File name: Pandora135s1_ManhattanNY-CCNY_20231122_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20231123T045858.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20231122_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20231122 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231122T135614.2Z 8726.580720 163 1 9.09 2 72.08 139.26 139.66 26.99 0.00 1 0.00 1 0 25 7.118e-02 9.040e-03 7.934e-02 7.307e-03 4.210006e-01 3.726971e-03 5.153484e-03 -6.000000e+00 4.061215e-02 223.15 -2.00 3.51 -2.00 319.10 0.00e+00 5.999788e-04 9.103784e-04 3.299330e-04 -6.000000e+00 1.790062e-03 279.65 -2.00 20.00 -2.00 318.50 0.00e+00 3.207 0.001 302.00 328.00 3 4.4653e+00 1.0181e-02 3.8492e-02 -6.0000e+00 1.0002e-01 8.0571e-02 1.1811e-02 2.1852e-02 -6.0000e+00 1.0841e-01 -1.5639e-02 9.1039e-03 1.1030e-02 -6.0000e+00 6.4652e-02 2.8272e-04 4.8939e-03 3.2870e-03 -6.0000e+00 2.8386e-02 1.4543e-04 -3.0751e-03 2.0724e-04 3.5392e-05 -6.0000e+00 1.9350e-03 -5.5110e-02 -3.0635e-04 12 9 1 12 1 1 95.69 20.25 0.20 -0.05511 -0.07822 3 6 1 5 0 2272.050 25.07 19.99 20.25 15.57 23.3 944.09 -10671 -19993 -26707 -14642 9784 -4437 -36957 25664 -26428 -11237 -6224 -20287 -10038 3428 -27742 8106 4604 -14513 9659 4928 2093 -1838 -16134 7331 -6579 -2782 1671 1971 -4184 1723 -7257 6336 -1927 76 -3314 -278 -3121 -129 915 -1893 1702 -630 507 -2022 2270 -996 306 692 501 2883 -689 3385 -782 1577 133 3334 -2251 1708 -1778 1918 5035 1965 2185 663 1761 -1259 2208 -1494 538 -206 640 1401 569 -686 547 808 -2749 -935 -2249 -603 -1337 290 -2011 -1549 -1100 -799 -583 17 462 -418 168 764 1862 363 1024 356 792 636 -340 485 -1944 92 -518 -36 -1390 -1950 -574 -351 -218 105 162 400 621 -545 695 -193 -220 -764 1432 -467 393 843 330 704 -105 532 -156 1206 -61 357 -102 273 -192 -220 327 -402 309 -11 6 -224 100 -1007 -273 -634 -945 -439 217 -110 -1307 575 -1084 -422 -228 -917 -481 173 -2207 532 339 -1383 766 429 192 -175 -1770 708 -787 -336 194 218 -471 186 -947 820 -302 12 -528 -42 -530 -24 208 -521 486 -196 162 -671 725 -331 100 234 171 991 -256 1320 -343 720 62 1564 -1142 831 -874 925 2421 1023 1258 410 1102 -795 1273 -890 340 -145 476 1080 440 -514 385 525 -1690 -549 -1434 -421 -1078 250 -1862 -1504 -1133 -853 -656 19 529 -465 178 739 1706 335 982 387 942 824 -467 657 -2525 112 -591 -41 -1706 -2553 -777 -486 -313 164 265 658 1027 -861 1031 -279 -317 -1124 2196 -752 635 1324 516 1058 -156 748 -216 1670 -91 566 -170 471 -335 -401 616 -783 614 -22 13 -445 193 -1908 SS 20231122T140554.2Z 8726.587432 166 1 46.72 2 70.91 141.31 138.78 30.25 0.00 1 0.00 1 0 17 1.077e-01 1.382e-02 3.837e-02 3.548e-03 3.903109e-01 1.804157e-03 4.735346e-03 -6.000000e+00 6.157125e-02 223.15 -2.00 3.51 -2.00 319.08 0.00e+00 2.119778e-03 4.363789e-04 4.143330e-04 -6.000000e+00 2.712469e-03 279.65 -2.00 20.00 -2.00 318.47 0.00e+00 3.022 0.000 302.00 328.00 3 4.8997e+00 4.9384e-03 3.6024e-02 -6.0000e+00 1.5164e-01 7.9407e-02 5.7103e-03 2.0062e-02 -6.0000e+00 1.6426e-01 -3.2029e-02 4.2979e-03 1.0320e-02 -6.0000e+00 9.7957e-02 1.3982e-02 2.3053e-03 3.4524e-03 -6.0000e+00 4.3077e-02 1.1690e-04 -1.0544e-03 1.0177e-04 3.6676e-05 -6.0000e+00 2.9258e-03 -5.7905e-02 7.0806e-05 12 8 8 10 0 0 99.98 20.26 0.31 -0.05791 -0.06583 34 10 1 5 0 1373.580 25.07 20.00 20.26 15.74 23.3 945.04 -14604 11493 13883 -5351 55827 -46462 36446 -3634 34159 -22769 21359 -1462 13754 13446 -16581 12490 3085 11920 567 15759 1733 12792 -66064 6094 1539 4552 1771 -42 7692 -4494 9654 -70 13388 -2216 1860 -997 -785 3875 3086 2828 -71 2044 -1799 2212 -391 4432 8 2114 3005 2764 576 1280 3153 1520 3521 1255 142 -731 760 187 3734 2474 2041 1914 47 851 -934 -57 -568 769 -799 681 -573 -187 -413 303 -929 -2876 87 -1660 -676 -1456 -1784 -1655 -866 -993 -453 -245 -67 649 22 810 -102 733 -443 325 -306 587 141 -159 -210 -484 4 -881 -489 -849 -740 -371 114 473 191 659 -151 121 184 239 8 268 81 -149 224 714 826 625 602 -1855 516 572 741 131 278 12 36 -114 -508 -107 149 772 -618 60 -466 -544 -500 342 420 -187 995 -2119 795 -128 959 -1149 703 -64 606 717 -1366 907 257 1000 54 1401 175 1191 -12876 635 179 555 222 -5 834 -557 1142 -10 1916 -373 297 -160 -136 727 706 760 -22 650 -595 741 -135 1472 3 714 1009 955 218 506 1313 683 1614 605 70 -365 365 90 1776 1291 1183 1206 30 524 -550 -33 -356 523 -605 531 -450 -140 -287 194 -549 -1678 53 -1170 -521 -1263 -1619 -1580 -874 -1074 -498 -277 -76 724 23 795 -93 658 -433 342 -354 752 189 -212 -271 -588 5 -1021 -610 -1091 -995 -523 165 742 312 1104 -250 193 272 343 11 398 125 -244 370 1150 1284 938 889 -2678 692 775 1089 205 465 20 63 -206 -955 -211 301 1573 -1281 121 -895 -1023 SS 20231122T141148.4Z 8726.591532 170 1 46.78 2 70.23 142.58 138.20 32.19 0.00 1 0.00 1 0 25 2.756e-02 4.907e-03 1.312e-02 1.307e-03 3.830899e-01 6.604610e-04 4.592539e-03 -6.000000e+00 1.576110e-02 223.15 -2.00 3.51 -2.00 319.11 0.00e+00 7.072245e-04 1.622207e-04 1.683200e-04 -6.000000e+00 6.940353e-04 279.65 -2.00 20.00 -2.00 318.51 0.00e+00 2.924 0.000 302.00 328.00 3 3.0345e+00 1.8069e-03 3.4949e-02 -6.0000e+00 3.8817e-02 2.5843e-02 2.0990e-03 1.9588e-02 -6.0000e+00 4.2041e-02 1.8704e-02 1.6057e-03 9.9599e-03 -6.0000e+00 2.5072e-02 -1.3346e-02 8.6114e-04 3.0560e-03 -6.0000e+00 1.1030e-02 8.5547e-04 -3.6842e-04 3.7526e-05 3.1613e-05 -6.0000e+00 7.4829e-04 -5.9008e-02 1.7297e-04 10 0 0 10 0 0 99.99 20.25 0.33 -0.05901 -0.06178 443 125 1 5 0 105.580 25.07 19.98 20.25 15.83 23.4 945.82 -8562 -1212 -12773 -2318 -11399 -7930 -7494 -2233 -7491 -9544 -8135 -9103 -3727 -3429 -3215 -1387 2978 -1900 2884 -1954 1477 -906 8636 -1803 -2495 -406 -3286 -472 -1226 963 -1197 2669 569 -2022 -2134 -1706 -1168 335 542 -1120 -537 -2080 -780 -1178 -327 -1037 -697 -670 -250 951 467 1248 623 968 175 1561 -115 523 478 800 1499 1177 1624 1024 262 -176 596 598 1266 518 260 271 -150 138 -56 404 -432 112 -186 -176 -869 -1172 -1792 -1226 -797 -799 -311 -295 111 324 622 160 1013 1037 888 341 504 237 -126 -87 -618 -437 -104 -171 -1004 -704 -782 -464 157 216 72 92 203 -32 228 278 393 237 95 -340 -417 218 -19 469 235 -267 448 1034 348 345 -146 277 -183 -317 -165 -196 442 148 -122 -172 -189 -299 -241 -36 -442 -69 -339 -219 -220 -71 -284 -394 -337 -405 -183 -201 -223 -107 238 -170 260 -193 145 -91 812 -202 -303 -51 -423 -57 -141 109 -152 368 89 -340 -343 -267 -198 66 130 -294 -156 -650 -250 -385 -107 -342 -228 -219 -81 315 166 481 260 428 81 739 -57 255 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