File name: Pandora135s1_ManhattanNY-CCNY_20231120_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T180830.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20231120_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20231120 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231120T122319.5Z 8724.516198 52 1 46.47 2 85.05 121.45 150.78 38.44 0.00 1 0.00 1 0 73 1.964e+00 1.143e-01 4.160e-01 2.498e-02 9.188846e-01 1.564321e-02 1.201725e-02 -6.000000e+00 1.156030e+00 223.18 -2.00 3.51 -2.00 319.93 0.00e+00 1.635204e-01 7.217506e-03 7.068076e-03 -6.000000e+00 6.378400e-02 279.88 -2.00 20.00 -2.00 319.08 0.00e+00 9.898 0.018 302.00 328.00 3 -9.4425e-01 5.2614e-02 1.1453e-01 -6.0000e+00 2.8618e+00 3.7327e+00 5.6243e-02 5.5143e-02 -6.0000e+00 3.1421e+00 -3.9464e+00 2.9600e-02 2.8859e-02 -6.0000e+00 1.8503e+00 1.5426e+00 2.0782e-02 1.2001e-02 -6.0000e+00 8.0945e-01 9.0205e-06 -1.5509e-02 5.7904e-04 3.0774e-04 -6.0000e+00 5.8394e-02 -1.0569e-02 0.0000e+00 12 8 8 10 0 0 44.86 19.58 0.70 -0.01057 -0.12711 42 12 1 5 0 1105.060 24.46 20.01 19.58 8.91 22.8 896.95 900000 772222 900000 678176 900000 590066 900000 628125 900000 900000 274957 900000 161381 900000 197357 900000 467316 900000 457925 576181 498106 494465 -11776 256614 900000 66318 900000 133458 900000 86442 343053 316171 900000 476625 313857 900000 185973 900000 162398 900000 111028 160387 54383 135819 900000 179770 900000 238478 900000 186815 900000 152144 900000 122895 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10503 -5094 5431 -1434 6021 -4051 7588 -2456 2622 -48 -14419 -9786 -14414 -7497 -7426 7225 5420 19134 12786 11723 1582 -1887 -3672 -13338 1098 -13643 245 -13139 -1588 -11094 -2822 17 -4233 -3392 -5780 7865 4080 20090 13180 18685 6905 7380 -19458 2295 -1069 -3375 -2654 -1668 8620 521 -1532 -10379 -3398 -4852 1687 -10831 6952 14681 -1229 -422 SS 20231120T123439.4Z 8724.524068 55 1 46.69 2 83.24 123.42 149.41 42.86 0.00 1 0.00 1 0 17 7.314e-01 1.048e-02 3.445e-01 5.724e-03 8.789786e-01 3.285831e-03 9.407633e-03 -6.000000e+00 4.169159e-01 223.18 -2.00 3.51 -2.00 322.15 0.00e+00 7.055248e-03 2.023806e-03 3.166575e-03 -6.000000e+00 2.197131e-02 279.88 -2.00 20.00 -2.00 321.71 0.00e+00 7.755 0.008 302.00 328.00 3 4.0612e-01 1.3256e-02 9.4438e-02 -6.0000e+00 1.0275e+00 3.4230e-01 2.2189e-02 6.4459e-02 -6.0000e+00 1.1226e+00 -4.1974e-01 2.5370e-02 3.0183e-02 -6.0000e+00 6.6719e-01 1.6424e-01 1.1234e-02 1.2845e-02 -6.0000e+00 2.8659e-01 7.3764e-05 -1.1397e-03 1.5959e-04 1.3884e-04 -6.0000e+00 2.0615e-02 -1.0704e-02 0.0000e+00 12 9 8 11 8 0 -0.49 19.57 0.32 -0.01070 -0.01927 148 42 1 5 0 315.380 24.46 20.01 19.57 9.20 22.6 898.89 -271283 900000 -288680 -23533 900000 -298674 -259522 -254954 900000 -281382 900000 -211424 900000 -175144 -234473 -98221 900000 -87360 -105831 13428 -75088 34041 900000 38922 -81333 900000 -88138 900000 -58429 -57316 -95680 -15803 77602 -23118 1559 -20468 65190 20616 49504 -16696 51354 -32588 13309 -4945 14583 21864 -2165 23543 9506 30598 -11710 21269 3414 19681 6933 25503 -3076 8144 9155 -81 19950 3278 3993 7395 8325 -938 8359 471 6900 5367 2548 7919 2795 3838 2281 7864 -7040 -3012 -3695 -1211 1374 -602 -725 1007 -112 -1841 2817 -374 2791 486 2345 580 93 -841 -1138 -838 -1306 -474 -574 -94 -1789 74 107 -774 -1007 -1613 -457 -510 -570 -722 53 -532 335 -519 295 -407 106 -60 100 89 219 1363 788 1667 -202 -1938 35 774 160 243 513 618 224 -490 -240 -203 664 132 -182 -149 -194 -388 -137 -1512 900000 -2385 -131 900000 -2497 -1550 -1624 900000 -2800 900000 -1347 900000 -1464 -4760 -645 900000 -721 -1116 75 -651 190 900000 217 -907 900000 -1128 900000 -567 -627 -1955 -186 449 -387 20 -321 489 287 637 -482 859 -1379 379 -176 436 632 -84 753 381 1099 -732 1098 236 1276 548 1758 -291 684 735 -7 1445 313 444 895 1095 -138 1135 73 1136 1042 564 1738 636 807 439 1280 -1260 -543 -781 -306 408 -206 -277 405 -49 -862 1324 -187 1346 232 1030 246 39 -379 -596 -523 -942 -396 -536 -89 -1623 59 78 -560 -779 -1336 -396 -464 -583 -857 69 -763 491 -758 411 -552 145 -86 152 139 333 1943 1079 2273 -273 -2579 45 1034 243 430 990 1296 503 -1158 -609 -545 1800 364 -501 -392 -475 -906 -306 SS 20231120T124526.2Z 8724.531553 58 1 46.76 2 81.56 125.34 148.01 46.77 0.00 1 0.00 1 0 25 5.623e-01 6.687e-03 1.826e-01 2.303e-03 7.616869e-01 1.243286e-03 8.380105e-03 -6.000000e+00 3.164221e-01 223.18 -2.00 3.51 -2.00 321.64 0.00e+00 5.500628e-03 6.722368e-04 9.125091e-04 -6.000000e+00 1.433523e-02 279.88 -2.00 20.00 -2.00 321.15 0.00e+00 6.413 0.005 302.00 328.00 3 3.4624e-01 4.4585e-03 7.5390e-02 -6.0000e+00 7.7824e-01 1.3662e-01 6.8180e-03 4.2660e-02 -6.0000e+00 8.4822e-01 -1.5556e-01 7.6031e-03 2.3987e-02 -6.0000e+00 5.0588e-01 5.7324e-02 3.5026e-03 1.0408e-02 -6.0000e+00 2.1649e-01 3.1413e-04 -9.5120e-04 6.2945e-05 1.1247e-04 -6.0000e+00 1.5399e-02 -1.1273e-02 0.0000e+00 11 8 0 10 0 0 26.41 19.57 0.26 -0.01127 -0.01842 334 94 1 5 0 139.980 24.46 20.00 19.57 9.65 22.7 902.42 -172348 -201258 -73474 -229514 900000 -243341 -161707 -163366 -146314 -188658 -158738 -131222 -150184 -33834 -135512 50878 -71741 -30185 -66208 -46649 -47346 -57722 -47998 -88289 -20715 -64073 -26893 -47772 -12870 -58711 -19178 -15925 7429 -16090 -25146 -8247 -24118 3722 -5967 6493 -6773 1720 -7586 -1863 1451 -3140 6702 464 10402 -1223 5709 4049 9801 4429 5189 6739 1333 1390 381 1009 769 4294 1698 5996 1808 3999 1734 3235 2192 2324 2153 1818 1552 -771 499 -1084 -364 -2210 -266 -690 -234 -210 -1346 276 -1042 -329 -305 334 380 676 103 653 452 228 -87 -494 329 -748 281 -415 -489 -1013 125 -870 -1495 -1291 -914 -315 -286 330 -142 388 -7 252 -92 318 67 240 283 -302 110 369 858 397 287 -1013 559 662 92 24 32 384 -143 -115 -380 -87 205 292 -329 -11 -98 -76 -53 -619 -1068 -165 -1780 900000 -1987 -690 -807 -690 -1483 -998 -737 -1349 -129 -1886 137 -773 -244 -847 -524 -553 -752 -593 -1784 -233 -1180 -350 -762 -147 -1186 -323 -325 143 -430 -723 -198 -742 104 -226 262 -357 91 -470 -113 88 -206 415 32 705 -102 501 374 954 500 623 836 180 188 51 131 103 618 291 1132 385 837 371 712 545 668 688 611 518 -248 144 -285 -89 -569 -77 -241 -97 -100 -724 156 -583 -194 -190 213 242 415 65 386 259 137 -60 -368 285 -758 311 -470 -521 -969 107 -742 -1374 -1259 -938 -346 -348 455 -205 599 -10 387 -135 447 96 355 443 -495 177 565 1250 611 428 -1477 777 962 142 43 64 815 -301 -258 -917 -220 532 765 -865 -29 -232 -179 -121 SS 20231120T130203.0Z 8724.543090 63 1 46.78 2 79.05 128.38 145.68 52.28 0.00 1 0.00 1 0 25 2.642e-01 8.069e-03 4.014e-02 9.414e-04 6.232301e-01 4.898873e-04 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