File name: Pandora135s1_ManhattanNY-CCNY_20230910_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T164930.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20230910_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20230910 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230910T132411.2Z 8653.558463 292 1 46.89 2 58.78 113.04 16.13 162.48 0.00 1 0.00 1 0 17 5.393e-02 2.511e-02 3.566e-03 1.381e-03 2.340855e-01 6.954729e-04 2.876969e-03 -6.000000e+00 3.088518e-02 229.66 -2.00 3.51 -2.00 316.90 0.00e+00 7.649612e-04 9.332385e-05 2.516695e-04 -6.000000e+00 1.398107e-03 288.25 -2.00 20.00 -2.00 316.06 0.00e+00 1.922 0.000 302.00 328.00 3 4.8362e+00 1.8336e-03 2.2751e-02 -6.0000e+00 7.6921e-02 1.2761e-02 2.0628e-03 1.2289e-02 -6.0000e+00 8.3505e-02 -1.8566e-02 1.2041e-03 5.9671e-03 -6.0000e+00 4.9830e-02 1.0164e-02 5.7589e-04 1.6442e-03 -6.0000e+00 2.1033e-02 4.7749e-04 -1.3725e-04 3.9584e-05 1.9289e-05 -6.0000e+00 1.4687e-03 3.4664e-02 0.0000e+00 12 8 8 10 0 0 99.11 21.79 0.13 0.03466 0.03363 41 12 1 5 0 1143.450 26.41 20.00 21.79 30.73 23.9 1045.20 9138 9373 5061 5011 6974 3746 6972 5920 7038 2577 5281 3607 6707 6937 5419 4911 6720 5111 5618 5263 4638 4518 -54602 4909 3620 3854 2569 2201 2505 2670 3627 4307 3060 -47 -7 -54 1403 2187 1858 1025 915 598 430 767 1190 1079 477 263 428 1644 1117 1553 1390 1170 1231 1276 457 467 531 857 1697 1842 1918 1148 -126 -542 -384 -187 648 275 125 -16 83 -108 -397 -670 -1262 -1108 -1120 -1238 -1465 -1837 -2072 -1568 -737 -710 -206 -14 376 391 340 -236 60 363 70 122 352 228 -87 -330 -788 -904 -120 -624 -748 -437 -626 -209 221 622 352 467 155 -6 46 50 176 5 350 -36 259 789 563 796 528 -377 546 759 471 264 -27 141 69 -250 -154 -109 463 71 -308 -46 -226 -658 -742 1272 1384 773 726 890 481 935 904 1158 436 888 645 1260 1489 1327 1298 1802 1442 1572 1525 1363 1319 -27527 1541 1209 1313 864 693 768 813 1164 1486 1100 -17 -2 -19 531 974 956 585 544 370 273 486 750 676 293 163 259 996 697 1032 975 831 895 946 346 349 390 629 1290 1465 1648 1009 -109 -443 -300 -145 528 246 121 -15 79 -102 -358 -559 -962 -842 -883 -1071 -1377 -1840 -2199 -1694 -825 -851 -252 -17 464 473 389 -252 61 362 73 137 424 295 -114 -433 -990 -1075 -138 -759 -962 -574 -839 -291 316 916 543 716 232 -8 61 66 232 6 497 -53 386 1152 819 1104 717 -503 690 976 634 371 -40 211 102 -389 -248 -179 777 118 -518 -77 -365 -1052 -1175 SS 20230910T132926.4Z 8653.562112 295 1 46.90 2 57.87 114.15 15.88 166.60 0.00 1 0.00 1 0 17 9.939e-03 5.531e-03 3.237e-03 1.248e-03 2.302401e-01 6.300917e-04 2.733934e-03 -6.000000e+00 5.692027e-03 229.66 -2.00 3.51 -2.00 316.90 0.00e+00 5.550212e-04 8.326372e-05 1.022792e-04 -6.000000e+00 2.576386e-04 288.25 -2.00 20.00 -2.00 316.06 0.00e+00 1.874 0.000 302.00 328.00 3 4.6443e+00 1.6611e-03 2.2136e-02 -6.0000e+00 1.4176e-02 6.6088e-03 1.8666e-03 1.1884e-02 -6.0000e+00 1.5389e-02 6.0978e-03 1.0915e-03 5.7689e-03 -6.0000e+00 9.1833e-03 -4.2476e-03 5.2247e-04 1.6076e-03 -6.0000e+00 3.8765e-03 6.0850e-04 -1.6747e-04 3.5871e-05 1.8035e-05 -6.0000e+00 2.7065e-04 3.4085e-02 0.0000e+00 11 1 0 11 8 0 99.82 21.80 0.27 0.03408 0.03283 70 20 1 5 0 669.710 26.41 20.00 21.80 30.96 24.0 1047.28 383 -1532 -2460 -4156 -2054 -4433 -574 -163 -1051 -2958 -2253 -1424 -625 676 -729 -365 