File name: Pandora135s1_ManhattanNY-CCNY_20231024_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20231025T184514.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20231024_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20231024 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231024T122205.2Z 8697.515338 113 1 46.57 2 79.29 115.94 152.34 335.64 0.00 1 0.00 1 0 25 3.391e-01 8.153e-03 2.594e-01 4.807e-03 5.991595e-01 2.608971e-03 6.946586e-03 -6.000000e+00 1.955384e-01 225.17 -2.00 3.51 -2.00 320.94 0.00e+00 2.747782e-03 1.152767e-03 7.768700e-04 -6.000000e+00 8.815398e-03 283.13 -2.00 20.00 -2.00 320.40 0.00e+00 5.178 0.002 302.00 328.00 3 2.9252e+00 8.4865e-03 6.0301e-02 -6.0000e+00 4.8282e-01 5.7877e-02 1.1425e-02 3.2401e-02 -6.0000e+00 5.2213e-01 -4.7923e-02 1.1531e-02 1.7809e-02 -6.0000e+00 3.1131e-01 1.3673e-02 5.6414e-03 6.5515e-03 -6.0000e+00 1.3669e-01 8.8250e-05 -1.0277e-03 1.3790e-04 7.1145e-05 -6.0000e+00 9.2966e-03 -5.2060e-02 1.3789e-04 11 9 0 11 8 0 99.94 20.30 0.27 -0.05206 -0.05978 74 21 1 5 0 629.250 25.07 20.00 20.30 17.99 23.4 958.30 -5424 -111966 -46678 -132183 900000 -198614 24064 -68686 111494 -70099 33655 -32683 -83749 156968 -77598 69031 -42293 75811 -22738 -6204 6404 6000 -33218 -29008 -8344 -20995 14772 -13515 8704 -43481 -10390 -8007 29460 -3416 -9477 469 -7502 19176 2091 6469 -3830 -1141 -2998 -290 13090 9552 1380 -550 6859 885 3826 2910 5549 2410 6193 6067 -1216 413 -1031 1353 3461 4255 -1216 3438 -1248 974 -508 1541 -1004 -153 11 368 522 -662 662 -832 -1497 -547 142 -1587 -836 50 -2009 -416 -947 -417 -282 274 -335 1764 -500 664 -36 394 -19 -509 78 1074 112 -299 -165 -965 -152 -610 -1025 -576 -1217 572 -179 740 -359 227 -162 290 318 -38 262 -339 517 -264 298 771 695 597 415 -2346 97 746 98 161 -17 272 -490 -258 -503 -22 318 532 -297 129 2 -317 -25 -1024 -240 -1563 900000 -3977 113 -490 522 -626 158 -241 -1289 736 -1735 469 -944 604 -502 -123 116 110 -941 -861 -220 -665 333 -395 202 -1824 -369 -332 973 -168 -480 21 -407 954 145 514 -381 -119 -337 -33 1310 1015 163 -68 825 121 562 483 987 459 1260 1235 -274 91 -237 299 776 1044 -343 1036 -414 309 -159 487 -360 -63 5 173 243 -295 267 -306 -517 -189 54 -727 -445 30 -1291 -279 -683 -320 -228 227 -278 1383 -375 458 -25 278 -14 -447 78 1170 133 -360 -186 -1025 -148 -601 -1091 -649 -1452 686 -236 1080 -562 372 -266 455 487 -56 386 -527 846 -437 489 1265 1100 915 613 -3420 133 1053 157 277 -33 541 -1027 -552 -1152 -53 779 1321 -743 311 4 -706 SS 20231024T133433.7Z 8697.565668 163 1 3.89 2 67.81 130.07 153.40 12.65 0.00 1 0.00 1 0 17 2.582e-02 6.397e-03 2.025e-02 4.641e-03 3.204369e-01 2.357126e-03 3.918987e-03 -6.000000e+00 1.485080e-02 225.16 -2.00 3.51 -2.00 317.83 0.00e+00 4.197411e-04 3.964051e-04 1.847502e-04 -6.000000e+00 6.590476e-04 283.12 -2.00 20.00 -2.00 317.13 0.00e+00 2.625 0.000 302.00 328.00 3 3.7312e+00 6.2360e-03 3.0838e-02 -6.0000e+00 3.6695e-02 4.0211e-02 7.0325e-03 1.6539e-02 -6.0000e+00 3.9692e-02 -8.9170e-03 4.5050e-03 8.2109e-03 -6.0000e+00 2.3684e-02 1.1895e-03 2.3552e-03 2.3643e-03 -6.0000e+00 1.0386e-02 6.2416e-04 -1.3186e-03 1.3186e-04 2.5774e-05 -6.0000e+00 7.0214e-04 -4.9093e-02 -2.2890e-05 12 1 1 12 9 1 -153.64 