File name: Pandora135s1_ManhattanNY-CCNY_20231125_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T180806.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20231125_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20231125 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231125T122940.1Z 8729.520602 231 1 46.30 2 85.02 123.04 113.79 319.11 0.00 1 0.00 1 0 25 8.077e-01 5.426e-02 4.058e-01 2.782e-02 9.611858e-01 1.731051e-02 1.061482e-02 -6.000000e+00 4.893477e-01 223.10 -2.00 3.51 -2.00 322.36 0.00e+00 -5.039355e-03 9.390942e-03 8.902347e-03 -6.000000e+00 2.713186e-02 279.33 -2.00 20.00 -2.00 321.90 0.00e+00 9.861 0.018 302.00 328.00 3 3.8078e-01 6.6407e-02 1.2395e-01 -6.0000e+00 1.2090e+00 1.8159e+00 7.8801e-02 8.7123e-02 -6.0000e+00 1.3327e+00 -2.1800e+00 5.2332e-02 3.0863e-02 -6.0000e+00 7.9503e-01 8.5031e-01 2.7362e-02 1.0435e-02 -6.0000e+00 3.4043e-01 7.1888e-06 -2.5772e-03 8.1143e-04 1.4519e-04 -6.0000e+00 2.6333e-02 -1.4309e-02 0.0000e+00 12 8 8 10 0 0 15.95 19.31 0.94 -0.01431 -0.03367 31 9 1 5 0 1493.330 24.25 20.00 19.31 6.12 22.4 878.84 41966 900000 94921 900000 900000 -57411 361127 363534 900000 -35798 900000 104940 900000 227517 -42672 900000 900000 900000 74287 900000 86095 900000 -85749 900000 49380 900000 136957 900000 900000 -4653 183699 28174 900000 46253 900000 27088 900000 900000 900000 900000 900000 97215 45328 55455 96463 900000 88703 900000 244532 900000 3667 250109 67985 67098 125841 242407 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4546 -5730 4487 -4058 -1311 -9436 2137 -9440 9926 -7143 -4078 -39 -1532 301 -5629 3685 -3683 2029 -2479 3551 1222 1226 1102 -5345 -2633 -22 -1178 -3341 2058 1113 3382 3348 8031 11736 9788 1704 -25136 166 138 7437 -3179 8333 -3546 2860 -5870 -1314 -3112 3163 7792 -6271 6544 2399 -3473 -6326 SS 20231125T124105.1Z 8729.528531 234 1 46.91 2 83.23 125.03 115.07 321.64 0.00 1 0.00 1 0 25 6.739e-01 1.548e-02 3.173e-01 6.005e-03 8.831854e-01 3.478834e-03 9.558431e-03 -6.000000e+00 3.865582e-01 223.10 -2.00 3.51 -2.00 322.16 0.00e+00 9.822212e-03 2.107747e-03 4.460940e-03 -6.000000e+00 1.861783e-02 279.33 -2.00 20.00 -2.00 321.72 0.00e+00 7.749 0.008 302.00 328.00 3 4.5436e-01 1.3804e-02 9.7296e-02 -6.0000e+00 9.5853e-01 5.2776e-01 2.1896e-02 7.2001e-02 -6.0000e+00 1.0498e+00 -6.6768e-01 2.4336e-02 2.9599e-02 -6.0000e+00 6.2116e-01 2.6728e-01 1.0885e-02 1.3848e-02 -6.0000e+00 2.6537e-01 6.7137e-05 -1.7820e-03 1.6713e-04 1.4098e-04 -6.0000e+00 1.9115e-02 -1.5346e-02 0.0000e+00 12 9 8 11 8 0 1.45 19.31 0.35 -0.01535 -0.02874 137 39 1 5 0 342.320 24.25 20.01 19.31 7.13 22.4 886.11 -241108 900000 -263876 900000 -129456 -83289 -292404 900000 -238184 900000 -153932 -117272 106479 -117309 -163840 -108626 900000 -142237 900000 -123164 900000 -72262 900000 -84372 13088 