File name: Pandora135s1_ManhattanNY-CCNY_20230814_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T161422.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230814_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230814 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230814T132919.9Z 8626.562036 229 1 46.08 2 52.77 104.22 32.84 109.29 0.00 1 0.00 1 0 17 1.570e-02 7.564e-03 6.009e-03 2.551e-03 2.168812e-01 1.294952e-03 2.532884e-03 -6.000000e+00 9.062803e-03 231.83 -2.00 3.51 -2.00 316.71 0.00e+00 5.451270e-04 1.635436e-04 8.343127e-05 -6.000000e+00 4.104188e-04 290.17 -2.00 20.00 -2.00 315.84 0.00e+00 1.649 0.000 302.00 328.00 3 6.0969e+00 3.4159e-03 1.9959e-02 -6.0000e+00 2.2677e-02 4.6296e-02 3.8341e-03 1.1204e-02 -6.0000e+00 2.4570e-02 2.8085e-03 2.2212e-03 5.3927e-03 -6.0000e+00 1.4652e-02 -4.0010e-03 1.0425e-03 1.4835e-03 -6.0000e+00 6.1667e-03 1.7751e-04 -1.3770e-04 7.3149e-05 1.6255e-05 -6.0000e+00 4.2790e-04 3.6017e-02 0.0000e+00 11 8 0 10 0 0 99.97 22.01 0.00 0.03602 0.03498 16 5 1 5 0 2879.420 26.62 20.00 22.01 32.09 23.5 1057.24 1998 -1604 400 -5799 521 -9903 2101 -3516 20 -3431 -2571 305 -789 5593 -3948 2103 1060 260 -115 891 357 1563 1038 1099 76 515 813 -520 1605 -17 2067 -639 1466 -2608 -3440 -297 -2120 1445 -264 -1180 -944 -335 -1404 -1323 -276 131 56 -965 92 381 1356 444 1593 561 2067 960 423 229 302 653 1707 2182 938 1127 -567 -748 -1114 -400 -26 763 422 206 287 649 620 -1207 -783 -1983 -979 -1314 -1474 -1678 -1882 -510 -801 -337 318 584 446 835 263 64 -132 155 -760 -228 752 699 77 -463 -317 -853 -333 -792 -949 -509 -434 70 203 780 308 603 -110 31 18 116 -364 88 320 -147 604 726 285 850 428 -1913 242 356 313 121 -230 271 -313 -306 -174 59 575 782 -276 450 -165 -789 -863 317 -280 68 -950 75 -1534 312 -622 4 -650 -491 59 -167 1262 -1096 587 308 79 -36 285 116 497 340 378 28 191 293 -177 501 -6 673 -230 550 -1009 -1255 -105 -850 663 -142 -704 -602 -220 -951 -897 -185 86 36 -607 58 241 869 306 1140 409 1517 726 325 174 233 504 1316 1805 821 1025 -508 -630 -899 -317 -22 691 413 202 286 617 561 -995 -601 -1485 -775 -1137 -1381 -1717 -1975 -555 -911 -409 391 732 556 1014 304 69 -130 156 -797 -254 895 911 103 -614 -389 -997 -377 -952 -1201 -674 -583 98 297 1169 470 934 -163 43 24 150 -475 117 444 -218 904 1066 407 1184 568 -2464 299 448 421 169 -325 387 -458 -467 -273 97 937 1297 -463 748 -266 -1235 -1375 SS 20230814T133851.6Z 8626.568653 232 1 8.00 2 51.03 106.15 31.20 111.83 0.00 1 0.00 1 0 17 8.792e-03 5.807e-03 3.003e-03 1.599e-03 2.047228e-01 8.169594e-04 2.436720e-03 -6.000000e+00 5.073280e-03 231.83 -2.00 3.51 -2.00 316.01 0.00e+00 3.842211e-04 8.807818e-05 5.098333e-05 -6.000000e+00 2.298073e-04 290.17 -2.00 20.00 -2.00 315.19 0.00e+00 1.587 0.000 302.00 328.00 3 3.7911e+00 2.1354e-03 1.9120e-02 -6.0000e+00 1.2694e-02 1.5486e-02 2.3840e-03 1.0644e-02 -6.0000e+00 1.3755e-02 1.4310e-03 1.3648e-03 5.1369e-03 -6.0000e+00 8.2025e-03 -2.3994e-03 6.2059e-04 1.4043e-03 -6.0000e+00 3.4515e-03 1.9658e-03 -1.7060e-04 4.5363e-05 1.6660e-05 -6.0000e+00 2.3960e-04 3.7528e-02 0.0000e+00 12 1 1 12 1 1 99.89 22.02 0.29 0.03753 0.03625 21 37 1 5 0 355.710 26.62 19.99 22.02 32.29 23.5 1057.95 -490 -74 -3370 -2603 -1697 -886 946 398 733 -3213 -497 -1788 999 492 -18 74 