File name: Pandora135s1_ManhattanNY-CCNY_20231208_L2Fit_fout2c19d20211023p1-8.txt File generation date: 20250218T210131.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c19p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v19d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20231208_L1_smca1c19d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20231208 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231208T125329.8Z 8742.537151 200 1 46.89 2 83.57 127.65 50.27 174.37 0.00 1 0.00 1 0 17 9.706e-01 3.858e-02 3.334e-01 1.006e-02 7.126157e-01 5.621219e-03 9.680617e-03 -6.000000e+00 5.513241e-01 222.91 -2.00 3.51 -2.00 321.87 0.00e+00 4.092997e-02 3.009812e-03 9.663160e-04 -6.000000e+00 2.812937e-02 277.90 -2.00 20.00 -2.00 321.41 0.00e+00 8.082 0.010 302.00 328.00 3 9.4234e-01 2.0310e-02 9.7052e-02 -6.0000e+00 1.3631e+00 1.2147e+00 2.3471e-02 8.2066e-02 -6.0000e+00 1.4911e+00 -1.6034e+00 1.7453e-02 1.9535e-02 -6.0000e+00 8.8284e-01 6.8903e-01 8.8133e-03 3.3482e-02 -6.0000e+00 3.7963e-01 2.8949e-05 -3.8054e-03 2.8929e-04 4.4571e-04 -6.0000e+00 2.7645e-02 -1.0942e-02 0.0000e+00 12 8 8 10 0 0 87.04 19.74 0.28 -0.01094 -0.03954 55 16 1 5 0 852.460 24.56 20.00 19.74 11.58 23.0 918.84 240472 900000 214487 261026 900000 -106756 468491 73847 900000 43463 900000 243873 900000 900000 77239 900000 179329 322052 127240 322624 163679 900000 95773 154371 186899 70059 106652 900000 900000 32332 120134 71996 900000 80960 162354 95003 232073 224599 180496 100143 83091 83513 33326 94576 68825 114791 74424 101461 119285 125340 60995 58423 78695 50658 71588 50382 32084 21257 24798 24288 59947 39964 20718 34619 24741 35841 17973 21604 8251 16157 9125 16924 7888 1943 12363 9098 128 -13490 -1360 -5972 4660 1454 -1882 140 -2957 -5271 -1429 -3118 -2560 1132 -4782 633 -8349 -6734 -10100 -7319 -6302 -4053 -1089 -1273 1277 765 84 -4978 -3173 -5171 -3380 -2472 -1520 -1106 -1843 -673 -1655 -2427 -1201 -1927 -1667 388 883 1315 4167 4965 5533 3880 3045 -3610 2721 1892 2619 1294 2417 2061 1007 1310 -739 -739 -29 -3 -1422 473 -239 -1327 -2863 2354 900000 2799 2555 900000 -18263 4585 1446 900000 810 900000 2387 900000 900000 2520 900000 3072 3152 4047 3158 3284 900000 2812 2115 1829 1646 1618 900000 900000 1234 2410 2924 900000 3605 3094 3022 2271 2198 2789 3480 3538 3637 2512 4073 4008 4672 4516 4916 5285 5424 5074 5375 6239 5479 6236 5202 3784 2642 2840 2781 5075 4635 3376 5625 4795 6174 3580 4144 1831 3720 2454 4323 2143 520 2819 1906 27 -3340 -340 -1815 1520 561 -823 63 -1444 -2788 -766 -1763 -1451 604 -2543 296 -4062 -3292 -5766 -4847 -4943 -3493 -1026 -1243 1211 653 65 -3902 -2594 -4610 -3140 -2459 -1661 -1311 -2491 -976 -2476 -3581 -1670 -2602 -2262 544 1318 2056 6328 7203 7651 5298 4058 -4985 3417 2479 3875 2247 4643 4285 2136 2939 -1806 -1903 -76 -9 -3826 1208 -576 -2996 -6508 SS 20231208T130414.4Z 8742.544611 203 1 46.79 2 81.98 129.57 50.18 177.76 0.00 1 0.00 1 0 17 4.186e-01 1.298e-02 2.301e-01 3.649e-03 6.658629e-01 1.940564e-03 7.513713e-03 -6.000000e+00 2.349844e-01 222.91 -2.00 3.51 -2.00 321.45 0.00e+00 8.764481e-03 9.777653e-04 8.297764e-04 -6.000000e+00 1.069046e-02 277.90 -2.00 20.00 -2.00 320.96 0.00e+00 6.708 0.005 302.00 328.00 3 9.9484e-01 6.7226e-03 7.5311e-02 -6.0000e+00 5.7835e-01 2.1698e-01 9.4299e-03 3.7420e-02 -6.0000e+00 6.3062e-01 -2.3772e-01 1.0055e-02 2.1189e-02 -6.0000e+00 3.7653e-01 9.2506e-02 4.7691e-03 1.2102e-02 -6.0000e+00 1.6238e-01 1.3517e-04 -1.0884e-03 1.0427e-04 1.3219e-04 -6.0000e+00 1.1498e-02 -1.1205e-02 0.0000e+00 12 8 8 10 0 0 75.18 19.75 0.31 -0.01121 -0.01938 141 40 1 5 0 331.740 24.65 20.00 19.75 12.62 23.0 925.99 -152392 900000 -139043 900000 -96708 -300726 -150001 138911 -67754 -127472 19758 -44164 59222 -58168 -19851 -9837 108470 -37980 -200 -17986 1561 -15333 2631 -8974 -23978 -23748 -14320 23135 -17128 -18074 -22897 -3772 12257 2614 3956 75 13348 8006 21019 6184 20929 -4226 10650 -3217 13126 6296 8598 8986 8674 18734 5488 14013 8361 12447 5375 10390 -248 -53 5180 305 8407 3269 4789 5314 5159 2082 4607 958 4042 2619 1963 2840 1270 1100 -349 3433 -4375 -678 -1623 663 -1238 -1265 -1670 -1631 -1710 -1904 1092 -324 446 -150 387 -859 -838 -1278 -1541 -766 -994 371 -429 181 -518 111 -359 -467 -1054 -1198 -937 -777 -147 29 -163 20 -95 -661 196 -114 118 354 274 58 572 1173 653 1040 285 -880 353 805 572 402 259 497 158 -740 -355 -66 308 390 -155 -196 -199 -387 -364 -1295 900000 -1346 900000 -554 -11992 -1453 494 -348 -1260 70 -227 211 -598 -180 -99 386 -653 -3 -291 21 -245 36 -145 -479 -493 -275 320 -338 -396 -638 -107 346 88 127 2 414 309 864 350 1150 -323 745 -269 957 509 703 765 782 1640 610 1606 1117 1732 804 1533 -42 -9 843 52 1361 585 970 1218 1266 522 1107 246 1110 840 702 1054 474 389 -115 974 -1252 -190 -517 247 -555 -651 -904 -939 -1050 -1250 735 -229 313 -102 246 -517 -510 -804 -1038 -598 -907 366 -471 200 -543 109 -322 -418 -1018 -1233 -1016 -902 -178 39 -248 32 -148 -1058 295 -164 171 536 441 93 911 1875 1009 1555 414 -1248 477 1126 907 695 496 1013 341 -1636 -838 -165 782 1005 -386 -491 -470 -857 -813 SS 20231208T131446.9Z 8742.551932 206 1 46.85 2 80.47 131.49 50.20 181.09 0.00 1 0.00 1 0 17 2.689e-01 7.252e-03 1.142e-01 1.910e-03 5.942985e-01 9.916682e-04 6.834314e-03 -6.000000e+00 1.509745e-01 222.91 -2.00 3.51 -2.00 320.95 0.00e+00 4.574676e-03 4.366306e-04 1.155983e-03 -6.000000e+00 6.681996e-03 277.90 -2.00 20.00 -2.00 320.43 0.00e+00 5.756 0.003 302.00 328.00 3 9.3013e-01 3.2003e-03 6.4781e-02 -6.0000e+00 3.7160e-01 9.0520e-02 4.2531e-03 3.1627e-02 -6.0000e+00 4.0518e-01 -7.9981e-02 4.3564e-03 1.8003e-02 -6.0000e+00 2.4159e-01 2.6625e-02 2.1346e-03 7.6429e-03 -6.0000e+00 1.0321e-01 3.8857e-04 -7.6186e-04 5.4334e-05 9.0104e-05 -6.0000e+00 7.2922e-03 -1.1593e-02 0.0000e+00 11 8 0 10 0 0 12.84 19.76 0.23 -0.01159 -0.01732 274 77 1 5 0 170.930 24.65 20.01 19.76 13.61 23.1 932.54 -10359 -73856 8799 -96987 24538 -205052 -74436 -84678 -64317 -63320 -68180 -14684 -60947 -5148 -42826 -3495 -8231 -7176 -19914 -9215 -12568 -18313 -78100 -22206 1347 -23074 -1239 -15096 -2905 -19302 -8668 -2110 4664 1735 -8209 -945 -7151 5939 1208 4596 103 -293 -384 -878 2839 2406 5975 1897 4362 3245 4298 4236 4127 3676 2621 3077 343 -428 -1164 908 1503 4477 1074 3998 1399 1464 1512 1362 1687 1205 1083 224 922 -403 630 -615 -840 -1415 -802 -299 -1154 -1234 -2313 -1168 -1292 -689 -382 74 -21 681 232 398 307 -120 31 -232 534 424 36 -323 -392 -761 -32 -397 -1175 -926 -945 -220 -52 590 -42 406 -80 85 -233 444 333 365 297 -159 168 354 473 293 383 -632 301 687 179 142 -401 162 -255 -315 -293 -33 375 257 -217 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