File name: Pandora135s1_ManhattanNY-CCNY_20240107_L2Fit_fnvs5c16d20211023p1-8.txt File generation date: 20241024T184759.7Z Data description: Level 2 spectral fitting results file Data file version: fnvs5c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240107_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240107 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 929 1474 Nominal wavelengths inside fitting window [nm]: 400.0632 400.1954 400.3276 400.4598 400.5919 400.7241 400.8562 400.9883 401.1204 401.2525 401.3846 401.5166 401.6487 401.7807 401.9127 402.0448 402.1767 402.3087 402.4407 402.5726 402.7046 402.8365 402.9684 403.1003 403.2322 403.3640 403.4959 403.6277 403.7595 403.8913 404.0231 404.1549 404.2867 404.4184 404.5502 404.6819 404.8136 404.9453 405.0770 405.2087 405.3403 405.4720 405.6036 405.7352 405.8668 405.9984 406.1299 406.2615 406.3930 406.5246 406.6561 406.7876 406.9191 407.0505 407.1820 407.3134 407.4449 407.5763 407.7077 407.8391 407.9704 408.1018 408.2331 408.3645 408.4958 408.6271 408.7584 408.8896 409.0209 409.1521 409.2834 409.4146 409.5458 409.6770 409.8082 409.9393 410.0705 410.2016 410.3327 410.4638 410.5949 410.7260 410.8570 410.9881 411.1191 411.2501 411.3811 411.5121 411.6431 411.7740 411.9050 412.0359 412.1668 412.2977 412.4286 412.5595 412.6904 412.8212 412.9520 413.0828 413.2136 413.3444 413.4752 413.6060 413.7367 413.8674 413.9982 414.1289 414.2596 414.3902 414.5209 414.6515 414.7822 414.9128 415.0434 415.1740 415.3045 415.4351 415.5656 415.6962 415.8267 415.9572 416.0877 416.2181 416.3486 416.4790 416.6095 416.7399 416.8703 417.0007 417.1310 417.2614 417.3917 417.5221 417.6524 417.7827 417.9130 418.0432 418.1735 418.3037 418.4340 418.5642 418.6944 418.8246 418.9547 419.0849 419.2150 419.3451 419.4752 419.6053 419.7354 419.8655 419.9955 420.1256 420.2556 420.3856 420.5156 420.6456 420.7756 420.9055 421.0354 421.1654 421.2953 421.4252 421.5550 421.6849 421.8148 421.9446 422.0744 422.2042 422.3340 422.4638 422.5935 422.7233 422.8530 422.9827 423.1124 423.2421 423.3718 423.5015 423.6311 423.7607 423.8904 424.0200 424.1495 424.2791 424.4087 424.5382 424.6677 424.7973 424.9268 425.0562 425.1857 425.3152 425.4446 425.5740 425.7034 425.8328 425.9622 426.0916 426.2209 426.3503 426.4796 426.6089 426.7382 426.8675 426.9967 427.1260 427.2552 427.3844 427.5136 427.6428 427.7720 427.9012 428.0303 428.1594 428.2886 428.4177 428.5467 428.6758 428.8049 428.9339 429.0629 429.1920 429.3210 429.4499 429.5789 429.7079 429.8368 429.9657 430.0946 430.2235 430.3524 430.4813 430.6101 430.7390 430.8678 430.9966 431.1254 431.2541 431.3829 431.5117 431.6404 431.7691 431.8978 432.0265 432.1552 432.2838 432.4125 432.5411 432.6697 432.7983 432.9269 433.0554 433.1840 433.3125 433.4411 433.5696 433.6981 433.8265 433.9550 434.0835 434.2119 434.3403 434.4687 434.5971 434.7255 434.8538 434.9822 435.1105 435.2388 435.3671 435.4954 435.6237 