File name: Pandora135s1_ManhattanNY-CCNY_20231201_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T180632.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20231201_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20231201 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231201T124723.0Z 8735.532905 287 1 47.77 2 83.37 126.48 57.07 276.16 0.00 1 0.00 1 0 25 8.020e-01 3.835e-02 3.984e-01 1.956e-02 8.542003e-01 1.143729e-02 9.521329e-03 -6.000000e+00 4.614257e-01 223.01 -2.00 3.51 -2.00 321.93 0.00e+00 1.356592e-02 6.117517e-03 3.620942e-03 -6.000000e+00 2.874285e-02 278.67 -2.00 20.00 -2.00 321.46 0.00e+00 7.882 0.009 302.00 328.00 3 2.0137e+00 4.1568e-02 9.6883e-02 -6.0000e+00 1.1386e+00 1.3679e+00 5.0685e-02 6.9352e-02 -6.0000e+00 1.2488e+00 -1.5839e+00 4.0168e-02 2.3109e-02 -6.0000e+00 7.4098e-01 6.3220e-01 1.9813e-02 1.7545e-02 -6.0000e+00 3.2006e-01 9.8236e-06 -2.7724e-03 5.5023e-04 1.8296e-04 -6.0000e+00 2.4319e-02 -9.2908e-03 0.0000e+00 12 8 8 10 0 0 99.40 19.85 0.24 -0.00929 -0.03012 17 5 1 5 0 2809.680 24.65 20.00 19.85 11.11 22.8 913.86 132178 900000 291519 900000 900000 -121063 72751 38795 900000 -48128 900000 900000 900000 900000 -105517 900000 131369 900000 126918 183629 53649 900000 -8198 116149 900000 149401 900000 900000 900000 -20583 78801 55697 900000 28707 55610 134459 318328 900000 180855 900000 190658 62852 55605 28732 78458 107822 326800 68164 351932 107306 19987 40085 50221 38048 78489 105916 18134 31506 38129 21054 95177 41087 -2137 30804 1285 2428 16826 7165 5051 11500 13061 13337 15644 11884 15930 -15544 5656 -4740 17697 -4139 -121 9557 4091 9031 775 -2941 3444 22 3271 4585 -7002 149 -262 -10130 -10349 -5862 -4237 -7402 -1089 -4336 1333 818 -3074 -2393 -2741 -3201 -3210 531 -1531 -1605 -1206 -264 -4838 -3734 792 -2676 -828 -1095 3141 549 4387 3558 3907 4125 772 2864 -794 1176 3275 1358 863 692 1285 1913 -1882 -55 1094 1434 -1634 680 865 -3922 -2980 2512 900000 5540 900000 900000 -11001 1383 737 900000 -1799 900000 900000 900000 900000 -13599 900000 2497 900000 2498 3490 1934 900000 -447 2207 900000 2839 900000 900000 900000 -1093 1926 2079 900000 1599 2265 2555 6050 900000 3437 900000 3624 3498 3397 2222 3781 4023 6211 3794 6689 4608 2083 3757 4738 4139 6073 6255 2460 3593 3960 2472 5561 4323 -382 4522 273 508 2999 1446 1135 2751 3355 3514 3906 2835 3247 -3820 1042 -994 3387 -1193 -40 3307 1599 3682 349 -1448 1660 11 1608 2214 -3429 66 -113 -5045 -5717 -3687 -3114 -6560 -1012 -4266 1169 640 -2222 -1727 -2105 -2539 -2690 464 -1524 -1844 -1577 -374 -7162 -5401 1086 -3670 -1121 -1557 4531 843 6361 4936 5146 5263 987 3473 -968 1473 4635 2289 1594 1390 2732 4327 -4590 -140 2868 3777 -4273 1717 2018 -8816 -6281 SS 20231201T125816.6Z 8735.540470 290 1 47.07 2 81.74 128.42 59.07 277.70 0.00 1 0.00 1 0 17 5.441e-01 1.551e-02 3.066e-01 6.027e-03 7.730121e-01 3.273058e-03 8.879104e-03 -6.000000e+00 3.059924e-01 223.01 -2.00 3.51 -2.00 321.74 0.00e+00 1.169639e-02 1.770061e-03 2.449167e-03 -6.000000e+00 1.389652e-02 278.67 -2.00 20.00 -2.00 321.27 0.00e+00 6.533 0.005 302.00 328.00 3 1.8447e+00 1.1843e-02 7.6721e-02 -6.0000e+00 7.5255e-01 3.9914e-01 1.7236e-02 4.2652e-02 -6.0000e+00 8.2095e-01 -4.8668e-01 1.8353e-02 2.6723e-02 -6.0000e+00 4.8912e-01 1.9403e-01 