File name: Pandora135s1_ManhattanNY-CCNY_20231009_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T172914.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20231009_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20231009 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231009T124144.2Z 8682.528984 256 1 24.83 2 72.51 115.08 22.41 159.20 0.00 1 0.00 1 0 25 2.467e-01 3.536e-02 8.522e-02 5.114e-03 4.425491e-01 2.583221e-03 5.622888e-03 -6.000000e+00 1.401228e-01 226.62 -2.00 3.51 -2.00 319.58 0.00e+00 7.043164e-03 7.536468e-04 2.184416e-03 -6.000000e+00 6.307385e-03 284.96 -2.00 20.00 -2.00 318.86 0.00e+00 3.280 0.001 302.00 328.00 3 4.7068e+00 7.3874e-03 4.0448e-02 -6.0000e+00 3.4694e-01 1.6234e-01 8.7110e-03 2.4062e-02 -6.0000e+00 3.7720e-01 -2.1547e-01 6.5267e-03 1.3431e-02 -6.0000e+00 2.2521e-01 1.0649e-01 3.4131e-03 5.3262e-03 -6.0000e+00 9.5787e-02 1.0229e-04 -1.4739e-03 1.4573e-04 6.9284e-05 -6.0000e+00 6.7036e-03 8.4298e-03 0.0000e+00 12 9 9 12 1 1 99.92 20.21 0.62 0.00843 -0.00265 10 6 1 5 0 2256.710 24.96 19.99 20.21 15.56 23.0 940.01 56653 32033 40247 31264 117083 -38189 84613 40403 47724 7521 29117 41418 55047 82803 14959 53122 55067 46243 25564 49317 29620 34726 -118573 29557 24260 15246 22168 17092 27832 7236 27704 20686 33277 17605 16481 24922 13681 20717 10703 17335 11416 7788 8746 9259 13186 13618 12410 11683 13864 11502 9221 6797 9833 7663 5541 5250 1243 227 -281 1098 6649 6644 4438 4506 917 2521 782 313 1150 320 -858 -379 -378 -1154 -1222 -1744 -589 -484 -1272 -2376 -2067 -3117 -4037 -3204 -1259 -2733 -1410 -1236 -1207 -221 -429 -247 -1493 -1094 -2568 -1378 -643 510 -422 -894 -704 -1328 -218 -318 -1135 -1156 -513 -248 186 636 498 421 241 393 316 456 6 564 553 374 403 1497 1532 1450 788 1429 1587 166 970 342 923 660 -11 506 -551 -389 -341 -147 111 112 -847 -886 -1911 1031 839 1004 803 1139 -1569 1097 887 1047 253 791 1074 1496 2106 860 2503 2760 2698 1839 3037 2131 2442 -35209 2270 2039 1433 1929 1504 2144 713 2508 2300 3634 2216 2084 2821 1869 3079 1998 3499 2678 2001 2314 2489 3448 3596 3330 3171 3717 3264 2879 2369 3563 3002 2292 2122 529 96 -123 470 2799 3059 2221 2460 530 1363 407 164 647 206 -585 -267 -263 -806 -786 -1012 -310 -262 -721 -1578 -1503 -2560 -3607 -2988 -1177 -2768 -1486 -1339 -1304 -228 -430 -228 -1299 -947 -2460 -1417 -746 632 -567 -1199 -879 -1571 -238 -356 -1379 -1489 -662 -338 271 967 819 715 401 618 480 656 9 851 856 611 662 2373 2344 2224 1161 1998 2206 230 1459 548 1576 1176 -20 940 -1060 -784 -702 -307 231 227 -1697 -1683 -3564 SS 20231009T125101.8Z 8682.535438 262 1 46.61 2 70.93 116.85 21.90 164.75 0.00 1 0.00 1 0 25 5.019e-02 5.965e-03 2.327e-02 1.958e-03 4.224291e-01 9.848380e-04 4.960858e-03 -6.000000e+00 2.851733e-02 226.62 -2.00 3.51 -2.00 319.29 0.00e+00 1.054232e-03 2.602548e-04 3.179147e-04 -6.000000e+00 1.283465e-03 284.96 -2.00 20.00 -2.00 318.55 0.00e+00 3.024 0.000 302.00 328.00 3 3.9454e+00 2.7669e-03 3.7170e-02 -6.0000e+00 7.0608e-02 3.5877e-02 3.2455e-03 2.1801e-02 -6.0000e+00 7.6756e-02 2.3577e-03 2.4537e-03 1.0834e-02 -6.0000e+00 4.5826e-02 -5.9079e-03 1.2933e-03 3.1800e-03 -6.0000e+00 1.9502e-02 2.9595e-04 -5.1564e-04 5.6052e-05 3.4350e-05 -6.0000e+00 1.3636e-03 5.0879e-03 0.0000e+00 10 0 0 10 0 0 99.91 20.22 0.22 