File name: Pandora135s1_ManhattanNY-CCNY_20231119_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T180825.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20231119_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20231119 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231119T122210.6Z 8723.515401 52 1 46.46 2 85.03 121.14 147.55 62.75 0.00 1 0.00 1 0 25 9.806e-01 6.051e-02 4.601e-01 3.153e-02 9.115585e-01 1.935708e-02 9.825878e-03 -6.000000e+00 5.869556e-01 223.19 -2.00 3.51 -2.00 322.28 0.00e+00 -1.081074e-02 1.118027e-02 4.664928e-03 -6.000000e+00 3.803329e-02 279.99 -2.00 20.00 -2.00 321.83 0.00e+00 9.871 0.018 302.00 328.00 3 6.8267e-01 7.6755e-02 1.1522e-01 -6.0000e+00 1.4498e+00 1.6511e+00 8.9731e-02 6.7179e-02 -6.0000e+00 1.5916e+00 -2.0887e+00 5.9496e-02 2.5146e-02 -6.0000e+00 9.3096e-01 8.3985e-01 3.0792e-02 1.1403e-02 -6.0000e+00 4.0924e-01 6.0573e-06 -2.3917e-03 9.5281e-04 1.1784e-04 -6.0000e+00 3.0921e-02 -8.5272e-03 0.0000e+00 12 9 8 11 8 0 41.15 19.77 1.19 -0.00853 -0.02650 26 7 1 5 0 1786.470 24.65 19.99 19.77 10.97 22.9 911.43 103846 900000 101148 900000 900000 -66728 900000 900000 900000 131046 900000 900000 900000 900000 -80315 345346 900000 345947 342596 122186 188804 900000 55225 142374 900000 176928 900000 900000 900000 87020 -1525 310935 900000 101198 161124 900000 900000 247849 900000 900000 900000 33469 110534 8194 158667 900000 900000 127964 900000 900000 13652 900000 60370 89921 186629 900000 -11719 65232 38183 9001 431339 15801 -5782 24824 -5532 -1964 84925 -19176 26665 22834 1699 45798 6316 32608 17496 120132 5517 9874 12780 5513 -9267 28309 -14738 25787 6318 -6189 17362 5186 10931 -2933 -15 -817 -8532 -15349 -13102 -1534 -17997 4710 -9631 -3076 2388 4504 -3804 -785 5121 -3072 -2259 -353 -246 -736 933 2447 -2828 -4887 7232 -3776 323 -5218 5642 -2289 6684 10567 5972 10712 -1092 -19794 -1171 7067 2657 2487 3549 1 571 -2122 -1499 -2055 2518 3017 -469 432 1205 -3993 -1034 3863 900000 3653 900000 900000 -7004 900000 900000 900000 4005 900000 900000 900000 900000 -14086 10553 900000 10572 10469 3734 5770 900000 2170 4351 900000 5407 900000 900000 900000 2659 -89 9502 900000 3092 4924 900000 900000 7574 900000 900000 900000 2581 4053 751 4849 900000 900000 3910 900000 900000 1231 900000 4059 4809 5703 900000 -1916 4784 3384 976 13181 1618 -822 2921 -938 -318 5709 -3809 3707 3768 379 6788 1351 4933 2727 5874 784 1373 1953 1087 -2520 6142 -5495 6856 2162 -2534 5863 2021 3975 -1174 -5 -283 -3155 -6473 -6226 -771 -12594 3058 -8049 -2467 1715 2829 -2325 -457 3005 -2089 -1616 -268 -210 -737 1059 3021 -3655 -6436 8586 -4858 401 -7191 7387 -3201 8803 12707 7191 12014 -1343 -28550 -1365 8012 3662 4035 6151 3 1195 -4926 -3730 -5441 6501 7819 -1250 1090 2781 -8902 -2230 SS 20231119T123340.5Z 8723.523386 55 1 47.03 2 83.19 123.14 145.66 65.86 0.00 1 0.00 1 0 25 6.026e-01 1.751e-02 3.275e-01 6.821e-03 8.466469e-01 3.922523e-03 9.266396e-03 -6.000000e+00 3.445065e-01 223.19 -2.00 3.51 -2.00 322.09 0.00e+00 7.930483e-03 2.365553e-03 1.286137e-03 -6.000000e+00 1.721571e-02 279.99 -2.00 20.00 -2.00 321.62 0.00e+00 7.707 0.008 302.00 328.00 3 7.5635e-01 1.5536e-02 9.0029e-02 -6.0000e+00 8.5011e-01 5.2393e-01 2.3942e-02 5.1589e-02 -6.0000e+00 9.2964e-01 -6.8815e-01 