File name: Pandora135s1_ManhattanNY-CCNY_20230822_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20230823T053415.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230822_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230822 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230822T131609.6Z 8634.552888 159 1 14.13 2 56.56 104.36 122.10 82.52 0.00 1 0.00 1 0 17 9.262e-03 5.699e-03 1.391e-03 6.401e-04 2.337307e-01 3.330801e-04 2.834908e-03 -6.000000e+00 5.442244e-03 231.24 -2.00 3.51 -2.00 316.37 0.00e+00 2.984261e-04 3.832309e-05 9.973218e-05 -6.000000e+00 2.429984e-04 289.70 -2.00 20.00 -2.00 315.57 0.00e+00 1.809 0.000 302.00 328.00 3 2.3026e+00 8.7120e-04 2.1858e-02 -6.0000e+00 1.3609e-02 8.9965e-04 9.6704e-04 1.2252e-02 -6.0000e+00 1.4650e-02 -4.6376e-04 5.6344e-04 5.9449e-03 -6.0000e+00 8.7348e-03 1.7296e-04 2.6927e-04 1.6433e-03 -6.0000e+00 3.7945e-03 6.6492e-03 -1.5631e-04 1.8191e-05 1.9445e-05 -6.0000e+00 2.5253e-04 -2.9623e-02 1.5604e-04 12 1 1 12 1 1 96.94 21.20 0.22 -0.02962 -0.03080 138 128 1 5 0 100.410 25.90 20.00 21.20 24.78 23.2 1005.83 -961 -1393 -1615 -3072 -2399 -2435 -198 88 -350 -2163 -1953 -1237 62 827 9 -162 238 242 818 960 220 580 4674 495 501 149 -309 -632 -228 320 686 1269 188 -1746 -1944 -1965 -1310 -170 -294 -843 -867 -613 -837 -387 -250 -227 -598 -665 -451 421 667 893 1031 761 1001 1079 549 509 571 1000 1221 1573 1519 1019 -209 -170 -443 380 880 378 279 244 103 14 -9 -295 -655 -730 -663 -1052 -1149 -1649 -1827 -1073 -815 -527 -330 -27 109 224 153 -292 215 472 265 387 606 301 64 -329 -529 -543 98 -375 -765 -633 -548 -374 268 438 323 451 331 200 86 464 336 155 109 -129 -40 184 233 559 454 -7 512 617 302 236 -71 116 -191 -313 -194 -46 263 137 -309 -129 -498 -384 -172 -269 -313 -557 -387 -380 -32 16 -71 -463 -411 -268 15 206 3 -50 75 79 275 333 78 203 1608 187 200 61 -125 -241 -81 112 252 502 81 -765 -800 -803 -586 -82 -158 -523 -582 -399 -558 -258 -166 -161 -415 -449 -297 277 463 617 751 581 783 861 447 411 452 789 999 1296 1355 960 -195 -146 -374 314 736 359 271 245 103 13 -9 -250 -538 -576 -555 -934 -1143 -1699 -2000 -1156 -939 -615 -406 -34 136 267 178 -328 220 472 283 431 747 388 82 -435 -653 -651 112 -454 -956 -834 -754 -509 381 630 486 679 476 279 116 590 430 209 151 -191 -60 272 334 762 621 -10 666 770 405 322 -102 168 -283 -462 -304 -71 422 224 -509 -206 -810 -600 SS 20230822T132016.3Z 8634.555744 162 1 43.00 2 55.81 105.17 121.37 83.24 0.00 1 0.00 1 0 17 8.048e-03 5.382e-03 4.642e-04 2.097e-04 2.288532e-01 1.092420e-04 2.770484e-03 -6.000000e+00 4.728763e-03 231.24 -2.00 3.51 -2.00 316.44 0.00e+00 3.425512e-04 1.285252e-05 7.836233e-05 -6.000000e+00 2.111385e-04 289.70 -2.00 20.00 -2.00 315.63 0.00e+00 1.774 0.000 302.00 328.00 3 1.1749e+00 2.8577e-04 2.1422e-02 -6.0000e+00 1.1825e-02 1.9990e-03 3.1737e-04 1.1987e-02 -6.0000e+00 1.2729e-02 8.1950e-04 1.8522e-04 5.8213e-03 -6.0000e+00 7.5896e-03 -2.5846e-04 8.8601e-05 1.6209e-03 -6.0000e+00 3.2971e-03 2.1406e-02 -1.3019e-05 5.9634e-06 1.8871e-05 -6.0000e+00 2.1941e-04 -2.9392e-02 1.6943e-04 10 0 0 10 0 0 99.64 21.20 0.26 -0.02939 -0.02949 1742 491 1 5 0 24.110 25.90 19.99 21.20 24.92 23.3 1007.31 -549 -1089 -1866 -3270 -2506 -2052 -178 425 -249 -1969 -1819 -905 -506 331 192 -261 116 599 681 992 412 639 652 767 571 250 -250 -511 69 626 1138 1569 442 -1588 -1730 -1347 -991 -166 -224 -676 -910 -585 -716 -329 -181 -291 -653 -669 -391 447 658 785 1030 644 807 872 523 453 636 951 1163 1478 1427 852 -165 -115 -393 478 822 393 248 42 93 -73 -65 -238 -548 -502 -418 -860 -1055 -1596 -1730 -1259 -814 -551 -349 -142 21 283 265 59 546 829 414 445 548 148 -36 -345 -560 -554 132 -280 -798 -700 -676 -424 109 344 209 311 140 171 131 499 320 320 194 -125 -88 163 224 539 517 54 601 719 415 240 -29 220 -58 -252 -201 -41 250 41 -342 -168 -500 -464 -97 -207 -357 -583 -398 -313 -29 77 -50 -412 -374 -191 -119 88 53 -78 36 189 222 334 141 217 226 281 221 100 -98 -188 24 210 402 596 182 -667 -682 -525 -425 -84 -125 -402 -586 -391 -489 -225 -124 -197 -433 -432 -246 281 436 555 766 502 644 664 404 348 513 765 906 1237 1293 764 -156 -99 -314 400 694 376 242 43 93 -70 -62 -203 -456 -400 -353 -767 -989 -1647 -1895 -1357 -937 -678 -427 -178 26 335 307 65 556 825 441 493 672 190 -49 -453 -684 -658 150 -337 -988 -914 -923 -601 153 513 309 461 209 234 174 626 404 425 278 -181 -130 237 316 764 696 69 773 936 548 339 -41 313 -84 -382 -307 -66 411 69 -578 -276 -794 -747 SS 20230822T132451.8Z 8634.558933 165 1 42.55 2 54.97 106.08 120.55 84.04 0.00 1 0.00 1 0 17 8.003e-03 5.452e-03 3.640e-04 1.777e-04 2.243706e-01 9.255336e-05 2.723124e-03 -6.000000e+00 4.702652e-03 231.24 -2.00 3.51 -2.00 316.20 0.00e+00 3.191933e-04 1.023858e-05 6.873208e-05 -6.000000e+00 2.099630e-04 289.70 -2.00 20.00 -2.00 315.40 0.00e+00 1.737 0.000 302.00 328.00 3 9.2263e-01 2.4151e-04 2.0989e-02 -6.0000e+00 1.1760e-02 1.5832e-03 2.6785e-04 1.1756e-02 -6.0000e+00 1.2659e-02 1.0595e-04 1.5553e-04 5.7081e-03 -6.0000e+00 7.5476e-03 4.5182e-04 7.3773e-05 1.5866e-03 -6.0000e+00 3.2790e-03 2.8793e-02 3.5287e-05 5.0449e-06 1.8799e-05 -6.0000e+00 2.1818e-04 -2.9527e-02 1.8108e-04 10 0 0 10 0 0 99.81 21.20 0.25 -0.02953 -0.02926 1908 538 1 5 0 21.780 25.90 20.00 21.20 25.10 23.3 1008.43 -747 -811 -1934 -3006 -2726 -1876 -259 598 -255 -1854 -1634 -971 -279 317 320 -301 314 644 918 979 545 712 324 836 544 381 -249 -458 29 666 1200 1672 390 -1548 -1740 -1403 -1023 -199 -208 -706 -892 -617 -676 -356 -196 -369 -655 -631 -412 485 625 797 999 684 767 871 503 472 642 969 1185 1478 1423 828 -182 -134 -318 489 875 368 215 82 101 -50 -145 -221 -580 -465 -478 -839 -1044 -1587 -1744 -1253 -814 -608 -393 -130 37 234 253 2 538 779 368 407 524 170 -64 -313 -540 -520 152 -277 -781 -657 -669 -427 99 322 209 290 137 172 160 510 355 317 207 -118 -96 172 248 551 500 82 631 738 415 267 -33 224 -59 -262 -177 -58 241 27 -340 -244 -482 -506 -146 -170 -410 -592 -480 -316 -46 119 -56 -427 -370 -225 -72 85 96 -98 105 222 327 359 203 263 123 333 229 165 -106 -183 11 243 458 686 173 -702 -741 -591 -473 -100 -116 -452 -618 -414 -464 -244 -134 -251 -468 -437 -278 327 443 563 742 533 612 709 416 387 517 778 986 1239 1290 792 -172 -116 -271 406 737 351 209 83 102 -48 -138 -189 -479 -367 -400 -744 -1039 -1634 -1905 -1351 -938 -709 -482 -163 47 279 294 3 546 773 391 449 641 218 -86 -411 -660 -617 173 -332 -969 -859 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