File name: Pandora135s1_ManhattanNY-CCNY_20230823_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T161324.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230823_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230823 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230823T140406.1Z 8635.586182 187 1 46.84 2 48.21 114.94 124.92 87.42 0.00 1 0.00 1 0 17 2.406e-02 9.376e-03 1.350e-02 5.274e-03 1.985049e-01 2.662828e-03 2.321784e-03 -6.000000e+00 1.387050e-02 231.15 -2.00 3.51 -2.00 317.04 0.00e+00 4.510236e-04 3.614630e-04 8.401742e-05 -6.000000e+00 6.271383e-04 289.62 -2.00 20.00 -2.00 316.16 0.00e+00 1.498 0.000 302.00 328.00 3 5.7958e+00 7.0583e-03 1.8158e-02 -6.0000e+00 3.4658e-02 2.9071e-02 7.9400e-03 1.0231e-02 -6.0000e+00 3.7555e-02 2.0762e-02 4.6269e-03 4.9379e-03 -6.0000e+00 2.2402e-02 -1.1263e-02 2.2021e-03 1.3629e-03 -6.0000e+00 9.4536e-03 2.8783e-04 -1.6224e-05 1.5338e-04 1.4848e-05 -6.0000e+00 6.5521e-04 2.5499e-02 0.0000e+00 12 9 8 11 8 0 99.99 21.45 0.26 0.02550 0.02538 27 8 2 5 0 1734.250 26.11 20.00 21.45 29.30 23.6 1037.44 6284 -9040 -1414 -6407 9745 -12506 -4577 -1464 2611 -3747 -3630 -3613 2091 5873 -5372 2898 1051 1771 -2536 1302 -2481 1178 -100 2735 -101 -111 1568 1450 4539 -2187 1614 -2854 4210 -3467 -2101 -813 1346 3674 -20 999 -1426 -167 -2125 -2033 -12 -169 398 -2381 1006 2132 687 1992 1656 -216 2035 2960 -1155 -89 -1068 920 2358 2216 588 1327 -1165 -325 -167 -759 -232 900 50 -839 573 156 1664 -908 874 -2400 151 -1058 -1622 -894 -2274 -948 -1013 -699 602 530 -175 114 222 -340 -253 87 -301 -957 555 1883 391 -923 -285 -731 693 -1172 -598 -480 -1279 341 -104 436 247 625 -263 102 458 -395 -287 -242 823 236 609 415 164 392 361 787 345 126 176 582 -867 342 -254 -566 -480 286 426 1005 -978 796 44 -1065 -877 889 -1586 -228 -995 1197 -1789 -649 -227 425 -664 -630 -646 392 1204 -1376 731 278 478 -737 376 -751 341 -30 836 -33 -38 509 439 1293 -654 488 -968 1415 -1251 -699 -266 475 1498 -10 548 -861 -103 -1367 -1310 -8 -105 241 -1429 567 1194 411 1251 1097 -151 1428 2096 -861 -65 -775 655 1721 1742 506 1182 -1033 -260 -122 -571 -182 784 47 -830 555 145 1416 -736 628 -1704 110 -879 -1454 -867 -2361 -1019 -1168 -831 743 671 -221 138 256 -355 -250 84 -309 -1047 660 2421 532 -1237 -352 -836 786 -1374 -755 -638 -1788 487 -151 666 393 985 -398 147 597 -510 -373 -318 1155 355 932 627 241 549 479 1023 429 159 236 794 -1247 493 -374 -873 -784 485 740 1771 -1700 1376 74 -1745 -1415 SS 20230823T140838.8Z 8635.589338 190 1 46.43 2 47.44 116.02 124.11 88.18 0.00 1 0.00 1 0 17 8.376e-03 5.594e-03 2.899e-03 1.438e-03 1.949496e-01 7.310718e-04 2.320202e-03 -6.000000e+00 4.828129e-03 231.15 -2.00 3.51 -2.00 316.24 0.00e+00 3.051018e-04 8.275122e-05 7.571526e-05 -6.000000e+00 2.183323e-04 289.62 -2.00 20.00 -2.00 315.41 0.00e+00 1.476 0.000 302.00 328.00 3 5.2451e+00 1.9137e-03 1.7898e-02 -6.0000e+00 1.2064e-02 3.3588e-02 2.1412e-03 1.0094e-02 -6.0000e+00 1.3073e-02 3.3425e-03 1.2298e-03 4.8848e-03 -6.0000e+00 7.7981e-03 -3.3122e-03 5.6618e-04 1.3343e-03 -6.0000e+00 3.2903e-03 5.1661e-04 -2.0046e-04 4.1032e-05 1.5698e-05 -6.0000e+00 2.2811e-04 2.6403e-02 0.0000e+00 10 0 0 10 0 0 99.94 21.46 0.17 0.02640 0.02490 72 20 1 5 0 644.770 26.11 20.00 21.46 29.40 23.6 1038.38 505 -1197 -1570 -3311 -587 -3650 911 196 -270 -1727 -966 -88 49 1731 -666 -1 25 524 736 931 494 759 742 77 718 -106 -331 -704 773 143 1512 1262 673 -1837 -2233 -985 -1035 323 -373 -476 -777 -628 -905 -588 -464 -524 -334 -1203 -108 350 510 684 1235 625 856 1145 262 497 654 1197 1210 1824 1218 879 -465 17 -303 191 678 554 314 64 293 -170 128 -640 -598 -725 -529 -835 -1164 -1379 -1948 -984 -560 -488 -208 173 3 415 171 77 191 581 369 79 495 -70 79 -383 -495 -599 202 -367 -731 -637 -685 -371 186 514 104 393 97 57 236 201 169 78 228 -49 120 336 486 477 718 -657 595 587 245 239 -167 383 3 -345 -347 93 395 224 -266 3 -258 -456 -601 101 -258 -336 -688 -106 -657 168 41 -62 -394 -223 -21 12 479 -210 0 9 184 265 345 186 282 281 31 300 -46 -139 -277 279 51 556 498 283 -788 -898 -389 -451 157 -218 -305 -537 -449 -662 -429 -337 -377 -232 -816 -70 228 348 496 935 477 665 903 210 395 529 965 976 1572 1096 827 -430 15 -252 155 570 507 311 66 298 -167 120 -542 -474 -549 -422 -722 -1125 -1403 -2105 -1067 -649 -585 -262 222 4 505 199 84 196 580 378 89 593 -89 105 -496 -617 -689 231 -430 -932 -827 -927 -520 263 768 156 589 142 80 311 251 211 103 314 -70 174 479 693 650 957 -842 741 739 317 319 -233 537 5 -500 -532 144 627 363 -435 5 -410 -700 -912 SS 20230823T141350.0Z 8635.592940 193 1 46.41 2 46.56 117.28 123.18 89.03 0.00 1 0.00 1 0 17 7.549e-03 5.571e-03 9.325e-04 5.566e-04 1.889532e-01 2.846934e-04 2.265150e-03 -6.000000e+00 4.351117e-03 231.15 -2.00 3.51 -2.00 315.59 0.00e+00 2.801870e-04 2.819442e-05 4.335416e-05 -6.000000e+00 1.967721e-04 289.62 -2.00 20.00 -2.00 314.83 0.00e+00 1.452 0.000 302.00 328.00 3 3.6864e+00 7.3887e-04 1.7528e-02 -6.0000e+00 1.0872e-02 1.7629e-02 8.2336e-04 9.8013e-03 -6.0000e+00 1.1781e-02 1.8940e-03 4.6969e-04 4.7419e-03 -6.0000e+00 7.0277e-03 -1.2030e-03 2.1030e-04 1.2941e-03 -6.0000e+00 2.9651e-03 2.5616e-03 -2.0547e-04 1.5764e-05 1.6181e-05 -6.0000e+00 2.0558e-04 2.6704e-02 0.0000e+00 10 0 0 10 0 0 99.94 21.47 0.21 0.02670 0.02516 161 45 1 5 0 288.220 26.11 20.00 21.47 29.60 23.6 1040.06 -287 -618 -1819 -2613 -2172 -1263 365 1327 164 -1405 -1123 -586 214 732 172 -131 313 513 728 737 500 306 816 673 452 113 -402 -393 201 751 1293 2000 521 -1672 -1894 -1255 -932 195 -34 -738 -923 -821 -729 -588 -293 -436 -673 -800 -325 319 605 958 878 707 751 921 448 533 609 990 1192 1367 1415 783 -289 -310 -329 353 930 413 253 25 93 -58 8 -150 -522 -360 -313 -708 -1139 -1579 -1720 -1205 -930 -635 -353 -188 22 224 291 -55 543 683 340 353 446 167 -70 -327 -496 -440 134 -250 -710 -622 -671 -363 49 306 145 282 131 173 163 414 303 212 155 -118 12 188 298 675 577 140 658 741 369 278 -47 255 -120 -258 -217 16 227 142 -241 -119 -362 -435 -581 -78 -178 -524 -693 -512 -285 87 352 48 -427 -332 -177 65 249 66 -53 130 218 318 332 227 138 373 324 211 54 -189 -186 88 320 573 941 264 -859 -910 -596 -487 110 -21 -528 -662 -610 -552 -445 -221 -325 -523 -600 -235 230 457 766 689 578 627 781 386 454 510 827 1033 1271 1325 769 -278 -290 -282 294 836 394 261 25 93 -59 7 -136 -427 -301 -257 -654 -1104 -1674 -1815 -1328 -1096 -755 -442 -240 29 271 343 -59 557 684 363 389 542 211 -93 -420 -592 -512 150 -297 -870 -801 -903 -480 67 445 209 402 187 227 206 522 385 268 212 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