2.5836e-02 2.7230e-02 -6.0000e+00 5.5370e-01 2.7673e-01 1.1606e-02 1.1746e-02 -6.0000e+00 2.4055e-01 5.4566e-05 -1.5191e-03 1.9258e-04 1.5199e-04 -6.0000e+00 1.7267e-02 -8.1867e-03 0.0000e+00 12 8 8 10 0 0 19.43 19.78 0.32 -0.00819 -0.01960 108 30 1 5 0 435.340 24.65 20.00 19.78 11.47 22.9 915.40 900000 -87111 900000 900000 900000 -240578 -197830 900000 -260831 -131040 -209841 900000 -48623 900000 -183942 900000 900000 -100460 187319 -53445 900000 -139840 900000 -102377 49660 -57200 23937 62119 40818 -6843 -78743 78249 -3002 29146 -33262 95722 -10287 158583 56176 89134 56157 -5583 58380 -19924 70481 -12246 57443 6786 92387 21357 31968 32884 19766 39481 12014 43713 -4351 22385 -9657 14759 8990 26328 8080 17609 14038 2654 16238 -3847 15469 822 13060 4179 9589 2045 5254 10435 -4460 -701 -7121 4296 -4768 4167 -4562 6977 -1904 2794 1437 1714 3180 -5 2577 -2881 2353 -4446 -753 -3866 -795 -3789 -924 -668 -879 -44 -2041 -176 -3411 -1142 -3505 356 -1285 813 -182 458 275 -1222 1161 -848 356 -1324 1114 -792 1661 1058 2006 1516 428 -2028 -362 2028 -349 1129 116 1203 -286 -218 -546 -134 647 625 -366 -286 259 -1440 20 900000 -578 900000 900000 900000 -3484 -1910 900000 -5509 -870 -2912 900000 -323 900000 -5328 900000 900000 -2001 1243 -742 900000 -4472 900000 -2409 330 -932 191 412 271 -82 -2186 623 -64 484 -903 762 -253 1053 1007 1361 1342 -243 1550 -1082 1731 -643 1716 356 2208 1134 1719 1986 1372 2454 1044 2875 -473 1837 -1049 1220 808 2208 946 2168 1948 416 2234 -680 2520 179 2782 1014 2164 464 1040 1751 -818 -129 -1616 1060 -1545 1436 -1911 2783 -882 1312 719 880 1604 -2 1185 -1321 1004 -2152 -405 -2557 -605 -3180 -839 -617 -766 -37 -1566 -131 -2789 -971 -3236 342 -1292 924 -238 649 402 -1788 1594 -1149 481 -1910 1662 -1246 2500 1523 2732 2021 560 -2634 -450 2599 -531 1974 231 2568 -661 -498 -1349 -348 1704 1664 -981 -735 614 -3480 46 SS 20231119T124426.6Z 8723.530863 58 1 46.74 2 81.50 125.05 143.85 68.57 0.00 1 0.00 1 0 25 5.566e-01 6.502e-03 1.888e-01 2.623e-03 7.398397e-01 1.397660e-03 8.169596e-03 -6.000000e+00 3.127164e-01 223.19 -2.00 3.51 -2.00 321.58 0.00e+00 4.658588e-03 7.549353e-04 1.005202e-03 -6.000000e+00 1.394937e-02 279.99 -2.00 20.00 -2.00 321.08 0.00e+00 6.376 0.005 302.00 328.00 3 6.4982e-01 5.0581e-03 7.4381e-02 -6.0000e+00 7.6963e-01 1.0613e-01 7.6222e-03 4.0973e-02 -6.0000e+00 8.3881e-01 -1.2194e-01 8.4078e-03 2.3034e-02 -6.0000e+00 5.0066e-01 4.2219e-02 3.8778e-03 9.3579e-03 -6.0000e+00 2.1407e-01 2.4879e-04 -9.0964e-04 7.1721e-05 1.0519e-04 -6.0000e+00 1.5096e-02 -8.9318e-03 0.0000e+00 11 8 0 10 0 0 22.53 19.79 0.28 -0.00893 -0.01577 262 74 1 5 0 178.370 24.65 20.00 19.79 12.30 23.0 921.27 -200713 -130412 -212399 -161711 -98955 -241868 -202487 -168365 -140849 -187058 -118771 -139578 -80828 -85979 -135409 -66110 -28907 -45976 -45936 -34669 -49130 -48312 -45542 -56063 -40142 -55778 -31256 -40505 -28841 -42057 -34538 -27439 -1224 -25849 -14344 -19751 -11436 -2716 7129 2028 1454 -4552 -2540 -3226 -4630 3929 -515 3094 6617 9944 1699 5584 4531 5073 3484 5543 128 1423 -654 -1228 3901 5239 3342 3362 2387 2604 2903 2456 2941 2496 1140 2294 387 1436 821 744 -2396 -2918 -1173 -350 127 -231 -1115 -852 -528 -601 127 -75 555 1108 528 454 -78 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