File name: Pandora135s1_ManhattanNY-CCNY_20230805_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T160423.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230805_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230805 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230805T133751.7Z 8617.567960 328 1 40.63 2 49.76 103.10 81.44 262.59 0.00 1 0.00 1 0 17 8.214e-03 5.548e-03 2.690e-04 1.390e-04 2.194473e-01 7.104578e-05 2.618066e-03 -6.000000e+00 4.748104e-03 232.15 -2.00 3.51 -2.00 316.11 0.00e+00 3.231122e-04 7.848942e-06 6.555725e-05 -6.000000e+00 2.144644e-04 289.97 -2.00 20.00 -2.00 315.30 0.00e+00 1.545 0.000 302.00 328.00 3 6.2011e-01 1.8602e-04 1.9289e-02 -6.0000e+00 1.1891e-02 -5.9187e-04 2.0766e-04 1.1420e-02 -6.0000e+00 1.2879e-02 -2.2988e-04 1.1880e-04 5.5175e-03 -6.0000e+00 7.6774e-03 -3.5801e-04 5.4273e-05 1.4977e-03 -6.0000e+00 3.2301e-03 4.7546e-02 -3.2689e-04 3.9352e-06 1.7649e-05 -6.0000e+00 2.2380e-04 3.2761e-02 0.0000e+00 10 0 0 10 0 0 20.70 21.69 0.27 0.03276 0.03031 2822 796 1 5 0 13.830 26.32 20.00 21.69 29.89 23.3 1044.79 -563 -1099 -2051 -3499 -2675 -1804 73 677 -292 -2024 -1580 -820 -174 565 271 -189 195 626 780 1005 444 638 844 873 607 158 -332 -609 76 719 1375 1687 198 -1659 -1672 -1317 -763 79 -58 -569 -826 -648 -753 -363 -248 -385 -738 -704 -352 508 639 822 1004 627 785 823 477 427 661 1069 1234 1572 1435 737 -281 -209 -352 575 883 402 255 12 82 -106 -138 -274 -582 -464 -448 -874 -1084 -1685 -1746 -1234 -787 -551 -334 -136 13 260 272 52 580 799 337 385 444 86 -123 -380 -599 -529 195 -363 -760 -660 -629 -359 139 296 163 282 115 168 170 505 339 310 173 -146 -42 238 280 618 540 167 756 733 386 237 -20 207 -34 -258 -193 -25 279 37 -289 -122 -372 -358 -561 -121 -252 -470 -744 -506 -329 14 147 -70 -504 -385 -206 -44 163 88 -66 70 230 296 393 176 251 340 342 251 67 -138 -256 30 277 556 733 86 -728 -744 -584 -345 42 -34 -383 -560 -456 -541 -260 -177 -273 -512 -473 -246 356 441 604 776 507 608 650 383 340 549 886 998 1366 1348 685 -256 -185 -288 460 768 373 256 13 84 -105 -125 -238 -489 -375 -386 -797 -1041 -1776 -1838 -1358 -926 -657 -419 -166 16 314 319 55 594 805 364 433 524 112 -158 -476 -735 -631 224 -443 -956 -873 -826 -489 198 427 245 420 163 231 225 633 429 413 236 -203 -59 347 395 830 726 213 917 903 511 317 -28 293 -49 -372 -297 -39 436 59 -464 -191 -588 -546 -847 SS 20230805T134715.8Z 8617.574488 331 1 40.18 2 48.03 105.01 83.13 264.14 0.00 1 0.00 1 0 17 8.075e-03 5.565e-03 2.461e-04 1.336e-04 2.113304e-01 6.834230e-05 2.521560e-03 -6.000000e+00 4.667533e-03 232.15 -2.00 3.51 -2.00 315.97 0.00e+00 3.325669e-04 7.306454e-06 5.455300e-05 -6.000000e+00 2.108344e-04 289.97 -2.00 20.00 -2.00 315.17 0.00e+00 1.493 0.000 302.00 328.00 3 5.9511e-01 1.7858e-04 1.8611e-02 -6.0000e+00 1.1690e-02 -1.0093e-03 1.9933e-04 1.0992e-02 -6.0000e+00 1.2661e-02 6.1941e-04 1.1378e-04 5.3113e-03 -6.0000e+00 7.5472e-03 -6.4328e-04 5.1539e-05 1.4443e-03 -6.0000e+00 3.1752e-03 5.2066e-02 -3.1910e-04 3.7724e-06 1.7236e-05 -6.0000e+00 2.2001e-04 3.2995e-02 0.0000e+00 10 0 0 10 0 0 19.86 21.71 0.25 0.03299 0.03060 2967 837 1 5 0 13.020 26.32 20.00 21.71 31.12 23.2 1052.99 -535 -809 -2090 -3225 -2603 -1609 260 793 -120 -1937 -1444 -825 1 554 290 -213 214 665 810 992 412 