File name: Pandora135s1_ManhattanNY-CCNY_20231118_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20231119T045259.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20231118_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20231118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231118T162657.0Z 8722.685382 199 1 46.62 2 60.18 176.19 97.16 117.20 0.00 1 0.00 1 0 17 3.704e-02 8.155e-03 5.838e-03 1.739e-03 2.606853e-01 8.762116e-04 3.188770e-03 -6.000000e+00 2.118261e-02 223.20 -2.00 3.51 -2.00 317.40 0.00e+00 2.411667e-04 1.298965e-04 9.381771e-05 -6.000000e+00 9.341820e-04 280.08 -2.00 20.00 -2.00 316.76 0.00e+00 2.002 0.000 302.00 328.00 3 4.8397e+00 2.2903e-03 2.3857e-02 -6.0000e+00 5.2168e-02 3.9413e-02 2.5706e-03 1.3229e-02 -6.0000e+00 5.6495e-02 1.0425e-02 1.5914e-03 6.6280e-03 -6.0000e+00 3.3699e-02 -7.4318e-03 8.1607e-04 1.9443e-03 -6.0000e+00 1.4829e-02 4.1027e-04 -6.1684e-05 4.9863e-05 2.1438e-05 -6.0000e+00 1.0054e-03 -5.7657e-02 2.2190e-04 11 8 0 10 0 0 99.99 20.21 0.10 -0.05766 -0.05812 100 28 1 5 0 466.120 24.96 20.00 20.21 15.07 23.4 940.44 -2460 319 -3946 -4796 453 -7302 910 -1568 1664 -5471 125 -4020 557 -7 -3358 -691 -715 8 -1550 1151 -1982 529 40156 600 -269 51 -825 -922 -188 -1049 1658 -198 1919 -2681 -1866 -1794 -1080 -543 -341 -892 -1111 -710 -1438 -571 -750 247 -1075 -812 -746 530 246 444 974 503 1235 1345 869 -206 1105 357 1537 1297 1438 1150 -156 -103 -442 232 458 560 -68 501 62 305 116 330 -527 -911 -16 -1002 -936 -1443 -1679 -1155 -647 -701 -352 -188 107 648 273 213 243 743 296 563 295 449 259 -85 -502 -571 -13 -462 -781 -808 -731 -459 111 526 381 283 -96 64 -96 247 140 156 120 -13 -183 401 76 510 666 -820 373 694 363 205 89 293 -102 -80 -429 -84 500 411 -352 -50 -419 -572 -249 35 -455 -524 44 -722 87 -174 200 -712 16 -526 78 -1 -642 -141 -153 2 -362 271 -490 127 6838 154 -74 14 -235 -249 -47 -259 420 -56 572 -859 -560 -523 -338 -198 -144 -440 -582 -389 -814 -323 -425 138 -599 -455 -410 289 141 264 611 333 837 931 615 -147 761 246 1075 976 1136 970 -134 -81 -335 170 357 476 -62 471 59 276 101 268 -389 -640 -11 -826 -840 -1388 -1730 -1241 -716 -831 -426 -235 134 797 312 229 247 726 306 620 351 573 352 -114 -656 -682 -15 -554 -986 -1083 -991 -649 163 801 596 449 -152 94 -133 331 186 216 173 -20 -280 604 115 737 941 -1119 476 912 495 293 134 450 -160 -127 -722 -145 876 734 -639 -88 -715 -965 SS 20231118T163604.7Z 8722.691721 206 1 25.31 2 60.10 178.67 95.68 118.54 0.00 1 0.00 1 0 17 9.154e-03 5.329e-03 2.551e-03 9.216e-04 2.575812e-01 4.663303e-04 3.186348e-03 -6.000000e+00 5.235359e-03 223.20 -2.00 3.51 -2.00 316.92 0.00e+00 4.902431e-04 6.122267e-05 9.260453e-05 -6.000000e+00 2.309108e-04 280.08 -2.00 20.00 -2.00 316.28 0.00e+00 1.997 0.000 302.00 328.00 3 3.3001e+00 1.2100e-03 2.3749e-02 -6.0000e+00 1.2893e-02 3.1782e-02 1.3523e-03 1.3113e-02 -6.0000e+00 1.3963e-02 -8.8914e-04 8.1368e-04 6.5546e-03 -6.0000e+00 8.3289e-03 -1.0442e-03 4.0919e-04 1.9272e-03 -6.0000e+00 3.6648e-03 1.9453e-03 -1.8008e-04 2.6275e-05 2.2290e-05 -6.0000e+00 2.4854e-04 -5.7892e-02 1.8608e-04 12 1 1 12 9 1 99.97 20.21 0.21 -0.05789 -0.05925 128 67 1 5 0 196.100 24.96 20.00 20.21 15.39 23.5 942.52 -740 -293 -2462 -2625 -3277 -3028 -150 -468 549 -2722 -1371 -1779 195 453 -628 -649 15 689 778 1405 357 1006 -3108 820 544 466 -703 -436 -204 354 920 1824 1364 -1285 -1616 -1612 -850 -370 -439 -885 -602 -860 -732 -368 -3 -174 -600 -242 -643 725 267 717 994 642 835 996 713 430 787 753 1059 1458 1595 1041 25 -57 -407 442 712 554 194 134 18 -49 -13 -161 -505 -545 -143 -843 -788 -1352 -1830 -1378 -859 -811 -409 -198 -89 198 250 70 371 779 452 318 445 487 6 -278 -572 -535 46 -144 -702 -705 -743 -456 23 396 101 238 165 198 32 389 325 315 234 40 -164 98 135 550 574 -1 554 876 360 251 85 206 -50 -292 -185 -96 226 94 -315 -176 -483 -453 -92 -40 -346 -347 -426 -372 -19 -61 79 -422 -208 -278 33 89 -142 -162 4 184 215 400 105 290 -950 254 179 159 -241 -141 -62 104 282 604 490 -486 -579 -562 -317 -149 -212 -499 -344 -517 -452 -228 -2 -107 -365 -143 -373 417 162 466 682 464 621 756 552 332 594 564 814 1118 1329 928 22 -48 -314 353 563 496 179 129 18 -45 -12 -133 -407 -417 -113 -707 -744 -1328 -1929 -1517 -945 -956 -508 -253 -114 243 285 78 372 804 462 360 526 637 8 -363 -743 -636 55 -177 -883 -942 -979 -626 33 573 154 369 247 290 43 518 430 435 328 59 -253 149 199 774 813 -1 707 1115 492 349 125 309 -76 -440 -295 -161 388 157 -532 -306 -809 -729 SS 20231118T164038.8Z 8722.694893 209 1 48.76 2 60.09 179.91 94.95 119.22 0.00 1 0.00 1 0 17 9.382e-03 5.030e-03 1.424e-03 4.071e-04 2.575409e-01 2.050931e-04 3.177999e-03 -6.000000e+00 5.365603e-03 223.20 -2.00 3.51 -2.00 317.56 0.00e+00 4.528391e-04 3.162729e-05 1.325872e-04 -6.000000e+00 2.366632e-04 280.08 -2.00 20.00 -2.00 316.92 0.00e+00 1.997 0.000 302.00 328.00 3 1.8581e+00 5.3764e-04 2.3758e-02 -6.0000e+00 1.3214e-02 1.9085e-02 6.0424e-04 1.3141e-02 -6.0000e+00 1.4311e-02 3.1634e-03 3.7624e-04 6.5847e-03 -6.0000e+00 8.5363e-03 -3.4180e-03 1.9351e-04 1.9400e-03 -6.0000e+00 3.7558e-03 8.2745e-03 -1.5137e-04 1.1753e-05 2.1801e-05 -6.0000e+00 2.5474e-04 -5.7311e-02 1.9514e-04 10 0 0 10 0 0 100.00 20.22 0.20 -0.05731 -0.05845 3398 958 1 5 0 13.770 25.07 19.98 20.22 15.57 23.5 943.92 -907 -564 -2350 -3459 -3222 -3198 -1423 -682 -307 -2601 -1947 -1826 -897 -367 212 -321 153 230 528 1193 371 728 -2804 549 124 158 -570 -827 -558 178 1065 1586 726 -1402 -1899 -1533 -1176 -231 -52 -561 -866 -734 -820 -470 -168 -204 -588 -475 -364 395 744 932 1209 834 853 985 637 382 701 884 1197 1484 1617 1114 38 -3 -148 369 865 619 281 161 9 -24 -64 -130 -436 -397 -226 -657 -868 -1367 -1746 -1272 -835 -714 -413 -165 24 242 188 37 496 796 498 477 498 89 -2 -286 -534 -668 52 -67 -791 -744 -692 -480 6 327 230 340 161 159 20 453 281 350 177 -93 -224 131 158 451 515 -11 529 767 417 212 11 167 -97 -265 -175 -7 303 114 -270 -136 -396 -465 -88 -60 -260 -363 -302 -284 -131 -70 -35 -318 -235 -226 -123 -57 38 -63 31 49 116 270 86 167 -679 136 33 43 -155 -213 -134 42 260 420 210 -424 -545 -427 -352 -80 -22 -273 -426 -378 -434 -250 -89 -118 -335 -264 -197 214 422 566 712 518 546 643 425 254 456 570 792 1051 1245 917 31 -2 -106 254 632 513 256 153 9 -22 -55 -100 -304 -286 -170 -510 -761 -1330 -1821 -1385 -892 -817 -498 -205 30 289 208 40 493 763 506 534 573 113 -3 -386 -676 -839 62 -81 -972 -968 -942 -681 9 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