File name: Pandora135s1_ManhattanNY-CCNY_20231201_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20231202T045700.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20231201_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20231201 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231201T124723.0Z 8735.532905 287 1 47.77 2 83.37 126.48 57.07 276.16 0.00 1 0.00 1 0 25 1.026e+00 4.073e-02 4.315e-01 2.013e-02 8.688007e-01 1.210466e-02 9.988962e-03 -6.000000e+00 5.933729e-01 223.01 -2.00 3.51 -2.00 321.81 0.00e+00 1.307527e-02 6.062301e-03 1.889062e-03 -6.000000e+00 3.354381e-02 278.67 -2.00 20.00 -2.00 321.39 0.00e+00 7.882 0.009 302.00 328.00 3 1.9457e+00 4.2252e-02 9.3743e-02 -6.0000e+00 1.4651e+00 1.3824e+00 5.1105e-02 5.9461e-02 -6.0000e+00 1.5921e+00 -1.5862e+00 4.0752e-02 2.4490e-02 -6.0000e+00 9.4217e-01 6.3754e-01 2.0435e-02 1.7462e-02 -6.0000e+00 4.2116e-01 1.0030e-05 -2.9030e-03 5.4729e-04 2.0463e-04 -6.0000e+00 3.0302e-02 -6.2892e-02 1.4618e-04 12 8 8 10 0 0 99.40 19.85 0.23 -0.06289 -0.08471 17 5 1 5 0 2809.680 24.65 20.00 19.85 11.11 22.8 913.86 113543 900000 243763 411757 900000 -129091 61191 28693 900000 -55642 900000 900000 900000 900000 -111736 373529 122477 387862 118803 172964 47366 900000 -13706 104078 900000 134113 417674 900000 900000 -27042 72068 48416 900000 24649 49756 124061 274833 900000 173101 900000 183881 59451 52322 25688 74754 103537 295600 63410 331505 103618 17409 36915 47896 36008 76394 103719 16742 30093 36573 19331 92517 38130 -4129 28925 -437 1289 15767 5900 4132 10653 12376 12768 15119 11072 15280 -16517 4721 -5660 16368 -4921 -711 9138 3701 8891 618 -3138 3198 -229 3000 4299 -7284 -298 -641 -10319 -10477 -5986 -4154 -7297 -761 -3847 1898 1334 -2805 -2449 -2952 -3433 -3496 244 -1789 -1746 -1177 -47 -4453 -3263 1376 -2111 -368 -769 3423 747 4460 3435 3678 3783 460 2521 -1175 676 2887 1118 741 665 1309 1920 -1895 -87 968 1233 -1945 293 296 -4648 2222 900000 4771 8059 900000 -12238 1198 562 900000 -2178 900000 900000 900000 900000 -14899 7311 2397 7592 2491 3385 1790 900000 -778 2037 900000 2625 8175 900000 900000 -1515 1864 1929 900000 1431 2156 2428 5379 900000 3388 900000 3599 3449 3328 2063 3762 4053 5786 3723 6488 4657 1880 3613 4687 4058 6141 6380 2350 3554 3937 2351 5634 4185 -764 4392 -96 278 2905 1234 959 2632 3283 3473 3898 2735 3218 -4203 899 -1226 3248 -1465 -242 3263 1495 3738 287 -1593 1590 -121 1521 2141 -3678 -136 -285 -5300 -5967 -3886 -3147 -6670 -729 -3901 1715 1077 -2090 -1821 -2337 -2806 -3020 219 -1835 -2068 -1586 -68 -6792 -4864 1946 -2983 -513 -1127 5087 1180 6663 4913 4991 4976 606 3150 -1476 873 4210 1941 1410 1377 2867 4474 -4762 -227 2616 3346 -5242 763 712 -10762 SS 20231201T125816.6Z 8735.540470 290 1 47.07 2 81.74 128.42 59.07 277.70 0.00 1 0.00 1 0 17 5.554e-01 1.560e-02 3.063e-01 6.101e-03 7.748435e-01 3.449969e-03 9.013080e-03 -6.000000e+00 3.180209e-01 223.01 -2.00 3.51 -2.00 321.63 0.00e+00 1.150585e-02 1.775539e-03 2.400638e-03 -6.000000e+00 1.493073e-02 278.67 -2.00 20.00 -2.00 321.20 0.00e+00 6.533 0.005 302.00 328.00 3 1.8054e+00 1.2166e-02 7.7107e-02 -6.0000e+00 7.8288e-01 3.9201e-01 1.7806e-02 4.3661e-02 -6.0000e+00 8.4862e-01 -4.7512e-01 