380 392 230 589 912 778 1855 1052 768 -4 -173 -1031 578 -169 1259 1443 280 -2145 -2541 -1548 -872 275 129 -768 -775 -584 -624 -524 63 -230 -388 -601 -495 402 641 750 1115 763 950 1091 545 411 351 738 1379 1778 1455 903 -109 -520 -323 240 785 274 489 137 336 -34 -35 -433 -888 -918 -765 -1067 -1072 -1706 -1694 -1040 -731 -384 -150 77 338 503 372 -26 334 509 98 201 616 -62 146 -271 -508 -724 -162 -595 -787 -654 -708 -271 114 549 309 573 197 -67 -90 60 153 64 292 -11 161 371 554 504 444 -588 480 633 260 209 -46 177 -218 -210 -119 130 319 237 -151 -97 -297 -489 -554 54 -235 -378 -594 -259 -558 -75 -24 -171 -501 -374 -245 -120 147 -180 -97 103 110 67 177 276 234 567 342 264 -1 -60 -336 175 -51 399 494 103 -807 -900 -544 -339 125 64 -441 -479 -374 -409 -344 41 -149 -246 -372 -300 244 411 514 802 531 675 791 402 301 252 530 1028 1426 1265 826 -97 -428 -246 180 641 254 453 131 318 -33 -31 -352 -712 -712 -585 -923 -1037 -1684 -1767 -1134 -853 -447 -182 96 417 591 432 -28 347 522 100 227 718 -80 195 -354 -616 -867 -187 -730 -978 -855 -968 -385 159 811 478 880 288 -96 -119 75 194 86 420 -16 235 531 819 712 596 -757 626 840 347 296 -68 267 -337 -317 -191 218 546 390 -249 -166 -490 -781 -876 SS 20230910T171517.5Z 8653.718953 428 1 46.81 2 36.33 189.48 45.24 265.58 0.00 1 0.00 1 0 17 8.198e-03 6.085e-03 1.111e-03 7.598e-04 1.544066e-01 3.891222e-04 1.850651e-03 -6.000000e+00 4.698497e-03 229.64 -2.00 3.51 -2.00 314.99 0.00e+00 3.501314e-04 3.408902e-05 3.173099e-05 -6.000000e+00 2.124313e-04 288.24 -2.00 20.00 -2.00 314.30 0.00e+00 1.240 0.000 302.00 328.00 3 4.5880e+00 1.0014e-03 1.4694e-02 -6.0000e+00 1.1702e-02 1.0573e-02 1.1135e-03 7.9267e-03 -6.0000e+00 1.2699e-02 1.0741e-03 6.3655e-04 3.8480e-03 -6.0000e+00 7.5784e-03 -1.3049e-03 2.7941e-04 1.0686e-03 -6.0000e+00 3.2028e-03 1.3809e-03 -1.8810e-04 2.1429e-05 1.3606e-05 -6.0000e+00 2.2316e-04 2.7221e-02 0.0000e+00 12 1 1 12 1 1 99.57 21.42 0.12 0.02722 0.02581 69 20 1 5 0 668.630 26.11 20.00 21.42 26.47 23.7 1016.60 79 -705 -1385 -3070 -990 -1973 770 1064 534 -1650 -1060 -943 -306 939 -302 238 -15 709 488 1104 73 758 3273 1005 632 97 -322 -660 255 469 1436 1348 737 -1793 -1523 -1424 -1119 -117 -291 -430 -928 -711 -932 -369 -653 -168 -823 -873 -511 364 499 738 861 524 967 747 635 494 637 840 1023 1519 1431 965 -194 -242 -707 444 691 512 242 183 164 18 63 -252 -694 -801 -458 -1160 -1190 -1571 -1781 -1208 -765 -573 -93 14 317 361 206 -79 164 563 67 340 340 496 59 -312 -401 -742 3 -415 -692 -702 -537 -563 59 431 312 426 132 204 -61 311 64 160 285 190 166 410 408 763 538 -186 623 456 337 141 74 187 -158 -475 -230 78 270 195 -208 64 -320 -438 -811 27 -250 -487 -1032 -301 -582 236 351 193 -597 -383 -346 -118 400 -139 115 -7 342 242 558 38 383 1636 537 354 54 -181 -344 126 225 706 703 394 -972 -792 -734 -613 -72 -202 -329 -741 -586 -782 -309 -544 -138 -656 -687 -386 280 389 608 720 456 852 652 560 432 562 742 912 1407 1384 972 -191 -227 -625 379 618 502 250 191 170 19 61 -233 -596 -672 -390 -1081 -1166 -1635 -1908 -1350 -891 -681 -116 18 392 437 240 -86 169 561 71 373 401 608 75 -389 -476 -858 3 -480 -850 -888 -707 -752 79 599 449 607 182 271 -75 371 77 198 371 258 226 565 546 993 682 -230 744 549 420 182 97 246 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