00 7.3504e-03 -1.6266e-03 1.1970e-04 1.3300e-03 -6.0000e+00 3.0850e-03 2.5670e-02 -9.0303e-05 8.9247e-06 1.6126e-05 -6.0000e+00 2.1360e-04 3.2053e-02 0.0000e+00 12 1 1 12 1 1 99.89 21.73 0.25 0.03205 0.03137 458 400 1 5 0 30.240 26.32 20.00 21.73 30.89 23.0 1055.22 -7 -531 -1499 -2816 -2427 -1450 415 943 115 -1753 -1570 -722 -112 496 356 -205 84 674 771 1005 501 544 714 794 695 328 -197 -665 55 626 1444 1792 636 -1584 -1914 -1536 -922 7 -155 -605 -977 -663 -768 -471 -262 -365 -738 -763 -564 315 648 781 921 655 696 793 476 425 594 957 1127 1518 1516 958 -150 -349 -570 294 768 449 330 211 194 3 -93 -357 -727 -714 -601 -904 -1095 -1613 -1758 -1279 -747 -471 -234 23 239 441 379 56 360 578 264 329 448 189 96 -273 -643 -674 -119 -440 -756 -720 -629 -510 -7 319 284 372 147 87 12 316 156 185 214 33 151 336 373 647 591 113 475 577 398 256 21 212 -99 -359 -148 45 327 130 -163 -87 -361 -427 -720 -2 -143 -402 -697 -584 -336 101 258 32 -502 -438 -206 -35 176 130 -80 33 275 324 434 219 236 316 369 339 164 -96 -304 23 259 623 825 314 -792 -897 -716 -474 4 -97 -430 -700 -491 -580 -355 -197 -272 -570 -569 -408 227 491 589 728 540 586 679 413 366 501 808 988 1344 1444 954 -146 -309 -495 249 665 439 329 218 199 3 -89 -327 -605 -569 -508 -809 -1093 -1665 -1916 -1381 -861 -551 -287 28 297 523 434 62 381 599 276 378 537 236 126 -346 -799 -772 -139 -518 -919 -921 -839 -674 -10 463 409 531 208 120 15 394 197 234 291 45 213 466 502 870 755 145 577 709 522 340 29 296 -134 -509 -223 68 502 204 -256 -133 -536 -642 -1075 SS 20230710T134744.5Z 8591.574821 348 1 27.04 2 44.55 99.50 47.33 237.67 0.00 1 0.00 1 0 17 9.428e-03 6.110e-03 3.193e-03 1.695e-03 1.951582e-01 8.687412e-04 2.308934e-03 -6.000000e+00 5.465117e-03 232.89 -2.00 3.51 -2.00 316.00 0.00e+00 4.996791e-04 9.296726e-05 6.418456e-05 -6.000000e+00 2.451422e-04 288.99 -2.00 20.00 -2.00 315.20 0.00e+00 1.401 0.000 302.00 328.00 3 5.1848e+00 2.2762e-03 1.7381e-02 -6.0000e+00 1.3717e-02 3.3946e-02 2.5392e-03 1.0156e-02 -6.0000e+00 1.4850e-02 3.6509e-03 1.4517e-03 4.8872e-03 -6.0000e+00 8.8413e-03 -3.3402e-03 6.5731e-04 1.3387e-03 -6.0000e+00 3.7109e-03 5.8657e-04 -5.9612e-05 4.8269e-05 1.5724e-05 -6.0000e+00 2.5691e-04 3.1771e-02 0.0000e+00 12 1 1 12 1 1 99.97 21.75 0.17 0.03177 0.03132 27 14 1 5 0 959.410 26.41 20.00 21.75 31.45 23.0 1058.68 1551 -631 -421 -4095 448 -3718 1534 420 911 -2830 -1839 -1312 751 1800 -334 476 -133 672 338 1390 62 262 -150 601 333 135 538 -1043 713 -544 1782 1126 1146 -1915 -2091 -1560 -930 26 -765 -473 -1082 -358 -868 -139 -303 -334 -914 -839 -945 260 783 630 1332 483 1007 788 526 248 587 767 1298 1939 1414 1003 -286 -217 -981 373 568 300 300 435 424 190 381 -710 -689 -1348 -565 -1275 -922 -1484 -1695 -1091 -627 -339 -9 279 427 685 86 -97 129 420 -195 125 704 304 226 -599 -675 -833 -222 -797 -442 -660 -803 -400 -21 596 346 509 261 80 -97 290 -228 227 134 159 194 234 378 571 602 1 275 249 522 154 -24 185 -231 -459 -168 236 421 333 -234 234 -254 -617 -790 342 -150 -99 -908 88 -740 311 93 220 -721 -454 -332 207 555 -113 170 -49 252 131 550 25 105 -62 257 144 60 239 -437 275 -209 701 477 515 -878 -897 -664 -436 14 -471 -320 -765 -260 -646 -102 -224 -244 -651 -595 -652 178 561 466 1027 390 826 640 433 202 483 632 1075 1718 1315 974 -272 -192 -832 307 493 286 299 447 431 191 354 -613 -553 -1077 -460 -1140 -888 -1521 -1835 -1200 -717 -413 -11 355 539 843 101 -105 131 418 -208 142 831 384 297 -769 -825 -966 -256 -950 -553 -850 -1080 -543 -30 866 510 761 371 110 -126 363 -289 294 183 224 280 331 532 766 785 1 333 306 682 209 -33 256 -328 -663 -251 366 652 526 -372 371 -391 -942 -1193 SS 20230710T140546.7Z 8591.587347 360 1 46.29 2 41.21 103.18 50.16 242.09 0.00 1 0.00 1 0 17 1.647e-02 8.714e-03 5.537e-03 2.667e-03 1.921960e-01 1.358683e-03 2.232524e-03 -6.000000e+00 9.544239e-03 232.89 -2.00 3.51 -2.00 316.38 0.00e+00 7.278389e-04 1.572300e-04 1.132832e-04 -6.000000e+00 4.281026e-04 288.99 -2.00 20.00 -2.00 315.55 0.00e+00 1.328 0.000 302.00 328.00 3 6.3761e+00 3.5758e-03 1.6647e-02 -6.0000e+00 2.3955e-02 4.7701e-02 3.9991e-03 9.8858e-03 -6.0000e+00 2.5934e-02 6.4140e-03 2.2942e-03 4.7523e-03 -6.0000e+00 1.5440e-02 -5.1535e-03 1.0540e-03 1.3219e-03 -6.0000e+00 6.4809e-03 1.9091e-04 -1.4165e-04 7.6210e-05 1.4395e-05 -6.0000e+00 4.4865e-04 3.1538e-02 0.0000e+00 11 9 0 11 8 0 99.96 21.79 0.05 0.03154 0.03047 32 9 1 5 0 1446.200 26.41 20.00 21.79 31.29 23.0 1056.33 9 -1054 -2903 -4205 -2272 -8174 663 -1912 1393 -3764 -2935 -2730 650 2703 -2066 488 163 398 704 886 -185 803 10566 1055 -304 257 -503 28 1875 728 1866 1412 1125 -2538 -2368 -1682 -1630 -208 35 -690 -541 -551 -1159 -764 -603 114 -1050 -929 -1296 235 538 860 1034 602 1430 1394 251 -10 387 939 1688 2376 1443 1659 171 -584 -974 -716 73 325 243 806 509 726 172 -989 -1448 -2370 -984 -1274 -1662 -1620 -2099 -1161 -389 -233 514 512 645 1061 73 -381 -1076 -699 -1077 317 126 1194 128 -82 -461 -791 -1065 -1093 -497 -508 -428 -183 288 455 718 792 213 70 -84 -363 -271 -445 520 374 839 642 810 1254 440 -1873 39 -25 309 114 -184 49 -254 -429 -322 164 616 769 9 318 -243 -834 -1034 2 -224 -620 -829 -393 -1452 115 -384 294 -852 -644 -616 157 726 -648 159 55 136 248 320 -68 290 3526 406 -120 106 -204 11 645 249 662 538 456 -1055 -917 -645 -692 -103 20 -430 -361 -380 -820 -539 -423 79 -711 -628 -853 153 367 622 755 459 1101 1092 201 -8 300 727 1350 2031 1293 1543 156 -504 -776 -579 61 307 240 814 510 697 158 -825 -1133 -1792 -777 -1092 -1590 -1629 -2235 -1286 -444 -283 654 646 832 1300 86 -406 -1087 -690 -1132 349 153 1522 171 -106 -577 -916 -1200 -1302 -638 -664 -583 -257 410 684 1117 1221 312 97 -110 -453 -340 -591 713 546 1205 940 1147 1685 584 -2410 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