8.5112e-03 1.4519e-02 -6.0000e+00 2.1065e-01 5.7630e-05 -1.6042e-03 1.6517e-04 1.9172e-04 -6.0000e+00 1.4973e-02 -8.9940e-03 0.0000e+00 12 8 8 10 0 0 98.53 19.86 0.28 -0.00899 -0.02105 67 19 1 5 0 702.410 24.75 20.00 19.86 11.40 22.9 916.00 900000 -116627 30017 -133480 900000 -293535 -193494 -129691 -77862 -212680 193732 69642 -137007 38240 -182333 179413 11163 -29325 -49864 -19087 -65606 2635 -20536 -60971 -14942 -36499 -20474 -3293 97095 -54874 -31809 23021 69259 1737 15911 19887 21995 54025 18501 22042 31796 9861 5054 -732 24048 24515 15905 14505 31617 16532 16205 11993 14594 17197 21082 23036 1837 6800 -2123 2270 12688 11255 5385 8296 5106 623 5919 3828 4005 5002 3882 4514 4928 4248 2008 5561 -1458 -1913 -1963 -1067 748 2210 -1591 2385 -1664 -1003 719 -1270 -526 -263 35 -552 -589 -1729 -2555 -2726 -1508 -1589 -613 -1021 -186 -661 -208 -2154 -1370 -1845 -1550 -473 -433 302 6 684 -302 -583 248 218 -117 -439 992 -242 1585 1483 1824 1406 119 -2557 -125 1342 696 495 445 444 140 -254 -222 -140 183 288 -635 125 -119 -542 -358 900000 -761 176 -1089 900000 -9530 -2463 -931 -457 -3887 1138 409 -1878 225 -6766 1054 91 -402 -911 -268 -1477 29 -288 -1333 -215 -667 -340 -46 570 -1379 -789 438 981 49 401 467 540 1120 622 842 1235 515 294 -47 1232 1296 955 933 1827 1203 1322 1151 1505 1875 2333 2579 258 899 -297 298 1553 1554 914 1573 1025 131 1238 805 931 1326 1149 1383 1480 1202 526 1327 -350 -475 -558 -345 283 951 -788 1208 -932 -593 439 -815 -335 -161 20 -298 -308 -957 -1625 -2054 -1257 -1540 -652 -1110 -189 -601 -178 -1851 -1247 -1704 -1509 -491 -499 395 8 1035 -470 -891 358 319 -173 -648 1529 -392 2485 2221 2735 2055 171 -3634 -168 1859 1112 872 875 941 301 -585 -549 -365 486 771 -1713 321 -287 -1216 -804 SS 20231201T130858.0Z 8735.547893 293 1 46.91 2 80.17 130.38 61.03 279.20 0.00 1 0.00 1 0 17 4.453e-01 7.478e-03 1.679e-01 2.507e-03 6.920509e-01 1.328716e-03 7.749735e-03 -6.000000e+00 2.503493e-01 223.01 -2.00 3.51 -2.00 321.31 0.00e+00 4.931083e-03 6.525075e-04 9.070903e-04 -6.000000e+00 1.129520e-02 278.67 -2.00 20.00 -2.00 320.80 0.00e+00 5.601 0.003 302.00 328.00 3 1.4543e+00 4.5078e-03 6.6246e-02 -6.0000e+00 6.1576e-01 8.7511e-02 6.4313e-03 3.7360e-02 -6.0000e+00 6.7141e-01 -9.9762e-02 6.9628e-03 2.1169e-02 -6.0000e+00 4.0017e-01 3.3575e-02 3.3081e-03 8.9653e-03 -6.0000e+00 1.7107e-01 2.3829e-04 -9.9606e-04 6.9483e-05 9.8059e-05 -6.0000e+00 1.2191e-02 -9.5105e-03 0.0000e+00 11 8 0 10 0 0 80.82 19.86 0.22 -0.00951 -0.01700 189 53 1 5 0 248.180 24.65 19.99 19.86 11.90 22.9 920.38 -55265 -196265 -51119 -174842 900000 -213165 -137865 -117742 -140054 -138338 -142323 -44435 -141765 3967 -127766 -18610 -36843 -26141 -50448 -28779 -17841 -39595 -15089 -49648 -5544 -52664 -9278 -33378 -6265 -36910 -11909 -2244 -5313 -3377 -16727 5481 -15392 12382 -5418 5506 -2592 1898 -3522 -3164 4439 1430 5560 -3075 8247 3895 4744 2282 6451 3412 5260 6156 -744 1010 -1159 3792 2388 5788 1992 5235 1293 2319 2163 1381 1749 731 1892 943 2038 -1334 1020 55 18 -2338 307 113 -1396 -549 -2176 -175 -1746 -781 -741 419 316 1077 406 310 680 -664 64 -580 204 -520 142 -525 -388 -708 -9 -539 -1458 -778 -1371 -104 -232 754 212 486 -29 229 -185 356 472 -15 509 -578 300 282 571 267 213 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