1.9243e-02 2.9135e-02 -6.0000e+00 5.0520e-01 1.8953e-01 9.0102e-03 1.6090e-02 -6.0000e+00 2.2470e-01 5.8749e-05 -1.3893e-03 1.6709e-04 1.9698e-04 -6.0000e+00 1.5410e-02 -6.3121e-02 1.6372e-04 12 8 8 10 0 0 98.53 19.86 0.28 -0.06312 -0.07356 67 19 1 5 0 702.410 24.75 20.00 19.86 11.40 22.9 916.00 900000 -111875 75675 -130176 900000 -296467 -193075 -124838 -66866 -213224 900000 134624 -136650 56112 -184900 244718 15693 -28117 -49712 -17648 -65801 5668 -18747 -60769 -12914 -35326 -18561 -444 109005 -54846 -31821 22340 71904 2015 16862 20996 22860 55403 18553 22036 31930 9665 4789 -1053 23991 24413 15666 14212 31487 16190 15790 11538 14183 16835 20825 22861 1636 6711 -2221 2146 12230 10921 4968 7919 4832 438 5762 3648 3745 4749 3803 4405 4899 4275 2082 5661 -1428 -1966 -2118 -1252 671 2157 -1666 2336 -1665 -1058 669 -1257 -496 -258 113 -524 -507 -1685 -2553 -2741 -1526 -1573 -597 -960 -61 -552 -132 -2136 -1380 -1827 -1579 -486 -456 280 -3 700 -263 -524 318 285 -67 -407 1007 -244 1567 1448 1778 1357 69 -2611 -175 1303 666 468 435 449 137 -252 -212 -133 169 264 -675 63 -198 -630 900000 -665 450 -989 900000 -9555 -2360 -825 -398 -3803 900000 800 -1805 334 -6827 1455 119 -371 -887 -239 -1456 60 -254 -1305 -179 -630 -299 -6 648 -1359 -778 422 981 57 419 485 552 1124 619 837 1234 504 278 -67 1228 1290 942 915 1820 1182 1293 1113 1471 1846 2318 2575 232 893 -313 284 1511 1519 850 1514 978 93 1216 774 879 1270 1135 1363 1486 1221 551 1363 -346 -493 -608 -409 256 938 -834 1196 -942 -632 413 -816 -319 -160 65 -286 -268 -942 -1641 -2088 -1287 -1541 -642 -1056 -62 -507 -114 -1856 -1270 -1706 -1554 -510 -531 369 -4 1071 -414 -810 465 421 -101 -608 1570 -400 2484 2193 2696 2005 100 -3752 -238 1825 1076 834 865 963 299 -588 -531 -349 454 716 -1844 163 -481 -1430 SS 20231201T130858.0Z 8735.547893 293 1 46.91 2 80.17 130.38 61.03 279.20 0.00 1 0.00 1 0 17 4.460e-01 7.552e-03 1.725e-01 2.540e-03 6.916388e-01 1.387090e-03 7.904686e-03 -6.000000e+00 2.553358e-01 223.01 -2.00 3.51 -2.00 321.19 0.00e+00 4.944561e-03 6.525647e-04 7.834148e-04 -6.000000e+00 1.137913e-02 278.67 -2.00 20.00 -2.00 320.74 0.00e+00 5.601 0.003 302.00 328.00 3 1.4166e+00 4.6097e-03 6.6494e-02 -6.0000e+00 6.2851e-01 8.4890e-02 6.5969e-03 3.8090e-02 -6.0000e+00 6.8085e-01 -9.4868e-02 7.2101e-03 2.2415e-02 -6.0000e+00 4.0555e-01 3.0979e-02 3.4574e-03 1.0049e-02 -6.0000e+00 1.7853e-01 2.4341e-04 -7.7463e-04 7.0134e-05 9.9727e-05 -6.0000e+00 1.2229e-02 -6.3631e-02 1.5578e-04 11 8 0 10 0 0 80.82 19.86 0.22 -0.06363 -0.06945 189 53 1 5 0 248.180 24.65 19.99 19.86 11.90 22.9 920.38 -50455 -196722 -47268 -174569 900000 -213367 -137087 -116806 -139741 -138023 -142191 -42572 -142443 5550 -128575 -18328 -36868 -26129 -50647 -28756 -17634 -39568 -14944 -49877 -5439 -52855 -9098 -33295 -6048 -37137 -12202 -2518 -5562 -3465 -16731 5477 -15660 12071 -5572 5166 -2880 1672 -3717 -3150 4490 1307 5447 -3217 8112 3712 4641 2068 6268 3330 5132 6123 -822 983 -1092 3773 2308 5645 1890 5167 1301 2378 2191 1353 1653 665 1845 944 2093 -1209 1152 192 103 -2291 281 22 -1448 -588 -2191 -180 -1760 -772 -725 468 368 1151 490 369 736 -654 37 -608 170 -544 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