File name: Pandora135s1_ManhattanNY-CCNY_20230729_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20230801T052031.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230729_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230729 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230729T133714.4Z 8610.567528 214 1 13.05 2 48.84 101.06 166.34 347.95 0.00 1 0.00 1 0 17 8.836e-03 6.033e-03 3.814e-03 2.022e-03 2.024457e-01 1.055167e-03 2.442084e-03 -6.000000e+00 5.202870e-03 232.40 -2.00 3.51 -2.00 315.95 0.00e+00 2.922176e-04 1.112384e-04 7.705482e-05 -6.000000e+00 2.320481e-04 289.81 -2.00 20.00 -2.00 315.18 0.00e+00 1.516 0.000 302.00 328.00 3 4.6943e+00 2.7544e-03 1.8566e-02 -6.0000e+00 1.3046e-02 2.0972e-02 3.0532e-03 1.0616e-02 -6.0000e+00 1.4043e-02 1.2448e-03 1.7588e-03 5.1342e-03 -6.0000e+00 8.3649e-03 -1.7958e-03 8.1878e-04 1.4117e-03 -6.0000e+00 3.6142e-03 8.4758e-04 8.3438e-05 5.7288e-05 1.7248e-05 -6.0000e+00 2.4130e-04 -1.1239e-02 1.8520e-04 12 1 1 12 1 1 99.67 22.22 0.17 -0.01124 -0.01061 13 14 1 5 0 918.040 26.83 20.00 22.22 33.46 23.4 1068.76 -1708 11 -1048 -2496 -683 -1593 1120 -931 1973 -2584 -574 -2560 1395 789 -742 -716 417 941 952 886 -168 1415 -208 1715 264 794 -93 146 638 827 825 1723 745 -2626 -1122 -1948 -97 -436 -379 -921 -704 -674 -1145 -32 -470 -247 -1055 -724 -1118 860 47 1130 399 709 1226 1006 -15 -154 562 699 1287 1621 1268 1070 -15 -247 -210 328 662 904 -19 399 82 428 -199 -707 -1031 -758 -615 -1056 -1499 -1716 -1712 -863 -716 -409 174 198 597 244 388 23 449 424 89 351 438 440 -137 -75 -1041 -581 31 -443 -625 -860 -332 -630 106 280 449 546 455 -74 270 362 -166 188 318 -190 51 276 278 766 361 -507 303 588 369 90 -135 10 55 -290 -88 44 351 -22 -190 -100 -271 -627 -385 2 -244 -554 -134 -307 227 -217 470 -655 -140 -660 385 240 -255 -262 154 357 361 346 -67 549 -84 716 117 358 -41 62 251 321 338 750 336 -1206 -490 -863 -45 -236 -236 -616 -503 -485 -843 -24 -343 -183 -764 -505 -785 598 34 855 310 571 1004 819 -13 -127 463 578 1074 1454 1195 1022 -15 -221 -178 274 587 852 -19 408 83 424 -188 -616 -839 -611 -514 -969 -1459 -1774 -1865 -956 -831 -495 215 250 743 297 453 25 456 437 96 395 532 557 -181 -96 -1297 -681 35 -538 -786 -1113 -446 -864 148 405 672 808 651 -101 348 455 -212 247 441 -274 73 396 386 1033 475 -652 379 729 479 122 -189 15 77 -421 -132 69 550 -34 -305 -156 -419 -957 SS 20230729T134626.6Z 8610.573919 217 1 41.60 2 47.14 102.89 166.58 356.13 0.00 1 0.00 1 0 17 7.463e-03 5.564e-03 2.658e-04 1.536e-04 1.948664e-01 8.038052e-05 2.355746e-03 -6.000000e+00 4.394666e-03 232.40 -2.00 3.51 -2.00 315.68 0.00e+00 3.111004e-04 8.001610e-06 5.870978e-05 -6.000000e+00 1.959974e-04 289.81 -2.00 20.00 -2.00 314.93 0.00e+00 1.468 0.000 302.00 328.00 3 9.1753e-01 2.0901e-04 1.7933e-02 -6.0000e+00 1.1020e-02 4.4797e-04 2.3112e-04 1.0213e-02 -6.0000e+00 1.1862e-02 -1.4372e-04 1.3291e-04 4.9408e-03 -6.0000e+00 7.0655e-03 1.6550e-04 6.1166e-05 1.3623e-03 -6.0000e+00 3.0528e-03 3.9753e-02 1.6337e-04 4.3516e-06 1.6586e-05 -6.0000e+00 2.0381e-04 -1.0942e-02 1.9860e-04 10 0 0 10 0 0 99.92 22.25 0.26 -0.01094 -0.00971 2379 671 1 5 0 16.920 26.83 20.00 22.25 33.59 23.4 1069.88 87 -498 -1305 -2617 -2033 -1032 204 