File name: Pandora135s1_ManhattanNY-CCNY_20230822_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T161400.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230822_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230822 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230822T131609.6Z 8634.552888 159 1 14.13 2 56.56 104.36 122.10 82.52 0.00 1 0.00 1 0 17 9.558e-03 5.756e-03 1.387e-03 6.367e-04 2.325893e-01 3.241183e-04 2.778172e-03 -6.000000e+00 5.512465e-03 231.24 -2.00 3.51 -2.00 316.43 0.00e+00 3.275375e-04 3.815962e-05 9.616323e-05 -6.000000e+00 2.491769e-04 289.70 -2.00 20.00 -2.00 315.59 0.00e+00 1.809 0.000 302.00 328.00 3 2.3440e+00 8.5061e-04 2.1763e-02 -6.0000e+00 1.3777e-02 -1.9118e-03 9.5152e-04 1.2102e-02 -6.0000e+00 1.4926e-02 1.5907e-03 5.4967e-04 5.8478e-03 -6.0000e+00 8.9033e-03 -1.1732e-03 2.5622e-04 1.5898e-03 -6.0000e+00 3.7578e-03 6.4444e-03 -3.4270e-04 1.8105e-05 1.8739e-05 -6.0000e+00 2.6024e-04 2.3849e-02 0.0000e+00 12 1 1 12 1 1 96.94 21.20 0.22 0.02385 0.02127 138 128 1 5 0 100.410 25.90 20.00 21.20 24.78 23.2 1005.83 -902 -1508 -1843 -3425 -2699 -2493 -121 209 -334 -2267 -2079 -1199 168 960 86 -193 193 200 790 921 155 533 4690 527 489 97 -445 -794 -333 319 765 1341 201 -1852 -2062 -1926 -1159 30 -125 -752 -840 -606 -842 -399 -247 -230 -612 -677 -452 451 730 937 1067 773 1000 1070 525 482 559 1025 1292 1665 1597 1057 -240 -237 -491 378 931 417 294 233 81 -13 -46 -330 -675 -723 -624 -1016 -1128 -1645 -1838 -1079 -812 -526 -327 -26 110 221 149 -300 203 461 249 364 576 265 21 -372 -565 -566 88 -380 -764 -629 -542 -367 264 423 305 437 320 192 73 440 295 109 69 -144 -24 226 286 623 520 68 574 634 297 235 -63 132 -189 -323 -204 -30 294 183 -230 -17 -367 -242 -611 -161 -290 -355 -617 -433 -387 -20 38 -68 -483 -435 -258 40 237 24 -59 60 65 264 318 55 186 1605 199 194 40 -180 -301 -118 111 280 528 86 -807 -844 -783 -516 15 -67 -464 -561 -420 -559 -265 -163 -162 -422 -454 -296 296 504 645 774 588 778 850 425 387 441 805 1052 1365 1417 991 -223 -201 -413 310 774 394 283 233 80 -12 -43 -279 -552 -568 -520 -897 -1116 -1687 -2001 -1157 -931 -611 -400 -33 136 263 172 -335 206 458 265 403 707 340 26 -490 -694 -675 101 -458 -950 -824 -742 -497 374 605 456 654 458 266 98 557 376 147 94 -211 -36 331 407 845 707 88 743 788 396 318 -89 190 -278 -475 -317 -47 468 298 -377 -27 -594 -377 -941 SS 20230822T132016.3Z 8634.555744 162 1 43.00 2 55.81 105.17 121.37 83.24 0.00 1 0.00 1 0 17 8.407e-03 5.427e-03 4.626e-04 2.085e-04 2.277857e-01 1.062802e-04 2.713794e-03 -6.000000e+00 4.848638e-03 231.24 -2.00 3.51 -2.00 316.52 0.00e+00 3.789235e-04 1.283392e-05 7.635969e-05 -6.000000e+00 2.191727e-04 289.70 -2.00 20.00 -2.00 315.67 0.00e+00 1.774 0.000 302.00 328.00 3 1.2161e+00 2.7895e-04 2.1328e-02 -6.0000e+00 1.2118e-02 -6.3131e-04 3.1228e-04 1.1838e-02 -6.0000e+00 1.3128e-02 2.7378e-03 1.8064e-04 5.7238e-03 -6.0000e+00 7.8311e-03 -1.4872e-03 8.4188e-05 1.5671e-03 -6.0000e+00 3.3053e-03 2.0744e-02 -2.3422e-04 5.9399e-06 1.8162e-05 -6.0000e+00 2.2890e-04 2.3912e-02 0.0000e+00 10 0 0 10 0 0 99.64 21.20 0.26 0.02391 0.02215 1742 491 1 5 0 24.110 25.90 19.99 21.20 24.92 23.3 1007.31 -489 -1177 -2104 -3644 -2794 -2126 -76 538 -249 -2108 -1972 -881 -379 459 271 -280 67 572 647 967 