759 1036 839 486 239 -387 -538 58 764 1391 1624 199 -1787 -1713 -1351 -752 98 -27 -617 -870 -649 -780 -346 -271 -417 -740 -709 -444 522 636 811 1023 655 783 846 477 437 682 1065 1281 1526 1421 707 -261 -229 -310 579 862 393 225 39 44 -81 -124 -252 -584 -436 -424 -853 -1070 -1690 -1742 -1219 -778 -559 -320 -124 53 269 285 78 598 789 338 410 428 94 -146 -371 -591 -479 182 -345 -751 -664 -612 -355 116 289 148 256 99 160 183 482 321 334 182 -126 -33 239 248 621 545 175 754 736 383 222 -29 221 -36 -281 -178 -25 274 26 -275 -108 -375 -356 -561 -124 -200 -519 -739 -532 -316 54 185 -31 -518 -377 -222 0 171 100 -79 81 259 326 411 160 315 406 346 211 107 -169 -220 24 308 588 737 90 -817 -732 -623 -353 54 -16 -403 -612 -472 -580 -257 -201 -306 -530 -491 -299 352 451 612 810 509 621 684 391 355 543 847 1059 1357 1283 671 -243 -206 -257 470 761 369 229 39 46 -81 -115 -222 -498 -356 -369 -786 -1037 -1798 -1850 -1353 -875 -671 -404 -152 65 328 337 84 617 799 366 462 506 122 -188 -466 -726 -571 209 -422 -946 -881 -805 -485 158 417 222 382 140 219 242 601 405 444 247 -174 -46 330 350 833 731 223 912 904 503 296 -41 311 -51 -403 -271 -38 424 42 -438 -168 -588 -539 -841 SS 20230805T135402.2Z 8617.579193 335 1 40.08 2 46.80 106.44 84.34 265.25 0.00 1 0.00 1 0 17 7.960e-03 5.586e-03 2.320e-04 1.287e-04 2.066933e-01 6.576719e-05 2.466731e-03 -6.000000e+00 4.601203e-03 232.15 -2.00 3.51 -2.00 315.86 0.00e+00 3.164893e-04 6.900539e-06 5.336815e-05 -6.000000e+00 2.078483e-04 289.97 -2.00 20.00 -2.00 315.06 0.00e+00 1.458 0.000 302.00 328.00 3 5.6545e-01 1.7179e-04 1.8191e-02 -6.0000e+00 1.1523e-02 -1.0839e-04 1.9184e-04 1.0755e-02 -6.0000e+00 1.2481e-02 4.4857e-04 1.0941e-04 5.1978e-03 -6.0000e+00 7.4400e-03 -4.2425e-04 4.9352e-05 1.4106e-03 -6.0000e+00 3.1299e-03 5.5929e-02 -3.6465e-04 3.6288e-06 1.7259e-05 -6.0000e+00 2.1690e-04 3.3252e-02 0.0000e+00 10 0 0 10 0 0 44.91 21.72 0.26 0.03325 0.03051 3042 858 1 5 0 12.630 26.32 20.00 21.72 31.56 23.3 1054.81 -387 -873 -2024 -3264 -2337 -1559 404 875 -43 -1831 -1413 -564 9 643 325 -141 212 690 877 1029 442 767 232 826 571 167 -414 -507 168 788 1345 1730 210 -1758 -1731 -1280 -761 101 -45 -625 -852 -699 -791 -376 -287 -414 -749 -750 -386 474 649 813 1038 647 807 841 473 463 700 1069 1244 1509 1412 703 -285 -210 -326 595 867 403 219 4 61 -147 -153 -246 -562 -383 -430 -848 -1130 -1704 -1714 -1196 -820 -544 -366 -132 0 255 252 82 603 792 328 374 456 79 -126 -365 -553 -467 216 -340 -779 -668 -605 -364 116 291 128 255 117 155 192 501 313 304 149 -139 -41 222 264 637 574 172 782 736 392 237 -33 244 -21 -300 -192 -27 253 24 -296 -111 -365 -358 -560 -95 -209 -486 -789 -502 -323 88 215 -12 -471 -387 -145 2 207 117 -54 84 280 338 409 178 305 95 354 258 77 -188 -214 72 329 587 746 98 -827 -762 -560 -367 57 -28 -419 -615 -522 -604 -286 -217 -311 -550 -532 -266 326 470 627 839 512 652 693 395 384 568 867 1049 1367 1298 679 -269 -192 -274 490 776 384 226 4 61 -149 -143 -220 -455 -317 -355 -789 -1107 -1729 -1837 -1340 -930 -659 -443 -163 0 314 285 89 627 808 339 425 542 98 -164 -460 -683 -560 251 -397 -988 -847 -801 -500 159 420 185 381 167 213 253 625 395 404 203 -193 -58 308 373 856 733 220 947 905 516 316 -46 343 -31 -429 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