435.7519 435.8802 436.0084 436.1366 436.2648 436.3930 436.5211 436.6493 436.7774 436.9055 437.0336 437.1617 437.2898 437.4179 437.5459 437.6739 437.8019 437.9299 438.0579 438.1859 438.3138 438.4418 438.5697 438.6976 438.8255 438.9534 439.0813 439.2091 439.3369 439.4648 439.5926 439.7203 439.8481 439.9759 440.1036 440.2313 440.3591 440.4868 440.6144 440.7421 440.8698 440.9974 441.1250 441.2526 441.3802 441.5078 441.6353 441.7629 441.8904 442.0179 442.1454 442.2729 442.4004 442.5279 442.6553 442.7827 442.9101 443.0375 443.1649 443.2923 443.4196 443.5469 443.6743 443.8016 443.9289 444.0561 444.1834 444.3106 444.4379 444.5651 444.6923 444.8194 444.9466 445.0738 445.2009 445.3280 445.4551 445.5822 445.7093 445.8363 445.9634 446.0904 446.2174 446.3444 446.4714 446.5984 446.7253 446.8523 446.9792 447.1061 447.2330 447.3599 447.4867 447.6136 447.7404 447.8672 447.9940 448.1208 448.2476 448.3743 448.5010 448.6278 448.7545 448.8812 449.0078 449.1345 449.2611 449.3878 449.5144 449.6410 449.7676 449.8941 450.0207 450.1472 450.2737 450.4003 450.5267 450.6532 450.7797 450.9061 451.0326 451.1590 451.2854 451.4117 451.5381 451.6645 451.7908 451.9171 452.0434 452.1697 452.2960 452.4223 452.5485 452.6747 452.8009 452.9271 453.0533 453.1795 453.3056 453.4318 453.5579 453.6840 453.8101 453.9362 454.0622 454.1883 454.3143 454.4403 454.5663 454.6923 454.8182 454.9442 455.0701 455.1960 455.3219 455.4478 455.5737 455.6995 455.8254 455.9512 456.0770 456.2028 456.3286 456.4543 456.5801 456.7058 456.8315 456.9572 457.0829 457.2086 457.3342 457.4599 457.5855 457.7111 457.8367 457.9623 458.0878 458.2134 458.3389 458.4644 458.5899 458.7154 458.8408 458.9663 459.0917 459.2171 459.3425 459.4679 459.5933 459.7187 459.8440 459.9693 460.0946 460.2199 460.3452 460.4704 460.5957 460.7209 460.8461 460.9713 461.0965 461.2217 461.3468 461.4720 461.5971 461.7222 461.8473 461.9723 462.0974 462.2224 462.3474 462.4725 462.5974 462.7224 462.8474 462.9723 463.0973 463.2222 463.3471 463.4719 463.5968 463.7217 463.8465 463.9713 464.0961 464.2209 464.3457 464.4704 464.5952 464.7199 464.8446 464.9693 465.0939 465.2186 465.3433 465.4679 465.5925 465.7171 465.8417 465.9662 466.0908 466.2153 466.3398 466.4643 466.5888 466.7133 466.8377 466.9622 467.0866 467.2110 467.3354 467.4597 467.5841 467.7084 467.8328 467.9571 468.0814 468.2056 468.3299 468.4541 468.5784 468.7026 468.8268 468.9509 469.0751 469.1993 469.3234 469.4475 469.5716 469.6957 469.8198 469.9438 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Temperature at electronics board [°C], 999=no temperature signal Column 159: Spectrometer control temperature [°C], 999=no temperature signal Column 160: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 161: Temperature in head sensor [°C], 999=no temperature signal Column 162: Humidity in head sensor [%], -9=no humidity signal Column 163: Pressure in head sensor [hPa], -9=no pressure signal Columns 