341 585 656 787 556 179 -398 -687 -40 626 1209 1637 462 -1704 -1848 -1314 -830 46 -49 -582 -886 -588 -725 -345 -182 -299 -672 -693 -401 479 720 832 1063 656 799 861 496 416 614 973 1234 1571 1504 880 -207 -184 -441 480 878 436 260 31 67 -104 -106 -278 -573 -494 -376 -820 -1030 -1591 -1739 -1262 -810 -547 -347 -142 20 278 258 49 534 818 399 425 520 115 -74 -382 -590 -572 123 -287 -798 -695 -669 -418 103 329 192 300 134 169 124 477 281 274 153 -140 -72 204 277 603 582 129 661 732 404 234 -24 234 -60 -268 -216 -32 275 82 -270 -63 -376 -329 -536 -86 -222 -400 -647 -441 -323 -12 97 -50 -438 -403 -185 -88 121 74 -83 21 180 210 324 116 197 227 286 214 71 -155 -251 -14 209 425 619 189 -712 -725 -510 -354 23 -27 -344 -567 -390 -493 -235 -123 -202 -444 -445 -250 299 474 585 787 509 635 652 382 318 493 778 956 1307 1355 785 -194 -158 -351 400 738 415 252 31 67 -99 -101 -237 -474 -392 -316 -728 -961 -1634 -1894 -1353 -927 -669 -422 -177 25 328 297 54 541 810 423 468 634 146 -99 -498 -716 -677 139 -343 -984 -903 -908 -590 144 488 283 443 199 230 164 594 353 362 218 -202 -106 295 387 850 780 164 846 949 531 329 -33 331 -86 -406 -329 -51 449 136 -454 -103 -594 -527 -849 SS 20230822T132451.8Z 8634.558933 165 1 42.55 2 54.97 106.08 120.55 84.04 0.00 1 0.00 1 0 17 8.348e-03 5.500e-03 3.628e-04 1.769e-04 2.234074e-01 9.021705e-05 2.672856e-03 -6.000000e+00 4.814983e-03 231.24 -2.00 3.51 -2.00 316.27 0.00e+00 3.533525e-04 1.022443e-05 6.794956e-05 -6.000000e+00 2.176433e-04 289.70 -2.00 20.00 -2.00 315.44 0.00e+00 1.737 0.000 302.00 328.00 3 9.6358e-01 2.3607e-04 2.0904e-02 -6.0000e+00 1.2033e-02 -8.0635e-04 2.6382e-04 1.1623e-02 -6.0000e+00 1.3037e-02 1.8287e-03 1.5198e-04 5.6219e-03 -6.0000e+00 7.7767e-03 -6.5927e-04 7.0286e-05 1.5382e-03 -6.0000e+00 3.2824e-03 2.7898e-02 -2.2922e-04 5.0331e-06 1.8183e-05 -6.0000e+00 2.2730e-04 2.3700e-02 0.0000e+00 10 0 0 10 0 0 99.81 21.20 0.25 0.02370 0.02198 1908 538 1 5 0 21.780 25.90 20.00 21.20 25.10 23.3 1008.43 -664 -885 -2165 -3380 -3011 -1938 -138 728 -243 -1978 -1789 -938 -139 465 409 -312 272 628 895 959 476 657 336 864 536 314 -397 -635 -86 668 1276 1743 416 -1668 -1857 -1365 -854 22 -24 -609 -865 -618 -687 -374 -201 -381 -679 -658 -426 517 686 845 1033 699 760 861 476 434 618 988 1250 1567 1496 854 -227 -207 -368 492 934 411 227 70 75 -83 -190 -265 -607 -458 -437 -801 -1021 -1581 -1752 -1256 -810 -603 -389 -130 36 230 248 -7 526 767 353 385 496 139 -99 -346 -564 -533 144 -286 -786 -655 -665 -425 91 306 193 283 137 177 160 493 318 271 164 -134 -81 213 300 616 566 158 692 746 399 257 -30 237 -63 -283 -198 -53 263 64 -271 -141 -362 -377 -537 -129 -185 -456 -663 -527 -325 -24 144 -53 -454 -403 -217 -36 124 123 -101 90 215 317 350 177 242 127 342 224 135 -168 -252 -32 242 485 712 184 -753 -787 -572 -393 11 -13 -388 -597 -413 -470 -256 -137 -258 -482 -454 -286 347 484 594 764 542 604 697 392 354 495 789 1036 1307 1350 814 -214 -178 -312 407 782 391 220 71 75 -80 -180 -225 -499 -361 -364 -707 -1011 -1620 -1905 -1349 -929 -701 -476 -163 44 273 286 -8 532 758 372 423 605 177 -132 -451 -686 -629 163 -342 -970 -851 -904 -570 128 434 286 418 204 243 211 613 399 358 222 -194 -119 308 421 867 757 202 881 962 523 360 -41 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