20.40 0.12 -0.04909 -0.05900 4 17 1 5 0 777.030 25.17 20.01 20.40 18.68 23.4 962.19 -10179 -6242 -15222 3223 -4239 -12766 -2348 -2615 -1006 -7817 2128 -7946 4470 -2305 1440 -583 4662 1304 -1447 1814 -1666 4279 -3595 2470 -570 177 -1642 -1139 2621 1941 470 2542 2471 -2134 -946 -1073 -381 -1609 1108 -2175 -626 -696 67 329 -824 567 -853 -1179 -1210 1475 192 1996 811 -329 1505 1064 491 70 -39 559 2247 542 2458 398 128 -66 -415 808 351 1147 284 -136 147 -40 -450 410 -578 -122 -372 -1014 -1177 -1405 -1379 -1503 -778 -490 -241 -201 -404 20 453 196 936 572 -43 754 364 828 -465 23 -365 -483 -27 -208 -887 -555 -940 -530 240 179 56 627 -57 -124 -370 925 11 654 -247 369 -238 512 104 492 698 -314 814 747 369 -89 -86 -105 -322 -278 -143 196 345 379 -500 -53 -494 -406 -780 -507 -1387 230 -294 -926 -164 -208 -88 -767 190 -822 466 -302 203 -93 750 228 -272 343 -333 802 -748 515 -131 42 -393 -257 538 400 106 621 639 -594 -255 -284 -109 -534 419 -959 -299 -340 33 165 -420 285 -430 -587 -616 744 101 1119 476 -206 961 701 322 46 -26 364 1487 383 1817 314 102 -51 -304 576 264 946 252 -126 135 -35 -381 317 -421 -88 -276 -838 -1046 -1352 -1387 -1592 -854 -560 -284 -244 -490 24 511 207 927 572 -46 852 440 1059 -628 32 -474 -587 -32 -251 -1116 -737 -1282 -739 344 270 88 1000 -89 -188 -529 1258 15 931 -364 562 -371 778 157 728 981 -434 1083 1004 525 -132 -132 -167 -522 -462 -247 347 615 687 -920 -95 -865 -694 SS 20231024T134232.2Z 8697.571206 166 1 5.35 2 66.67 131.79 153.01 16.63 0.00 1 0.00 1 0 25 1.305e-02 5.304e-03 2.538e-03 6.745e-04 3.035241e-01 3.424735e-04 3.708097e-03 -6.000000e+00 7.514338e-03 225.16 -2.00 3.51 -2.00 317.52 0.00e+00 4.702536e-04 5.280334e-05 1.339420e-04 -6.000000e+00 3.334044e-04 283.12 -2.00 20.00 -2.00 316.82 0.00e+00 2.506 0.000 302.00 328.00 3 6.2836e-01 9.0136e-04 2.9344e-02 -6.0000e+00 1.8567e-02 8.0187e-03 1.0123e-03 1.5603e-02 -6.0000e+00 2.0077e-02 -8.2083e-03 6.3096e-04 7.7526e-03 -6.0000e+00 1.1980e-02 1.7883e-03 3.2596e-04 2.2538e-03 -6.0000e+00 5.2582e-03 1.6269e-02 -3.4985e-04 1.9102e-05 2.4222e-05 -6.0000e+00 3.5476e-04 -5.1322e-02 1.4323e-04 12 1 1 12 1 1 49.28 20.41 0.21 -0.05132 -0.05395 192 489 1 5 0 26.970 25.17 20.00 20.41 18.76 23.5 964.49 -2591 -3178 -3596 -5390 -5062 -5858 -3591 -1577 -1404 -3810 -3846 -2927 -1225 -147 -914 -182 -511 380 569 744 398 317 239 679 254 150 -717 -799 -436 17 673 1560 708 -1569 -1506 -1697 -1175 -110 -58 -537 -1028 -431 -819 -132 -61 83 -405 -237 -253 453 840 812 1201 836 1003 1018 592 330 656 703 1164 1390 1373 1009 27 111 -224 576 908 658 321 42 57 -140 -259 -276 -465 -538 -389 -806 -979 -1524 -1776 -1329 -804 -669 -585 -241 -17 320 401 208 652 969 455 530 527 158 -147 -424 -597 -623 -7 -83 -827 -768 -741 -443 14 342 192 278 113 248 43 586 343 426 179 -129 -236 173 157 392 525 28 619 824 444 252 17 260 -41 -212 -209 -126 197 50 -381 -153 -470 -344 -220 -299 -347 -499 -420 -470 -299 -146 -145 -423 -428 -336 -157 -22 -158 -35 -103 79 124 168 92 73 56 169 68 42 -200 -211 -108 4 176 444 203 -474 -431 -520 -357 -39 -25 -248 -525 -230 -452 -73 -34 46 -222 -128 -135 243 477 499 727 536 664 692 411 229 445 473 806 1035 1045 825 22 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