1069 -131 -1400 -1360 -453 -269 567 200 -149 188 627 817 914 584 624 948 685 669 309 -141 -392 187 747 1231 1653 95 -1592 -1878 -1501 -1107 -187 -347 -744 -920 -713 -802 -457 -323 -536 -793 -892 -475 312 555 686 930 604 733 834 437 469 553 990 1078 1514 1399 795 -137 -198 -328 504 858 449 384 149 228 -33 -58 -383 -744 -684 -752 -986 -1233 -1642 -1673 -1083 -641 -335 -121 117 271 429 334 16 448 561 237 378 510 154 4 -359 -625 -643 -2 -533 -819 -699 -658 -390 108 371 274 381 143 123 94 337 226 222 259 -57 102 246 277 560 468 -6 527 559 351 233 -33 164 -88 -313 -151 39 279 64 -279 -190 -457 -529 23 -126 -358 -661 -458 -224 47 277 -37 -376 -390 -133 -81 191 75 -60 77 262 350 404 260 276 395 301 308 145 -65 -181 81 315 545 780 45 -746 -894 -716 -541 -107 -220 -501 -664 -531 -609 -346 -243 -401 -576 -626 -347 228 397 522 741 502 621 719 358 405 469 841 896 1350 1342 749 -133 -175 -285 431 750 443 384 154 232 -32 -56 -330 -620 -550 -646 -894 -1247 -1705 -1831 -1171 -741 -391 -149 147 335 532 381 17 446 586 250 438 617 193 6 -453 -773 -735 -3 -634 -1057 -898 -881 -542 149 539 394 568 202 168 117 422 287 282 356 -80 144 342 392 752 599 -8 642 694 466 311 -46 231 -127 -447 -229 58 429 101 -440 -291 -712 -797 SS 20230729T135124.2Z 8610.577364 221 1 42.90 2 46.22 103.90 166.61 0.62 0.00 1 0.00 1 0 17 7.457e-03 5.585e-03 2.887e-04 1.688e-04 1.922656e-01 8.825187e-05 2.321230e-03 -6.000000e+00 4.391044e-03 232.40 -2.00 3.51 -2.00 315.62 0.00e+00 2.823030e-04 8.714145e-06 6.019172e-05 -6.000000e+00 1.958414e-04 289.81 -2.00 20.00 -2.00 314.87 0.00e+00 1.443 0.000 302.00 328.00 3 1.1629e+00 2.2935e-04 1.7651e-02 -6.0000e+00 1.1010e-02 1.9383e-03 2.5383e-04 1.0072e-02 -6.0000e+00 1.1852e-02 2.2661e-04 1.4578e-04 4.8737e-03 -6.0000e+00 7.0597e-03 -4.9563e-05 6.6917e-05 1.3417e-03 -6.0000e+00 3.0502e-03 3.1993e-02 1.3956e-04 4.7749e-06 1.6635e-05 -6.0000e+00 2.0365e-04 -1.0793e-02 1.9796e-04 10 0 0 10 0 0 99.80 22.26 0.26 -0.01079 -0.00974 1911 539 1 5 0 21.740 26.83 20.00 22.26 33.90 23.5 1072.87 -24 -496 -1384 -2608 -1917 -1073 468 1058 27 -1428 -1247 -504 -177 638 206 -110 217 668 838 984 539 614 965 702 673 311 -81 -322 220 731 1314 1654 187 -1654 -1791 -1438 -1056 -192 -339 -745 -970 -726 -859 -454 -394 -536 -789 -850 -528 342 498 722 952 607 742 818 442 459 586 991 1099 1497 1382 760 -126 -183 -322 552 871 462 384 178 231 -20 -38 -329 -721 -698 -680 -1000 -1204 -1646 -1628 -1123 -633 -382 -144 98 231 411 314 29 479 578 247 410 515 165 -27 -343 -610 -614 38 -513 -823 -712 -668 -418 92 335 272 380 152 133 101 357 245 263 230 -60 90 229 286 568 456 7 541 570 351 224 -40 189 -67 -329 -158 22 273 47 -284 -198 -475 -504 -6 -131 -362 -683 -447 -242 112 284 8 -398 -370 -141 -55 221 80 -45 91 287 341 412 228 258 413 317 319 151 -38 -141 97 317 596 738 90 -794 -872 -701 -527 -112 -220 -513 -716 -552 -667 -351 -304 -409 -585 -608 -393 255 364 559 772 513 639 673 368 378 506 856 929 1357 1347 727 -117 -164 -284 478 772 435 389 186 238 -19 -37 -286 -609 -568 -591 -917 -1159 -1729 -1800 -1228 -740 -451 -178 124 289 489 362 32 482 574 263 453 628 209 -35 -436 -760 -707 43 -614 -1014 -922 -902 -556 128 491 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