164-709: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 710-1255: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240107T174313.1Z 8772.738346 340 1 4.62 2 63.91 190.62 87.57 235.80 0.00 1 0.00 1 0 33 2.714e-03 2.666e-03 2.627e-03 2.571e-03 6.291477e+02 4.766010e+02 6.531537e+01 3.679957e+02 5.288184e+02 275.71 -2.00 20.00 -2.00 445.34 0.00e+00 5.201934e-05 2.818157e-04 3.034631e-06 1.475841e-05 2.938438e-04 275.71 -2.00 20.00 -2.00 454.53 0.00e+00 2.300798e-04 2.270051e-05 1.557619e-06 1.303799e-05 2.448465e-05 227.24 -2.00 2.16 -2.00 435.89 0.00e+00 2.067516e+05 3.503889e+05 1.743491e+04 2.305805e+05 3.890830e+05 257.80 -2.00 11.21 -2.00 456.82 0.00e+00 4.083487e-01 7.262644e-02 1.050052e-03 9.320094e-03 8.437949e-02 223.51 -2.00 3.51 -2.00 453.91 0.00e+00 1.250877e-06 8.984474e-06 1.581507e-07 1.150972e-06 1.033297e-05 275.71 -2.00 20.00 -2.00 455.06 0.00e+00 2.260 0.000 397.00 473.00 4 7.1345e+00 2.6939e-03 5.7262e-03 3.9333e-04 2.7465e-03 4.3141e-02 3.2468e-03 1.1962e-03 2.3149e-04 3.3955e-03 -2.9006e-03 1.8635e-03 1.5803e-04 9.4221e-05 1.9419e-03 1.6680e-03 6.2383e-04 1.8697e-05 2.3868e-05 6.5245e-04 -1.1626e-04 3.2065e-04 3.6442e-06 1.4005e-05 3.2846e-04 8.8823e-04 5.9033e-03 1.7344e-03 9.2631e-06 3.3188e-05 1.6075e-03 -8.9333e-05 2.5589e-05 1.5344e-07 3.0798e-07 2.6666e-05 -3.1798e-05 3.5577e-05 1.3197e-07 3.6540e-07 3.5829e-05 -2.2439e-02 -3.3549e-06 8.8501e-01 2.5365e-01 8.3996e-04 1.6300e-03 2.4977e-01 12 9 9 12 1 1 999.00 19.44 0.78 -0.02244 -0.02170 2 8 1 4 0 1538.770 24.35 19.99 19.44 6.55 22.6 886.11 142 -394 80 -184 503 336 -186 21 286 32 -200 305 -345 88 -40 38 -17 333 -280 -359 -396 432 251 -391 -200 -305 365 -547 187 303 727 462 39 -91 119 -109 -286 310 -288 576 232 141 -240 13 485 20 -130 -567 286 -355 12 -197 11 -351 -277 -103 -143 -329 111 56 -255 -227 -309 231 -81 -368 -53 -21 263 45 -279 270 402 -245 49 -642 -237 -132 107 675 -180 545 -207 409 -506 -385 120 326 -256 408 28 -69 -28 -167 399 -269 -195 -61 -82 -589 89 120 -21 -197 160 -54 -107 88 -84 82 -150 55 -312 369 32 169 -162 -406 234 -118 394 -2 365 -402 -16 -313 586 -420 -43 163 -8 40 481 -262 -12 648 -30 -79 -346 -24 387 -150 543 -305 12 -241 633 -233 -139 -252 -229 -176 -395 357 107 -66 -530 -210 -15 207 135 42 68 329 547 -12 643 63 243 119 39 -45 -108 -123 -267 94 -152 348 -207 714 155 -286 -188 -239 -162 256 123 276 237 -221 -64 52 662 -794 561 -184 -241 102 5 6 -306 -76 -231 728 -411 346 347 -377 146 258 664 -319 -373 -676 -33 36 303 -294 273 -273 -166 81 62 -54 -710 163 -344 157 -301 -17 -1 257 -177 141 384 -411 132 -303 469 16 -109 -226 510 -194 406 517 -106 -20 -17 182 114 254 143 244 157 -28 185 -36 47 -205 149 -104 -471 -222 -101 -19 149 -139 -488 195 -554 -231 -137 -43 223 201 -247 -256 -15 -311 -335 91 77 171 222 -61 -80 289 -103 -66 -324 337 -239 -27 -397 26 579 489 362 -180 175 -259 118 20 -321 -40 -172 -58 240 -32 -135 272 -324 -207 -79 373 -79 504 -132 251 263 322 -263 216 -275 198 -111 157 -26 39 -40 -243 -491 -524 -270 -164 -201 -227 -113 281 103 -174 -182 90 420 -137 383 41 -356 417 266 -167 320 9 -62 -280 149 38 -82 153 -188 244 -298 -32 -383 135 -247 443 -102 -12 83 474 84 -418 -168 -184 -246 89 533 -444 -79 -4 -259 -83 147 115 -82 -53 99 130 -79 -142 -269 -100 222 62 -310 60 -271 -135 -231 -50 -187 -228 6 -70 -202 489 223 -90 -172 549 15 321 -67 369 -93 380 -312 324 88 215 -66 342 -129 -20 279 75 333 -71 -21 -160 -58 450 -10 -254 -62 148 94 118 -208 170 534 -163 -199 -207 241 -455 -61 -134 414 77 240 51 -106 -140 23 434 99 154 -293 -67 -67 142 192 -239 53 269 -194 -455 511 -56 88 83 62 55 101 199 171 342 -265 37 64 245 -676 34 -34 244 -625 -123 155 -88 -196 -118 -202 -76 -53 251 -119 -29 -307 457 -34 -58 46 -197 80 -65 39 -157 -132 -122 -27 -439 -338 435 -122 -213 331 -288 276 -370 119 82 7 153 -188 -145 123 445 131 116 75 -189 -212 -462 -57 76 152 -221 448 234 -33 137 -36 169 120 -323 67 -147 393 264 -152 18 237 26 -168 253 -287 73 -34 32 -14 280 -238 -308 -342 365 214 -319 -155 -239 298 -481 162 268 639 398 33 -75 95 -87 -234 274 -251 517 204 120 -200 11 405 17 -107 -456 235 -290 10 -171 10 -300 -238 -87 -121 -275 95 46 -219 -205 -284 210 -73 -341 -49 -20 245 42 -253 248 361 -214 43 -530 -184 -106 84 571 -157 491 -190 375 -474 -369 112 310 -243 380 26 -66 -27 -155 386 -260 -187 -58 -76 -539 79 107 -19 -189 152 -52 -104 85 -78 75 -138 53 -291 361 31 162 -153 -380 215 -110 376 -2 350 -397 -16 -308 560 -400 -43 156 -7 37 430 -238 -12 609 -29 -75 -331 -23 365 -140 503 -286 12 -237 603 -223 -137 -240 -208 -156 -368 317 98 -63 -528 -205 -15 204 134 42 67 316 541 -12 638 62 241 116 38 -41 -91 -105 -244 90 -147 337 -205 675 145 -267 -178 -234 -161 247 120 266 235 -210 -59 48 622 -768 548 -182 -236 97 5 6 -291 -76 -232 722 -402 334 310 -340 127 228 593 -306 -351 -644 -33 35 293 -283 259 -253 -148 75 55 -48 -659 151 -310 138 -259 -14 -1 196 -139 111 295 -327 102 -238 368 13 -97 -226 523 -201 425 527 -107 -19 -15 164 102 248 143 256 158 -28 193 -37 46 -182 128 -89 -423 -205 -96 -19 154 -145 -496 191 -535 -221 -135 -44 229 209 -249 -261 -15 -330 -353 95 78 171 231 -63 -80 286 -102 -67 -336 350 -241 -27 -358 23 517 467 348 -178 173 -260 119 20 -321 -41 -173 -58 246 -32 -131 261 -313 -206 -79 386 -85 537 -138 256 266 333 -284 226 -287 212 -118 166 -27 40 -41 -251 -500 -547 -278 -170 -212 -235 -119 291 105 -176 -186 94 444 -147 406 44 -371 436 269 -165 310 8 -61 -280 151 40 -83 158 -194 249 -309 -34 -412 148 -263 472 -109 -13 87 484 86 -442 -184 -204 -270 96 565 -475 -85 -4 -279 -89 161 122 -87 -57 108 144 -89 -160 -303 -112 246 68 -340 65 -290 -145 -249 -54 -203 -247 6 -76 -214 501 224 -90 -173 555 15 330 -71 398 -99 409 -339 347 94 239 -73 370 -138 -21 296 80 358 -77 -23 -179 -63 496 -11 -282 -67 166 105 127 -227 186 582 -179 -219 -230 269 -508 -66 -149 451 83 258 56 -116 -157 26 491 112 173 -327 -74 -74 157 212 -265 59 299 -217 -516 580 -62 98 93 69 61 116 229 197 394 -294 41 71 274 -763 38 -38 273 -704 -138 181 -103 -229 -136 -232 -87 -60 283 -136 -33 -351 511 -38 -63 50 -218 89 -74 44 -178 -150 -140 -32 -521 -400 506 -140 -236 353 -318 302 -396 130 92 8 176 -216 -167 140 496 146 129 85 -216 -245 -536 -65 87 173 -253 512 270 -38 157 -41 187 SQ 20240107T184036.9Z 8772.778205 379 1 9.03 2 67.21 204.74 96.77 244.66 0.00 1 0.00 1 0 33 9.340e-04 9.155e-04 8.410e-04 8.220e-04 8.701189e+02 1.512258e+02 8.013369e+01 3.679957e+02 1.819988e+02 275.70 -2.00 20.00 -2.00 445.48 0.00e+00 4.925543e-05 9.017242e-05 1.965236e-06 1.482861e-05 1.009510e-04 275.70 -2.00 20.00 -2.00 454.60 0.00e+00 2.905519e-04 7.260067e-06 1.976558e-06 1.304441e-05 8.430309e-06 227.40 -2.00 2.16 -2.00 436.13 0.00e+00 1.958686e+05 1.111520e+05 1.327249e+04 2.305778e+05 1.339020e+05 257.80 -2.00 11.21 -2.00 456.83 0.00e+00 4.119146e-01 2.316513e-02 1.657423e-03 9.310837e-03 2.902759e-02 223.51 -2.00 3.51 -2.00 453.96 0.00e+00 -7.875693e-10 2.873310e-06 1.860940e-07 1.151893e-06 3.555827e-06 275.70 -2.00 20.00 -2.00 455.09 0.00e+00 2.561 0.000 397.00 473.00 4 5.8446e+00 8.5795e-04 6.4875e-03 3.9455e-04 9.4486e-04 3.3788e-02 1.0447e-03 1.3546e-03 2.3281e-04 1.1726e-03 1.1876e-04 5.9299e-04 1.7820e-04 9.4227e-05 6.6401e-04 1.5921e-03 1.9979e-04 1.9950e-05 2.3998e-05 2.2466e-04 -3.4885e-04 1.0279e-04 3.7814e-06 1.4066e-05 1.1302e-04 2.9933e-03 3.1023e-03 5.4298e-04 8.5213e-06 3.1923e-05 5.4786e-04 -1.0990e-04 8.1015e-06 1.7792e-07 3.0776e-07 9.1765e-06 -1.4141e-05 1.1315e-05 1.7231e-07 3.7020e-07 1.2331e-05 -1.9170e-02 -2.7442e-05 3.3914e-01 8.1118e-02 8.0642e-04 1.6186e-03 8.6149e-02 12 1 1 12 1 1 98.78 19.47 0.83 -0.01917 -0.02038 14 22 1 4 0 600.720 24.35 20.00 19.47 7.50 22.7 893.41 72 -64 72 100 -85 -66 73 -72 -24 53 -132 -54 52 -13 108 152 -20 25 -148 -90 134 -53 10 137 1 -195 51 113 13 120 168 4 -52 160 47 -117 93 -66 -23 54 111 204 -90 43 9 43 -80 154 -32 13 46 -74 -107 51 -124 -2 -41 -218 110 -33 -27 -44 -103 43 144 125 100 135 29 118 -74 -9 -170 -89 -37 -227 -38 -113 17 -72 -49 12 -141 30 -5 -128 20 -59 27 41 -48 -1 -55 -139 -89 -295 -136 20 31 -249 60 -103 -71 -191 -38 68 148 -146 79 -73 -189 -47 65 195 -22 81 -53 -8 -8 -3 144 310 130 31 -86 -155 -89 39 97 -167 -45 -118 -47 -57 -175 61 -11 -28 64 130 -122 -78 -93 -89 93 -60 -24 118 -89 -291 43 -96 89 87 -79 -9 38 -20 -124 76 87 213 -158 -20 -36 204 111 65 91 113 0 132 138 133 70 -122 -66 138 104 113 38 34 51 24 77 75 31 115 -2 30 -16 140 -26 42 -81 36 53 101 138 49 -113 105 38 214 227 46 16 138 -86 30 -55 -1 22 59 -47 79 22 -125 260 -162 -22 -6 61 80 -124 -25 60 110 -113 46 186 241 102 117 -7 -27 60 -6 13 -146 -33 -18 151 -29 59 -176 116 -139 96 -97 40 -19 -48 120 46 82 -43 -47 -105 -104 -54 -108 -130 -160 44 13 9 -162 97 -38 -32 100 -72 -22 -12 -120 43 -152 -41 -30 -88 20 -184 -93 -68 -107 -145 36 16 -55 -19 -42 24 -181 -41 -9 -95 7 100 -3 117 -87 31 -5 153 -122 -46 41 28 -133 -165 88 -102 -19 -111 39 35 -13 29 93 65 -105 34 -125 -136 -48 -70 171 -141 -26 72 28 -84 -97 26 -75 52 -46 14 46 -2 75 65 -34 5 64 -82 205 -83 30 76 0 41 11 33 40 103 -127 103 -11 172 -67 -85 -16 12 -103 35 34 -37 -47 18 -73 62 28 -53 -4 165 14 101 -102 78 77 8 -131 31 41 -9 -83 57 -64 -37 -167 -9 146 114 127 -164 -57 -81 -12 -61 97 -87 13 -124 -61 164 -101 167 -52 16 -37 46 67 65 89 27 28 69 36 -58 6 -59 65 32 -52 94 60 -21 -77 166 -61 64 55 137 -64 -89 -38 -71 90 122 -18 27 -42 41 10 -106 83 65 3 3 -83 -161 -232 -76 5 46 -25 12 209 -74 -44 105 -42 -220 52 -63 162 53 33 -15 -41 59 -32 29 -53 -34 -3 176 -5 -46 47 52 7 -83 -6 20 12 6 35 -105 48 -2 63 -15 -4 35 -138 63 -74 34 17 16 -44 60 2 112 7 2 -132 -55 9 72 106 -10 111 124 53 -146 -46 -9 66 -150 -102 81 -126 56 47 -10 32 -148 -83 -24 -89 51 8 86 63 159 34 -55 -25 -29 -40 -17 -78 59 -51 58 78 -65 -51 58 -61 -20 44 -109 -45 42 -11 89 127 -17 21 -124 -76 114 -44 8 110 1 -157 41 97 11 105 147 3 -43 129 36 -92 75 -55 -20 46 96 172 -74 35 7 36 -65 127 -26 11 39 -63 -92 43 -105 -2 -35 -180 93 -28 -23 -39 -90 39 129 110 91 126 27 109 -67 -8 -153 -77 -32 -184 -31 -89 14 -61 -42 11 -129 27 -4 -117 19 -56 26 39 -44 -1 -50 -130 -83 -273 -124 18 29 -227 53 -92 -65 -175 -36 65 144 -137 74 -66 -174 -43 61 183 -21 74 -50 -7 -7 -3 132 293 127 31 -83 -155 -87 38 92 -155 -42 -108 -43 -52 -163 56 -10 -26 59 119 -112 -73 -87 -83 88 -57 -24 115 -85 -268 39 -86 79 78 -74 -8 36 -20 -125 76 88 216 -159 -20 -35 194 108 65 92 112 0 121 117 114 64 -114 -65 137 100 109 36 32 49 23 75 74 31 114 -2 28 -15 132 -25 40 -78 35 50 94 130 46 -105 103 37 210 227 44 15 125 -76 27 -51 -1 21 58 -45 75 20 -118 241 -154 -20 -5 55 74 -118 -24 55 98 -98 37 150 194 81 93 -6 -21 46 -4 11 -123 -30 -17 154 -30 62 -181 117 -132 87 -85 37 -18 -48 126 47 83 -45 -47 -101 -95 -47 -94 -114 -146 43 13 10 -169 97 -37 -31 99 -71 -23 -12 -120 43 -156 -43 -32 -94 21 -190 -94 -68 -106 -146 36 16 -55 -19 -43 24 -174 -38 -8 -89 7 97 -3 116 -87 31 -6 154 -125 -47 42 28 -132 -161 85 -98 -19 -112 41 36 -13 31 96 66 -110 36 -134 -146 -50 -73 177 -148 -27 76 29 -88 -99 26 -76 54 -49 15 49 -2 77 68 -36 5 68 -87 214 -88 31 75 0 40 11 33 41 103 -130 107 -12 181 -70 -90 -17 12 -112 39 38 -41 -50 19 -77 65 29 -57 -4 179 15 106 -109 83 82 8 -141 34 45 -10 -90 62 -72 -41 -190 -10 164 127 141 -181 -62 -87 -13 -66 105 -95 14 -133 -66 173 -104 173 -53 16 -39 47 69 68 96 30 30 76 39 -62 7 -65 70 34 -56 100 64 -22 -84 181 -68 70 62 154 -72 -98 -42 -79 98 134 -20 29 -46 45 11 -119 93 71 3 3 -90 -173 -252 -84 5 52 -28 13 235 -82 -49 116 -46 -244 57 -70 181 59 37 -17 -46 66 -37 33 -59 -38 -3 196 -6 -52 53 59 8 -94 -7 22 13 7 39 -119 54 -3 73 -17 -5 39 -157 72 -85 39 19 17 -48 65 3 126 8 3 -151 -63 10 84 121 -11 125 143 59 -164 -50 -10 74 -166 -115 93 -146 65 55 -12 36 -166 -94 -28 -102 59 9 100 73 183 39 -63 -30 -34 -46 -19 -88