File name: Pandora135s1_ManhattanNY-CCNY_20231222_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T185059.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20231222_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20231222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231222T130409.9Z 8756.544559 151 1 45.80 2 83.52 128.83 125.44 359.79 0.00 1 0.00 1 0 33 9.323e-01 5.766e-02 3.597e-01 2.119e-02 9.256379e-01 1.253767e-02 1.120412e-02 -6.000000e+00 5.433002e-01 223.00 -2.00 3.51 -2.00 322.04 0.00e+00 3.288369e-02 6.113700e-03 2.378629e-03 -6.000000e+00 3.090002e-02 276.69 -2.00 20.00 -2.00 321.62 0.00e+00 8.037 0.009 302.00 328.00 3 1.7081e+00 4.4345e-02 1.0230e-01 -6.0000e+00 1.3462e+00 1.8186e+00 4.9902e-02 8.5727e-02 -6.0000e+00 1.4810e+00 -2.2008e+00 3.1967e-02 2.3496e-02 -6.0000e+00 8.6966e-01 9.0692e-01 1.7565e-02 2.8274e-02 -6.0000e+00 3.7542e-01 9.2453e-06 -4.3039e-03 5.7465e-04 3.8650e-04 -6.0000e+00 2.7872e-02 -2.2507e-02 0.0000e+00 12 8 8 10 0 0 95.37 18.93 0.20 -0.02251 -0.05485 20 6 1 5 0 2289.310 23.93 19.99 18.93 1.62 22.0 849.38 900000 569051 900000 106829 900000 -77265 900000 321140 900000 81185 900000 900000 77234 900000 -7779 900000 83481 900000 57305 900000 145147 900000 81128 52877 900000 -9077 900000 138928 900000 -8452 282666 129490 900000 239946 87004 900000 64601 900000 124669 900000 70857 277611 15761 33169 71722 58452 258224 70025 900000 47057 179933 16317 176655 33391 141750 115979 -8706 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-877 -6568 -1776 -9157 -921 -11407 2578 -6658 3136 1870 1543 -4100 -4884 -2228 -9423 4979 -7113 2931 -3669 4033 -10030 -1772 734 -4783 -4778 -2769 11375 -3139 14721 5746 13548 4937 8825 -20406 3381 2917 2986 5897 2569 7778 -726 6023 -8961 2368 -1927 4218 -6890 1660 4481 -9285 -2540 SS 20231222T131501.4Z 8756.552099 154 1 47.14 2 81.95 130.77 125.35 2.88 0.00 1 0.00 1 0 17 5.454e-01 2.348e-02 3.503e-01 8.323e-03 8.598181e-01 4.747181e-03 9.740766e-03 -6.000000e+00 3.136236e-01 223.00 -2.00 3.51 -2.00 321.91 0.00e+00 2.109863e-02 2.562792e-03 2.275933e-03 -6.000000e+00 1.561914e-02 276.69 -2.00 20.00 -2.00 321.48 0.00e+00 6.683 0.005 302.00 328.00 3 2.0063e+00 1.7191e-02 8.6222e-02 -6.0000e+00 7.7505e-01 8.3358e-01 2.4113e-02 6.7748e-02 -6.0000e+00 8.4890e-01 -1.0269e+00 2.4851e-02 2.5839e-02 -6.0000e+00 4.9919e-01 4.2493e-01 1.1594e-02 2.2584e-02 -6.0000e+00 2.1376e-01 3.3888e-05 -2.2226e-03 2.2623e-04 2.4283e-04 -6.0000e+00 1.5892e-02 -2.2370e-02 0.0000e+00 12 8 8 10 0 0 92.25 18.93 0.32 -0.02237 -0.03907 49 14 1 5 0 961.800 23.93 20.00 18.93 1.87 22.0 850.86 900000 -84579 203517 -84341 900000 -256999 32581 900000 900000 124930 -8714 900000 32325 159044 -103203 900000 88763 153111 83555 88678 900000 3169 900000 -75342 900000 -71104 900000 166605 143257 -54751 17343 105112 119555 48657 -4208 900000 31773 900000 79331 76236 47426 -4393 42407 -3774 69964 25050 108057 37569 88623 33496 45414 26217 39815 32239 38689 38264 3891 26375 12671 19367 17132 27025 2099 20824 6082 10912 10017 7596 10563 4666 7499 8103 10351 1863 6914 16944 1124 3650 -4062 2439 -455 5163 -5129 5646 -2971 -2936 -594 533 -114 1212 -505 -1128 2751 -6050 -4533 -5800 -2357 -412 -1022 -1999 212 -365 -1881 -2722 -2371 -2384 -2505 228 -2775 719 -1549 321 -1284 -828 842 -1216 -598 -1199 1575 194 2417 2581 2369 2363 1674 -3095 86 1419 834 1840 295 1638 391 191 -744 -32 347 157 -797 -186 591 -1536 -1034 900000 -1181 1648 -1201 900000 -15054 264 900000 900000 1012 -71 900000 262 1288 -3228 900000 719 1240 752 771 900000 57 900000 -2702 900000 -2303 900000 1349 1160 -1694 343 1103 1291 1153 -156 900000 810 900000 1618 1829 1664 -266 1755 -249 2350 1319 2690 2006 3030 2063 2745 2146 3109 2909 3402 3408 486 2555 1345 1871 1739 2751 319 3053 1097 1901 1751 1404 2071 1109 1910 2129 2601 473 1496 3043 220 718 -957 659 -152 1900 -2250 2445 -1429 -1490 -309 282 -61 639 -254 -534 1214 -3039 -2565 -3846 -1805 -363 -989 -2017 205 -316 -1458 -2045 -1873 -2003 -2225 213 -2976 831 -2098 468 -1966 -1249 1200 -1705 -835 -1761 2381 308 3699 3740 3266 3157 2180 -4094 110 1869 1231 3150 562 3350 836 437 -1841 -82 914 418 -2069 -476 1388 -3490 -2205 SS 20231222T132540.9Z 8756.559501 157 1 47.15 2 80.44 132.72 125.16 5.89 0.00 1 0.00 1 0 17 5.287e-01 1.204e-02 2.573e-01 4.353e-03 7.757456e-01 2.346359e-03 8.786660e-03 -6.000000e+00 2.992605e-01 223.00 -2.00 3.51 -2.00 321.49 0.00e+00 8.752097e-03 1.178072e-03 1.651376e-03 -6.000000e+00 1.317739e-02 276.69 -2.00 20.00 -2.00 321.02 0.00e+00 5.742 0.003 302.00 328.00 3 2.1820e+00 8.0098e-03 7.0131e-02 -6.0000e+00 7.3823e-01 2.8428e-01 1.1744e-02 4.2388e-02 -6.0000e+00 8.0512e-01 -2.9301e-01 1.3005e-02 2.6124e-02 -6.0000e+00 4.7786e-01 1.1156e-01 6.1171e-03 1.3333e-02 -6.0000e+00 2.0464e-01 8.5097e-05 -1.1906e-03 1.1555e-04 1.5619e-04 -6.0000e+00 1.4573e-02 -2.2858e-02 0.0000e+00 12 8 8 10 0 0 78.34 18.94 0.15 -0.02286 -0.03180 64 18 1 5 0 736.670 23.83 20.01 18.94 1.94 22.0 851.50 -176273 900000 -193669 -59223 -94002 -282916 -251723 900000 -87472 -177645 149916 -139982 100648 -43387 -82371 -31444 27619 -45698 -23222 -36292 -21792 -41790 -148424 -54165 -15988 -31688 -20875 63679 -35800 -31904 -35983 12324 43790 -7178 -8402 9708 13050 10025 39543 3424 28940 -11254 3648 -5894 16941 11174 15923 12331 16134 22709 3944 14692 8198 11745 13640 12531 253 4096 4394 1152 10668 4887 4777 5298 4220 1447 6940 365 2665 1679 1662 2493 757 2171 -504 3693 -3564 -1616 -3088 -282 -1089 900 -2512 -77 -1147 -1144 1133 -1016 -291 410 210 -725 -248 -797 -824 -760 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