173660 -83572 900000 -50498 900000 -108514 900000 -12671 61983 -12390 49085 50814 5270 156596 12029 105023 -19286 83443 -19849 52420 4613 48225 29260 36982 52026 -2757 46870 5177 51768 5862 49080 -1501 27211 1295 8982 24500 5849 16617 741 12663 519 19155 -2347 12153 4364 6427 8559 4197 6608 -1650 18152 -9814 1207 -11260 3054 -2755 3542 -1659 4774 1315 -1166 4555 -299 3161 -293 4208 -1411 1992 -3061 -1303 -1346 -1773 137 -1890 160 -1829 733 -2859 -109 -3282 -888 -2516 -1024 -481 -804 145 -713 139 -1589 1231 -1025 664 -769 486 -315 652 2067 944 2462 -588 -928 -461 1894 81 805 351 1027 275 -334 -161 -406 515 -10 -147 -207 666 -1126 -586 -2186 900000 -3935 900000 -756 -487 -4831 900000 -2734 900000 -899 -685 622 -955 -2838 -1360 900000 -3295 900000 -2673 900000 -920 900000 -1285 82 1015 -1429 900000 -623 900000 -3284 900000 -233 590 -241 499 539 103 915 315 1275 -847 1444 -962 1259 185 1305 1020 1289 1711 -177 2090 390 2678 511 2889 -144 2014 119 745 1782 568 1694 100 1662 78 2418 -387 1933 868 1390 1893 955 1368 -334 2686 -1804 207 -2533 730 -842 1146 -633 1829 554 -534 2071 -147 1499 -139 1794 -601 804 -1376 -664 -822 -1253 111 -1757 150 -1650 574 -2133 -77 -2545 -716 -2183 -916 -481 -934 186 -1009 202 -2325 1688 -1390 891 -1096 724 -490 984 2916 1284 3312 -791 -1217 -585 2468 120 1397 671 2128 613 -781 -405 -1082 1389 -27 -402 -544 1659 -2632 -1297 SS 20231125T125151.1Z 8729.536009 237 1 46.88 2 81.59 126.95 116.22 324.09 0.00 1 0.00 1 0 25 5.436e-01 7.233e-03 2.281e-01 2.474e-03 7.772202e-01 1.335910e-03 8.527913e-03 -6.000000e+00 3.070136e-01 223.10 -2.00 3.51 -2.00 321.64 0.00e+00 6.669975e-03 7.275738e-04 9.294211e-04 -6.000000e+00 1.396844e-02 279.33 -2.00 20.00 -2.00 321.16 0.00e+00 6.431 0.005 302.00 328.00 3 4.4113e-01 4.8502e-03 7.6261e-02 -6.0000e+00 7.5697e-01 1.6400e-01 7.4585e-03 4.4470e-02 -6.0000e+00 8.2556e-01 -1.7034e-01 8.3792e-03 2.4680e-02 -6.0000e+00 4.9028e-01 6.0909e-02 3.8507e-03 1.1383e-02 -6.0000e+00 2.0939e-01 2.7157e-04 -1.0492e-03 6.7191e-05 1.2008e-04 -6.0000e+00 1.4961e-02 -1.5628e-02 0.0000e+00 11 8 0 10 0 0 12.54 19.31 0.31 -0.01563 -0.02351 293 83 1 5 0 159.950 24.25 20.01 19.31 8.47 22.6 896.18 -207094 -181198 -60794 -210906 900000 -264317 5898 -193869 900000 -244726 -133129 -91716 -47674 -15912 -148233 -4891 -106991 57407 -99275 12903 -80346 -9120 -40229 -52322 -30055 -62533 -27663 -61589 -17444 -66390 -18942 -43613 4279 -25929 -9549 -17886 -11499 4064 -7738 6453 354 3334 -8488 3348 -7117 7304 -27 3266 6114 4966 6475 4110 8416 3216 7758 2499 2205 584 973 268 2404 5999 1922 7219 1377 4922 887 2862 1264 3709 927 2435 2007 25 1344 -1259 -1043 -3725 -29 -1731 661 67 -928 -694 -707 -333 -139 661 25 1210 440 776 -405 457 -357 30 -126 -489 58 -519 -337 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