629 368 404 1425 -1 721 24 1305 475 788 -497 115 -77 724 1909 1320 746 -2598 -1263 -2317 -520 -328 -40 -724 -979 -745 -1090 -463 -264 345 -913 -789 -862 553 580 1036 1133 881 923 958 402 252 526 495 1395 1547 1439 490 -296 -312 -129 557 906 318 66 301 169 334 -225 -255 -629 -685 -548 -1207 -1436 -1572 -1408 -1054 -464 -773 -224 -79 138 443 395 162 282 535 291 432 494 337 -7 -349 -403 -1020 100 -322 -650 -733 -770 -342 354 346 172 316 41 42 149 185 218 163 114 -74 -122 471 157 810 468 48 604 562 293 389 -16 65 73 -461 -39 -13 350 95 -116 -33 -336 -459 -648 -109 -17 -805 -561 -339 -171 194 92 178 -824 -122 -460 279 151 -6 27 226 137 155 557 -1 284 10 550 212 358 -222 47 -31 286 785 565 341 -1212 -544 -1011 -248 -179 -24 -485 -683 -537 -804 -340 -193 248 -665 -555 -592 378 418 768 881 693 742 784 334 208 425 402 1171 1357 1322 473 -278 -274 -108 456 785 303 66 310 172 326 -209 -225 -519 -545 -464 -1091 -1409 -1636 -1502 -1149 -540 -918 -278 -98 173 542 455 174 292 544 308 491 589 430 -9 -449 -494 -1190 116 -386 -825 -955 -1022 -470 496 502 253 463 58 57 191 231 275 212 157 -105 -173 668 216 1083 611 61 748 709 386 531 -22 92 102 -678 -59 -20 542 151 -184 -53 -515 -695 -974 SS 20230814T134716.9Z 8626.574501 235 1 39.36 2 49.51 107.91 29.77 114.23 0.00 1 0.00 1 0 17 8.043e-03 5.603e-03 2.613e-04 1.440e-04 1.976873e-01 7.352409e-05 2.349654e-03 -6.000000e+00 4.640769e-03 231.83 -2.00 3.51 -2.00 315.90 0.00e+00 3.653920e-04 7.714569e-06 5.622050e-05 -6.000000e+00 2.102168e-04 290.17 -2.00 20.00 -2.00 315.08 0.00e+00 1.537 0.000 302.00 328.00 3 6.8336e-01 1.9199e-04 1.8490e-02 -6.0000e+00 1.1612e-02 -3.1979e-03 2.1448e-04 1.0254e-02 -6.0000e+00 1.2583e-02 -1.4023e-04 1.2239e-04 4.9471e-03 -6.0000e+00 7.5032e-03 -5.7455e-04 5.5223e-05 1.3485e-03 -6.0000e+00 3.1572e-03 4.7176e-02 -1.1272e-04 4.0932e-06 1.6331e-05 -6.0000e+00 2.1918e-04 3.7557e-02 0.0000e+00 10 0 0 10 0 0 99.97 22.02 0.25 0.03756 0.03671 3209 905 1 5 0 11.830 26.62 20.00 22.02 32.52 23.6 1062.80 -252 -662 -1926 -3206 -2341 -1618 405 837 -44 -1862 -1573 -797 -9 608 342 -139 196 725 748 1100 467 726 810 831 570 208 -420 -575 16 679 1390 1619 320 -1787 -1845 -1514 -865 39 -67 -550 -837 -588 -729 -341 -243 -372 -734 -698 -429 466 598 853 1042 680 821 851 497 453 643 980 1237 1526 1483 771 -270 -312 -463 493 867 472 348 176 161 -51 -130 -358 -741 -657 -585 -945 -1163 -1703 -1738 -1216 -733 -481 -231 -3 153 354 292 1 459 629 254 379 454 141 -64 -334 -629 -629 50 -461 -759 -693 -616 -404 145 351 280 341 170 136 98 342 222 233 180 -75 50 268 308 658 564 141 660 611 358 207 -33 185 -69 -335 -208 -1 294 69 -209 -57 -340 -367 -613 -60 -168 -487 -746 -485 -324 86 199 -12 -503 -415 -216 -3 188 118 -51 74 280 297 449 193 297 339 366 264 99 -194 -248 6 267 571 712 151 -850 -822 -674 -426 21 -43 -370 -605 -439 -556 -259 -184 -279 -537 -493 -294 319 432 653 781 531 654 691 409 370 515 786 1032 1368 1342 730 -249 -279 -383 399 764 440 350 183 165 -51 -118 -313 -630 -537 -476 -867 -1116 -1787 -1811 -1326 -855 -565 -286 -4 191 421 337 1 465 627 272 419 554 179 -84 -427 -747 -731 57 -553 -936 -898 -833 -537 202 515 404 489 243 189 125 437 287 300 250 -106 71 377 420 899 733 174 820 773 458 281 -47 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