0.00509 0.00121 72 20 1 5 0 647.200 24.96 20.00 20.22 15.73 23.1 941.67 -17020 1831 -20612 326 -2334 -30029 -23031 -239 -8150 -14180 -1106 -10568 328 1751 -4466 -3027 4844 -3721 2184 -3314 38 -1805 -26117 -2293 -2288 1251 -1699 497 -899 -1392 -2623 -990 3330 -2641 -3096 -1509 -84 -616 1696 192 -550 -1137 -1149 -1315 181 -172 -117 -742 1059 1876 214 2157 1454 1610 1210 1182 -24 470 237 414 2239 2328 1691 1110 671 75 351 -22 900 66 135 433 -204 417 -490 474 -289 -513 -510 -431 -1199 -1268 -1781 -1504 -451 -627 -381 -358 412 556 761 297 474 619 310 232 192 646 -44 -432 -730 -550 -118 -566 -1196 -714 -939 -280 322 304 36 328 289 73 359 233 405 58 197 -375 -223 333 288 556 183 -839 514 1008 338 346 31 325 -94 -380 -62 -127 261 203 -426 -67 -103 -325 -116 -418 42 -616 8 -51 -837 -647 -6 -254 -498 -35 -398 13 84 -270 -206 330 -296 174 -292 3 -161 -2928 -229 -234 136 -190 52 -92 -147 -312 -126 452 -395 -445 -222 -13 -112 366 49 -151 -332 -349 -406 56 -56 -38 -243 344 627 75 812 594 700 551 556 -12 227 112 194 1063 1203 933 670 413 44 195 -12 543 45 99 327 -154 298 -340 292 -172 -300 -308 -301 -923 -1092 -1660 -1415 -448 -668 -411 -397 451 607 770 289 430 560 306 248 223 835 -59 -575 -944 -643 -133 -662 -1463 -919 -1271 -382 468 464 59 534 477 113 535 330 571 86 299 -605 -362 525 438 844 266 -1176 705 1406 500 541 51 565 -164 -694 -115 -250 525 416 -878 -134 -195 -607 -210 SS 20231009T130142.5Z 8682.542853 265 1 46.96 2 69.15 118.94 21.52 171.35 0.00 1 0.00 1 0 25 1.580e-01 3.026e-02 3.751e-02 3.830e-03 3.809175e-01 1.918800e-03 4.681002e-03 -6.000000e+00 8.979942e-02 226.62 -2.00 3.51 -2.00 319.12 0.00e+00 4.577578e-03 4.812947e-04 1.189704e-03 -6.000000e+00 4.041413e-03 284.96 -2.00 20.00 -2.00 318.36 0.00e+00 2.782 0.000 302.00 328.00 3 5.2662e+00 5.3525e-03 3.4121e-02 -6.0000e+00 2.2234e-01 1.1043e-01 6.2190e-03 1.9875e-02 -6.0000e+00 2.4169e-01 -1.1641e-01 4.3890e-03 1.0618e-02 -6.0000e+00 1.4430e-01 5.8985e-02 2.3037e-03 4.1586e-03 -6.0000e+00 6.1415e-02 1.0294e-04 -7.3217e-04 1.1071e-04 4.7442e-05 -6.0000e+00 4.2935e-03 4.5007e-03 0.0000e+00 12 9 8 11 8 0 99.86 20.23 -0.01 0.00450 -0.00100 32 9 1 5 0 1467.140 24.96 20.00 20.23 15.95 23.0 942.48 32158 49566 25132 41809 69673 -89 17284 28462 34029 9853 27447 19438 29201 31703 12929 32513 30136 23687 21478 28528 21593 21582 -99613 13372 13573 13570 16100 17350 12131 6974 10938 9612 18750 6998 10736 10803 10596 9832 10498 5697 5686 4243 2689 3565 5957 7279 6525 6252 7573 7042 4105 5171 5124 3001 3787 3590 136 -127 61 244 4219 3977 2282 2403 1333 529 945 -467 -270 199 -834 250 -968 -333 -1239 550 -1070 -2122 -1500 -1974 -1770 -2630 -2872 -1769 -1642 -2107 -524 -691 -41 271 -447 -784 -1309 -110 -1128 -962 -654 642 -183 -404 -501 -423 -591 -527 -810 -859 -482 115 291 453 655 726 462 -256 382 -79 -12 98 500 -158 675 1101 1535 1473 620 -1160 925 813 850 218 320 555 418 -89 -531 -246 508 202 -624 -162 -361 -1060 -884 1008 1454 969 1283 1503 -4 599 976 1203 459 1073 876 1402 1793 1007 2349 2391 2120 2063 2645 2172 2140 -31382 1519 1612 1657 1901 1933 1370 847 1410 1415 2779 1201 1679 1650 1758 1926 2446 1558 1703 1359 906 1210 1989 2420 2177 2081 2487 2385 1530 2069 2190 1384 1789 1737 69 -64 30 119 2053 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